• 한국세라믹학회지
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• 제53권6호
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• pp.689-699
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• 2016

The effects of composition, structure design, and coating thickness of thermal barrier coating (TBC) on thermal barrier performance were investigated by measuring the temperature differences of TBC samples. TBCs with the thin and thick top coats were used for these studies, including TBCs with rare-earth (Gd, Yb, and La) compositions. The thermal barrier performance was enhanced with increasing the thickness of top coat even for thin TBCs, indicating that the thermal barrier performance was commensurate to the thickness of top coat. On the other hand, the bi-layered TBC, which was prepared with Yb-Gd-YSZ feedstock powder, with the buffer layer of high purity 8YSZ showed a better thermal barrier performance than that of regular purity 8YSZ. The interfaces in the bi-layered TBCs had a decisive effect on the thermal barrier performance, showing the performance enhanced with increasing numbers of interfaces. However, a new structural design and an additional process should be considered to reduce stress concentrations and to ensure interface stability, respectively, for improving thermal durability in the multi-layered TBCs.

• Composites Research
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• 제31권3호
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• pp.83-87
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• 2018

An object in the Low Earth Orbit (LEO) is affected by many environmental conditions unlike earth's surface such as, Atomic oxygen (AO), Ultraviolet Radiation (UV), thermal cycling, High Vacuum and Micrometeoroids and Orbital Debris (MMOD) impacts. The effect of all these parameters have to be carefully considered when designing a space structure, as it could be very critical for a space mission. Polybenzimidazole (PBI) is a high performance thermoplastic polymer that could be a suitable material for space missions because of its excellent resistance to these environmental factors. A thin coating of PBI polymer on the carbon epoxy composite laminate (referred as CFRP) was found to improve the energy absorption capability of the laminate in event of a hypervelocity impact. However, the overall efficiency of the shield also depends on other factors like placement and orientation of the laminates, standoff distances and the number of shielding layers. This paper studies the effectiveness of using a PBI coating on the front bumper in a multi-shock shield design for enhanced hypervelocity impact resistance. A thin PBI coating of 43 micron was observed to improve the shielding efficiency of the CFRP laminate by 22.06% when exposed to LEO environment conditions in a simulation chamber. To study the effectiveness of PBI coating in a hypervelocity impact situation, experiments were conducted on the CFRP and the PBI coated CFRP laminates with projectile velocities between 2.2 to 3.2 km/s. It was observed that the mass loss of the CFRP laminates decreased 7% when coated by a thin layer of PBI. However, the study of mass loss and damage area on a witness plate showed CFRP case to have better shielding efficiency than PBI coated CFRP laminate case. Therefore, it is recommended that PBI coating on the front bumper is not so effective in improving the overall hypervelocity impact resistance of the space structure.

• 한국식품과학회지
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• 제31권3호
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• pp.771-777
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• 1999

CSLM 기술을 이용하여 Salmonella enteritidis에 의한 계란 오염 과정을 관찰하여 난막의 3중막 구조, cuticle 층 그리고 5가지 필름 피복의 침투 방어효과를 조사하였다. 난막을 구성하는 fiber의 지름은 각각 outer membrane $1.5{\sim}7.2\;{\mu}m$, inner membrane $0.8{\sim}2.0\;{\mu}m$이었고, limiting membrane을 구성하는 입자의 지름은 $0.1{\sim}1.4\;{\mu}m$이었으며, 두께는 각각 평균 10.0, 3.5, $3.6\;{\mu}m$이었다. 난각과 접해 있는 outer membrane은 다음 층인 inner membrane과 부분적으로 중첩되어있고, limiting membrane의 입자들은 매우 밀집되어 inner membrane과 중첩된 상태로 존재하였다. Cuticle층은 전체 계란 표면적 중 $40{\sim}80%$ 를 덮고 있었으며, 두께는 평균 $6.0\;{\mu}m$이었고 피복 필름들의 평균 두께는 자각 mineral oil $5.0\;{\mu}m$, dextrin $3.6\;{\mu}m$, gelatin $3.9\;{\mu}m$, starch $2.5\;{\mu}m$, chitosan $2.2\;{\mu}m$이었다. 필름 피복에 의한 Salmonella enteritidis 생육 억제효과를 관찰한 결과, chitosan이 가장 효과적이었다. 그리고 trisodium phosphate (TSP), cetylpyridinium chloride (CPC) 처리, 5종의 필름 피복 처리와 무처리한 계란표면에 Salmonella enteritidis를 접종한 후 내부 전이 과정을 CSLM을 이용하여 다색영상화(multi-color imaging)와 시간당 투과 균수에 대한 plate count로 비교한 결과, 난각이나 3중막 구조의 난막보다는 cuticle 층이 Salmonella균의 오염을 차단하는데 결정적인 역할을 하는 것으로 나타났으며, chitosan 피복이 cuticle 층과 비슷한 효과를 보였다. 따라서 피복 필름중에서 chitosan이 최외부 방어막인 cuticle층이 결손된 난각 부위를 피복하는데 가장 적합할 것으로 사료된다.

