• Bulletin of the Korean Chemical Society
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• v.33 no.11
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• pp.3727-3734
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• 2012

An analytical method has been developed for the rapid determination of perfluorinated compounds (PFCs) in human serum samples. The extraction and purification of PFCs from human serum were performed by the modified method of previous report. Ten PFCs were rapidly separated within 3.3 min by C18-monolithic column liquid chromatography (LC) and detected by electrospray ionization (ESI) tandem mass spectrometry (MS/MS) in negative ion mode. The runtime of PFCs on monolithic column LC was up to 4-fold faster than that on conventional column LC. The effect of triethylamine (TEA) to the mobile phase has investigated on the overall MS detection sensitivity of PFCs in ESI ionization. Quantification was performed by LC-MS/MS in multiple-ion reaction monitoring (MRM) mode, using $^{13}C$-labeled internal standards. Method validation was performed to determine recovery, linearity, precision, and limits of quantification, followed by, the analysis of a standard reference material (SRM 1957 from NIST). The overall recoveries ranged between 81.5 and 106.3% with RSDs of 3.4 to 16.2% for the entire procedure. The calibration range extended from 0.33 to 50 $ng\;mL^{-1}$, with a correlation coefficient ($R^2$) greater than 0.995 and the limits of quantification with 0.08 to 0.46 $ng\;mL^{-1}$. This approach can be used for rapid and sensitive quantitative analysis of 10 PFCs in human serum with high performance and accuracy.

• Journal of Korean Association for Spatial Structures
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• v.6 no.2 s.20
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• pp.85-92
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• 2006

Precast large panel structures have various connection system such as the horizontal slab-to-wall connection, the vertical wall to wall connection, horizontal slab-to-slab connection, etc. Horizontal connection is connected by vertical tie bars, and vertical joint is connected loop bars and shear keys. The basic function is equalized deformations on later forces and the entire wall panel assembly acts as monolithic actions. Under lateral load some slip occurs in almost vertical connections. The shape and detail of precast connections are very important to the monolithic behavior of overall structures. The paper is a study on the design method and new elasto-plastic analysis of the connections by rigid-bodies spring model.

• Analytical Science and Technology
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• v.24 no.6
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• pp.421-428
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• 2011

In this study, headspace disk type monolithic material sorptive extraction (HS-MMSE) was developed, validated and applied to the analysis of volatile aroma compounds from vanilla perfume by gas chromatography -mass spectrometry (GC/MS). HS-MMSE uses monolithic material (MonoTrap) based on silica bonded with octadecyl silane (ODS) and activated carbon as a sorbent. Aroma compounds was adsorbed onto the MonoTrap in headspace and extracted by only 100 ${\mu}L$ of solvent. Total 12 volatile compounds from vanilla perfume were successfully analyzed using HS-MMSE. The influence of extractive parameters was investigated and optimized, using benzyl acetate, linalyl acetate, vanillin, ethyl vanillin as target compounds. Under the optimum condition, the limit of detection (S/N = 3) and the limit of quantification (S/N = 10) of proposed method for the target compounds were obtained within the range of 8.35~13.76 ng and 27.82~45.88 ng, respectively. The method showed good linearity with correlation coefficient more than 0.9888, satisfactory recovery and reproducibility. These results showed that HS-MMSE using disk type MonoTrap is a new promising technique for the analysis of volatile aroma compounds from vanilla perfume.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 1993.10a
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• pp.149-156
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• 1993

Precast concrete (P.C.) large panel structures have usually weaker stiffness at joints than that of monolithic in-situ reinforced concrete structures. But structural designers do not in general take into account this characteristics of P. C. large panel structures and use the same analytical models as for the monolithic structure. Therefore, the results of analysis obtained by using these models may be quite different from those actually occuring in real P.C. structure. In this study, the change in force and stress distribution and deflections of structure caused by applying lower shear stiffness at vertical joints are investigated through trying several finite element modeling schemes specific for P.C. structures. Finally, for engineers in practice. a simplified model, which takes account of the effect of lower shear stiffness at vertical joints, is proposed with the understanding on possible amount of errors.

• 한국전산유체공학회:학술대회논문집
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• 1995.10a
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• pp.76-81
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• 1995

A numerical procedure for the analysis of transient behavior in a monolithic catalytic converter is presented. The thermal behavior of a monolithic catalytic converter is fully coupled with mass transfer and exothermic reaction between exhaust gases and the catalytic converter. In the present study, all these processes are solved simultaneously. The heat transfer process is approximated by combinging one dimensional convection and conduction and the chemical reaction is also simply modelled by using the concepts of reaction rate and reaction heat. All the partial diffenrential equations for the heat transfer, mass transfer and chemical reactions are appximated by using finite volume method. Resulting algebraic equations are solved using the Newton's method. To see the workability of present numerical method, two well known problems, say step increase and step decrease in the gas inlet temperature, have been calculated. Comparion of present solutions with previous solutions shows a good agreement.

