• 제목/요약/키워드: Multi-Electrode

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폐 플로랄 폼을 이용한 슈퍼커패시터용 다공성 탄소 폼 제조 및 전기화학 성능 평가 (Preparation and Electrochemical Characterization of Porous Carbon Foam from Waste Floral Foam for Supercapacitors)

  • 이병민;박진주;박상원;윤제문;최재학
    • 한국재료학회지
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    • 제32권9호
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    • pp.369-378
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    • 2022
  • The recycling of solid waste materials to fabricate carbon-based electrode materials is of great interest for low-cost green supercapacitors. In this study, porous carbon foam (PCF) was prepared from waste floral foam (WFF) as an electrode material for supercapacitors. WFF was directly carbonized at various temperatures of 600, 800, and 1,000 ℃ under an inert atmosphere. The WFF-derived PCF (C-WFF) was found to have a specific surface area of 458.99 m2/g with multi-modal pore structures. The supercapacitive behavior of the prepared C-WFF was evaluated using a three-electrode system in a 6 M KOH aqueous electrolyte. As a result, the prepared C-WFF as an active material showed a high specific capacitance of 206 F/g at 1 A/g, a rate capability of 36.4 % at 20 A/g, a specific power density of 2,500 W/kg at an energy density of 2.68 Wh/kg, and a cycle stability of 99.96 % at 20 A/g after 10,000 cycles. These results indicate that the C-WFF prepared from WFF could be a promising candidate as an electrode material for high-performance green supercapacitors.

연료전지스택 바깥판의 위상최적설계 (Topology Optimization for End Plate of Fuel Cell Stack)

  • 최우석;오성진;김성종;홍병선
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 춘계학술대회
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    • pp.456-461
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    • 2003
  • A fuel cell is an electrochemical device in which the energy of a chemical reaction is converted directly into electricity. By combining hydrogen fuel with oxygen from air, electricity is formed, without combustion of any form. Water and heat are the only by-products when hydrogen is used as the fuel source. Fuel cell stack consists of multi-layered unit cells. A unit cell consists of MEA and bipolar plates. The end plate of fuel cell stack should give a uniform distributed pressure to multi unit cell layers so as to reduce the contact resistance and to prevent the leakage of reactant gases and the damage of multi layer components. The current end plate is redundantly large and heavy. It makes the power per unit volume reduced. Topology optimization of end plate is conducted for mass reduction and enhancement of bending rigidity. The evaluation of the current design and the recommendation for the future design is remarked.

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디지털 신호처리기를 사용한 태아심전도 신호 추출 시스템 (A Fetal ECG Signal Monitoring System Using Digital Signal Processor)

  • 박영철;조병모;김남현;김원기;박상휘;연대희
    • 대한전자공학회논문지
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    • 제26권9호
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    • pp.1444-1452
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    • 1989
  • This paper describes the implementation of a real time fetal ECG monitoring system in which an adaptive multi-channel noise canceller is realized using the Texas Instruments TMS32020 progrmmmable ditital signal processor. An ECG signal from the electrode placed on the mother's abdomen and three ECGs from those on the chest are applied as the desired signal and the referened inputs, respectively, of the multi-channel filter. The coefficients of the filter are updated using the LMS algorithm such that the output of the multi-channel filter copies the maternal ECG embedded in the abdominal ECG. The enhanced fetal ECG is obtained by subtracting the filter output from the abdominal ECG, and the difference signal is recorded. Both off-line and on-line experimental results are presented to verify the effectiveness of the parameters for the digital signal processing algorithms and the prototype system.

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다중벽 탄소나노튜브를 이용한 공진기 제작 (Fabrication of a Resonator using suspended Multi-wall Carbon Nanotubes)

  • 이종홍;서희원;송진원;한창수
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2006년도 춘계학술대회 논문집
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    • pp.465-466
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    • 2006
  • A single-wall carbon nanotube (SWCNT) has been studied as a material of Nano-Eletro-Mechanical-System (NEMS) device together with various nanowires. In order for oscillation of a multi-wall carbon nanotube (MWCNT) or a single-walled carbon nanotube (SWCNT) on plane surface, it needs suspension of a CNT across trench electrodes. So we propose fabrication method of a MWCNT resonator using dielectrophoresis and show successful results of suspeneded MWNT. Thin electrodes with large gaps could not suspend small diameter MWNT but thicker electrodes could. Thin MWNT could be suspended only when the electrode gap was reduced.

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우리나라 고용량 MLCC 기술 개발의 역사와 전망 (Development History and Trend of High-Capacitance Multi-layer Ceramic Capacitor in Korea)

  • 홍정오;김상혁;허강헌
    • 한국세라믹학회지
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    • 제46권2호
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    • pp.161-169
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    • 2009
  • MLCC (Multi-layer Ceramic Capacitor) is the most important passive component in electronic devices such as HHP, PC and digital display. The development trend of MLCC is a miniaturization with increasing the capacitance. In this paper, a development history of the high capacitance MLCC in Korea was introduced, and the necessity of the finer $BaTiO_3$ was explained in the viewpoint of the issued electrical and dielectric properties of high capacitance MLCC. The bottleneck technologies to realize the high capacitance was shortly introduced, followed by the prediction of the development trend of MLCC in near future.