• 한국재료학회지
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• 제17권4호
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• pp.185-191
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• 2007

The purpose of this study is to evaluate the thin fihn dielectric made of hybrid sol, which consist of barium titanate powder, polymeric sol and other polymers. This sol will be used dielectric applied to small, thin electric passive components such as MLCC(Multi Layer Ceramic Condenser), resister, inductor. This sol is composed of mixed fine barium titanate powder and polymeric sol including Ba, Ti-precursor, solvent, chelating agent, chemical reaction catalyst, the additive sols to improve fired densification and temperature reliability. First at all, we mixed hybrid sol to be dispersed and be stabilized by ball milling for 24hrs. By spin coating method, we makes thin film dielectric on the convectional green sheet for MLCC. After heat treatments, we analyzes the structure morphology, physical, electrical properties and X5R Temperature properties.

• 한국결정성장학회지
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• 제23권2호
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• pp.81-85
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• 2013

새로운 표면처리로서 TCF(thermal color fusion) 기술이 적용된 스와로브스키사의 패션 토파즈(passion topaz)의 코팅 층 성분과 적층구조를 파악하기 위해 ED-XRF와 TOF-SIMS 분석을 실시하였다. 더불어 감별특징 관찰을 위한 확대검사와 내구성 평가를 미스틱 토파즈(mystic topaz)와 비교 분석하였다. 그 결과, 패션 토파즈에서도 미스틱 토파즈에서 보이는 유사한 특징들이 확대검사를 통해 관찰되었고, TOF-SIMS에 의한 depth profile 분석 결과에서 토파즈 표면으로의 확산코팅과 다층구조 코팅이 되어있음을 알 수 있었다. 또한 패션 토파즈는 금속 원소간의 화학반응에 의한 코팅처리로 미스틱 토파즈 보다 화학약품에 대한 안정적인 특성과 높은 모스경도를 보였다.

• 펄프종이기술
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• 제40권5호
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• pp.60-69
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• 2008

The principal reasons for applying a pigment coating to paper are to improve appearance and printability. The pigment coating provides a surface that is more uniform and more receptive to printing ink than are the uncoated fibers and, in turn, both facilitates the printing process and enhances the graphic reproduction. The improvement in print quality is readily apparent, especially in image areas or when multiple colors are involved. Although pigment coating of paper is to improve the printability, coated paper is not completely free from printing defects. Actually there are a number printing defects that are observed only with the coated papers. Among the printing defects that are commonly observed for coated papers, print mottle during multi-color offset printing is one of the most concerned defects, and it appears not only on solid tone area but also half dot print area. There are four main causes of print mottle ranging from printing inks, dampening solution, paper, and printing press or its operation. These indicates that almost every factors associated with lithographic printing can cause print mottle. Among these variation of paper quality influences most significantly on print mottle problems in multicolor offset printing, and this indicates that paper is most often to be blamed for its product deficiency as far as print mottle problems are concerned. Furthermore, most of the print mottle problems associated with paper is observed when coated papers are printed. Uncoated papers rarely show mottling problems. This indicates that print mottle is the most serious quality problems of coated paper products. Overcoming the print mottle is becoming more difficult because the operating speeds of coating and printing machines are increasing, coating weights are decreasing, and the demands on high-quality printing are increasing. Print mottle in offset printing is caused by (a) nonuniform back trap of ink caused by a nonuniform rate of ink drying, referred as "back trap mottle, and (b) nonuniform absorption of the dampening solution. Furthermore, both forms of print mottle have some relationship to the structure of the coated layer. The surest way of eliminating ink mottling is to eliminate unevenness in the base paper. Coating solutions, often easier to put into practice, should, however, be considered. In this paper the principal factors influencing print mottle of coated papers will be discussed. Especially the importance of base paper roughness, binder migration, even consolidation of coating layers, control of the drying rate, types of binders, etc. will be described.