• Nuclear Engineering and Technology
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• v.51 no.6
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• pp.1575-1588
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• 2019

Fracture near the U-10Mo/cladding material interface impacts fuel service life. In this work, a mesoscale stress model is developed with the fuel foil considered as a porous medium having gas bubbles and bearing bubble pressure and surface tension. The models for the evolution of bubble volume fraction, size and internal pressure are also obtained. For a U-10Mo/Al monolithic fuel plate under location-dependent irradiation, the finite element simulation of the thermo-mechanical coupling behavior is implemented to obtain the bubble distribution and evolution behavior together with their effects on the mesoscale stresses. The numerical simulation results indicate that higher macroscale tensile stresses appear close to the locations with the maximum increments of fuel foil thickness, which is intensively related to irradiation creep deformations. The maximum mesoscale tensile stress is more than 2 times of the macroscale one on the irradiation time of 98 days, which results from the contributions of considerable volume fraction and internal pressure of bubbles. This study lays a foundation for the fracture mechanism analysis and development of a fracture criterion for U-10Mo monolithic fuels.

• Journal of the Korea institute for structural maintenance and inspection
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• v.11 no.5
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• pp.99-106
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• 2007

To satisfy with the increased requirements of cost reduction, labor saving, and rapid construction, the purpose of this study is to investigate the structural behavior of PSC monolithic and spliced girders. Three tests were conducted on small-scale girder specimens. This paper presents the result of experimental studies in terms of the load-deflection behavior. Different joint type and tendon amount were investigated as major variables. The monolithic girder was arranged with three tendons. The spliced girder consisted of five segments connected by three tendons. In addition, five-segmented girders connected by more than three tendons were built to examine the effect of the tendon amount. The experimental results show the difference of behavior between monolithic and spliced girders. Moreover, nonlinear finite element method analysis was utilized to verify the experimental result.

• Steel and Composite Structures
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• v.37 no.3
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• pp.371-390
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• 2020

One of the most common strategies for retrofitting as-built reinforced concrete (RC) columns is to enlarge the existing section through the application of a new concrete layer reinforced by both steel transverse and longitudinal reinforcements. The present study was dedicated to developing a comprehensive model to predict the seismic behavior of as-built RC jacketed columns. For this purpose, a new sectional model was developed to perform moment-curvature analysis coupled by the plastic hinge method. In this analysis-oriented model, new methodologies were suggested to address the impacts of axial, flexural and shear mechanisms, variable confining pressure, eccentric loading, longitudinal bar buckling, and varying axial load. To consider the effective interaction between core and jacket, the monolithic factor approach was adopted to extent the response of the monolithic columns to that of a respective RC jacket strengthened column. Next, parametric studies were implemented to examine the effectiveness of the main parameters of the RC jacket strategy in retrofitting as-built RC columns. Ultimately, the reliability of the developed analytical model was validated against a series of experimental results of as-built and retrofitted RC columns.

• Journal of the Korean Ceramic Society
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• v.30 no.7
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• pp.535-542
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• 1993

It was investigated in this study that a preparation method, activation energy, surface area, pore volume, pore size distribution and DTA analysis of the dry gel in process of producing monolithic porous gel in Li2O-Al2O3-TiO2-SiO2 system by the sol-gel technique using metal alkoxides. Activation energy for gellation according to the variation of water concentration and the kind of catalysts ranged from 10 to 20kcal/mole. Monolithic dry gels were prepared after drying at 9$0^{\circ}C$ when the amount of water for gellation was 4~8 times more than the stoichiometric amount, that was necessary for the full hydrolysis of the mixed metal alkoxide. The specific surface area, the pore volume, the average pore radius of the dried gel at 18$0^{\circ}C$ according to the various kinds of catalyst were about 348~734$m^2$/g, 0.35~0.70ml/g and 10~35$\AA$, respectively. It showed that the dry gels were porous body. As a result ofthe analysis of DTA, it was confirmed that the exothermaic peaks at 715$^{\circ}C$ and 77$0^{\circ}C$ was clue to the crystallization of dried gel.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.31 no.4
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• pp.425-431
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• 2007

[ $Al_2O_3/SiC$ ]composite ceramics were sintered to evaluate the bending strength and elastic wave characteristics. The three-point bending test was carried out under room temperature. The elastic wave was detected by fracture wave detector. The crack healing behavior was investigated from 1373 K to 1723 K. The bending strength of $Al_2O_3/SiC$ composite by nanocomposite is higher than that of $Al_2O_3$ monolithic. Crack-healing behavior depended on an amount of additive powder $Y_2O_3$. In $Al_2O_3/SiC$ composite ceramics with 3 wt. % $Y_2O_3$ for additive powder, the bending strength at 1573 K is about 100% increase than that of the smooth specimens. From the result of wavelet analysis of elastic wave signal, the smooth specimen and heat treated specimen of $Al_2O_3$ monolithic and $Al_2O_3/SiC$ composite ceramics showed characteristics of frequency about 58 kHz. The strength of $Al_2O_3/SiC$ composite ceramics was a little higher than those of $Al_2O_3$ monolithic. The dominant frequencies were high with increasing of $Y_2O_3$ for additive powder. The dominant frequencies had direct connection with the bending strength.