저온 고체산화물연료전지 구현을 위한 다층 나노기공성 금속기판의 제조 (Development of Metal Substrate with Multi-Stage Nano-Hole Array for Low Temperature Solid Oxide Fuel Cell)

  • 강상균;박용일
    • 한국세라믹학회지
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    • 제42권12호
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    • pp.865-871
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    • 2005
  • Submicron thick solid electrolyte membrane is essential to the implementation of low temperature solid oxide fuel cell, and, therefore, development of new electrode structures is necessary for the submicron thick solid electrolyte deposition while providing functions as current collector and fuel transport channel. In this research, a nickel membrane with multi-stage nano hole array has been produced via modified two step replication process. The obtained membrane has practical size of 12mm diameter and $50{\mu}m$ thickness. The multi-stage nature provides 20nm pores on one side and 200nm on the other side. The 20nm side provides catalyst layer and $30\~40\%$ planar porosity was measured. The successful deposition of submicron thick yttria stabilized zirconia membrane on the substrate shows the possibility of achieving a low temperature solid oxide fuel cell.

직접메탄올 연료전지용 다층스택의 성능특성 (Performance of multi-cell stack for direct methanol fuel cells)

  • 이창형;정두환;김창수;신동열
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 D
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    • pp.1870-1872
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    • 1999
  • Performance of 20-cell stack for direct methanol fuel cell (DMFC) was tested at constant temperature. Electrode evaluation used to the stack was tested by the performance of a single cell. A new composite electrode prepared from active carbon cloth and high porous active carbon was developed for hydrophilic layer of the cell. Characteristics of a single cell using the composite electrode showed the current density of $500mA/cm^2$ at the cell voltage of 0.4V at $120^{\circ}C$. For the operating of 20 days. the cell voltage at constant cell current densty of $100mA/cm^2$ was slightly reduced from 0.62V to 0.53V with the cell voltage decay rate of 14.5%. Power of 20-cell stack at 5.3V, $100^{\circ}C$ was about 180W.

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Surface Modification of Multi-walled Carbon Nanotubes for Enhancement of Dispersion and Electrochemical Properties

  • Kim, Young-Ja;Zhang, Wentao;Lee, Hong-Ro;Kim, Jong-Hyee
    • 한국표면공학회지
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    • 제41권5호
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    • pp.194-198
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    • 2008
  • Several methods for improving dispersion of carbon nanotubes (CNTs) have been investigated. CNTs modified by acids and hydrogen peroxide ($H_2O_2$) showed improved dispersion. From SEM micrographs and photos of dispersion, CNTs modified with nitric acid and $H_2O_2$, showed no agglomeration in solution even standing for 4 months, which means successfully improved dispersion property. TEM micrographs of surface modified single CNT treated with 69% $HNO_3$ in boiling acid solution as the optimum method were obtained. For confirmation of CNTs' application to EDLC electrode materials, characteristics of EDLC have been analyzed by cyclic voltammetry curve, specific capacitance of unit cell, electrode discharge curves and AC impedance curve. From the results, it could be confirmed that electrochemical properties of CNTs were enhanced after surface modification with 69% $HNO_3$ acid treatment.

Characteristics of the Multi-kW Class Polymer Electrolyte Membrane Fuel Cell Stack for a Hybrid Electric Golf Cart

  • I.H. Oh;S.J. Shin;J.H. Jo;Park, S.K.;H.Y. Ha;S.A. Hong;S.Y. Ahn;Lee, Y.C.;S.A. Cho
    • 에너지공학
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    • 제11권3호
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    • pp.254-261
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    • 2002
  • The fabrication method for the main components of the polymer electrolyte membrane fuel cell stack such as electrodes, membrane-electrode assemblies, and bipolar plates was established for the effective electrode area of 240 ㎠. A counter-flow type 100-cell stack was fabricated by using the above components and then a maximum power of 7.44 kW for H$_2$/O$_2$ and 5.56 kW for H$_2$/air could be obtained at 70$\^{C}$ and 1 atm. It was seen that the distribution of the OCV for unit cells in the stack was uniform but the voltage deviation increased as the load increased due to the IR drop and the electrode polarization. The stack was applied to the power source of the fuel cell/battery hybrid electric golf car. It produced about 1 kW at a room temperature operation during the test run, which occupied about 43% of the total power required by the 2.3 kW motor.

분포형 압전 필름 감지기와 압전 세라믹 작동기를 이용한 보의 진동 제어 (Vibration Control of Beam using Distributed PVDF sensor and PZT actuator)

  • 박근영;유정규;김승조
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 1997년도 춘계학술대회논문집; 경주코오롱호텔; 22-23 May 1997
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    • pp.413-417
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    • 1997
  • Distributed piezoelectric sensor and actuator have been designed for efficient vibration control of a cantilevered beam. Both PZT and PVDF are used in this study, the former as an actuator and the latter as a sensor for our integrated structure. For the PZT actuator, the position and size have been optimized. Optimal electrode shape of the PVDF sensor has been determined. For multi-mode vibration control, we have used two PZT actuators and a PVDF sensor. Electrode shading of PVDF is more powerful for modal force adjustment than the sizing and positioning of PZT. Finite element method is used to model the structure that includes the PZT actuator and the PVDF sensor. By deciding on or off of each PZT segment, the length and the location of the PZT actuator are optimize. Considering both of the host structure and the optimized actuators, it is designed that the active electrode width of PVDF sensor along the span of the beam. Actuator design is based on the criterion of minimizing the system energy in the control modes under a given initial condition. Sensor is designed to minimize the observation spill-over. Modal control forces for the residual(uncontrolled) modes have been minimized during the sensor design. Genetic algorithm, which is suitable for this kind of discrete problems, has been utilized for optimization. Discrete LQG control law has been applied to the integrated structure for real time vibration control. Performance of the sensor, the actuator, and the integrated smart structure has been demonstrated by experiments.

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