• 반도체디스플레이기술학회지
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• 제16권1호
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• pp.40-44
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• 2017

The effect of weak dielectric silicone dioxide($SiO_2$) embedded in polyfluorene(PFO) emitting layer of polymer-based multi structure OLED was investigated. Indium tin oxide(ITO)/poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS)/poly(9,9-di-n-octylfluorenyl-2,7-diyl)(PFO)/2,2,2"-(1,3,5-benzinetriyl)-tris(1-phenyl-1-H-benzimidazole) (TPBi)/aluminum(Al) structure OLED was fabricated by spin-coating method. Applied electric field causes some effect on $SiO_2$ in PFO layer. Thus, interaction between polymers and affected $SiO_2$ might generate electrical and luminance properties change. Experimental results, show the reduced threshold voltage of 6 V(from 23 V to 17 V). The maximum current density was rather increased from $71A/m^2$ to $610A/m^2$ and maximum brightness was also increased from $7.19cd/m^2$ to $41.03cd/m^2$, 9 and 6 times each. Additionally we obtained colour broadening result due to the increasing of blue-green band emission. Consequently we observed that electrical and luminance properties are enhanced by adding $SiO_2$ and identified the possibility of controlling the emission colour of OLED device according to colour broadening.

• 한국광학회지
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• 제13권3호
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• pp.209-214
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• 2002

기판의 표면거칠기가 반사경의 산란에 미치는 영향을 조사하였다. 기판의 표면거칠기가 다른 다섯 종류의 기판에 이온빔 스퍼터링 방법과 전자총 증착 방법으로 각각 반사율이 1에 가까운 고반사율 박막을 증착하고 산란을 TIS 방법으로 측정하였다. 기판의 표면거칠기가 2$\AA$ 이상인 경우의 기판의 산란에 대한 반사경 산란 비율은 표면거칠기가 2$\AA$ 미만인 경우의 산란 비율에 비하여 급격한 증가를 나타냄을 알 수 있었으며, 기판의 표면거칠기가 낮은 경우 반사경의 산란은 기판의 표면거칠기보다 반사경을 구성하는 박막의 미세구조에 의존하는 것으로 판단되었다. 한편 반사경 중에서 가장 작은 산란은 2.1 ppm이었고, 이것은 표면거칠기 0.23$\AA$인 기판에 이온빔 스퍼터링 방법으로 제작되었다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회A
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• pp.1825-1828
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• 2008

A simple method for the fabrication of porous nano-master for antireflective surface is presented. In conventional fabrication methods for antireflective surface, coating method with low refractive index has usually been used. However, it is required to have high cost and long times for mass production. In this paper, we suggested the fabrication method of antireflective surface by the hot embossing process using the porous nano patterned master on silicon wafer fabricated by low-temperature anodic aluminum oxidation. Through multi-AAO and etching processes, nano patterned master with high aspect ratio was fabricated at the large area. Pore diameter and inter-pore distance are about 150nm and from 150 to 200nm. In order to replicate anti-reflective structure, hot embossing process was performed by varying the processing parameters such as temperature, pressure and embossing time etc. Finally, antireflective surface can be successfully obtained after etching process to remove selectively silicon layer of AAO master.

• 한국전기전자재료학회논문지
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• 제29권3호
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• pp.168-174
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• 2016

A conductive oxide-based sapphire glass indium tin oxide/metal electrode and the optical coating, through patterning process was studied in excellent optical properties and integrated touch panel has a high strength. Indium tin oxide conductive oxides of the sapphire glass to 0.3 A at DC magnetron sputtering method of 10 min, gas flow Ar 10 Sccm Ar, $O_2$ 1.0 Sccm the formation conditions of the thin film after annealing at $550^{\circ}C$ for 30min was achieved through a 86% transmittance. In addition, the coating 130 nm hollow silica sol-gel was to improve the optical transmittance of the indium tin oxide to 91%. For the measurement by the modeling hollow silica sol by Macleod simulation and calculated the average values of silica part to the presence or absence in analogy to actual. Refractive index value and the actual value of the material on the simulation the transmittance difference is it does not completely match the air region similar to the actual value (transmission) could be confirmed that the measurement is set to a value of between 5 nm and 10 nm.