• Proceedings of the KSME Conference
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• 2001.06d
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• pp.146-151
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• 2001

Several design parameters for a 100 kW molten carbonate fuel cell stack was described. Approximately 170 cells are required to generate 100 kW at a current density of $125\;mA/cm^{2}$ with $6000\;cm^{2}$ cells. An overall heat balance was calculated to predict exit temperature. In order to limit the stack temperature in the range of $600-700^{\circ}C$, current load cannot exceed $75\;mA/cm^{2}$ at atmospheric operation. The 100 kW power is expected only under pressurization. Recycle of cathode gas by more than 50% is recommended to run the stack at $125\;mA/cm^{2}$ and 3 atm. Manifolds should be designed based on gas flow rates for the suggested operating condition.

• Proceedings of the KIEE Conference
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• 1992.07b
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• pp.854-856
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• 1992

The molten carbonate fuel cell has conspicuous features and high potential in being used as an energy converter of various fuels to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at 650 [$^{\circ}C$] have many problems. This study has examined fabricating methods and specimen characteristics of porous anode electrode.

• Electrical & Electronic Materials
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• v.9 no.8
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• pp.831-835
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• 1996

The molten carbonate fuel cell has conspicuous features and high potential in being used as an energy converter of various fuels to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at 650[.deg. C] have many problem. Systematic investigation on corrosion behavior of Fe-based Cr has been done in ($62{\times}38$)mol % (Li+K)$CO_3$ melt at 923K by using steady state polarization and electrochemical impedance spectroscopy method. It was found that the corrosion current of these Fe-based alloys decreased with increasing Cr content, and this was attributed to the formation of $LiCrO_2$ layer at the surface .

• Transactions of the Korean hydrogen and new energy society
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• v.15 no.1
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• pp.54-61
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• 2004

Temperature characteristics in a stack of molten carbonate fuel cell (MCFC) have been investigated with simulation based on the computational fluid dynamics (CFD) codes and experimental way. The MCFC has generally two stack structures when the natural gas is used as fuel; one is the external reforming type and the other is internal reforming type. Computer simulation at the external reforming stack suggests that the maximum temperature in the stack depends on the gas flow length. The 2 kW MCFC stack with 25 cm gas flow length showed about $675^\circ{C}$ of maximum temperature.

• Proceedings of the KSME Conference
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• 2000.04b
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• pp.264-269
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• 2000

As a part of the ongoing effort towards commercial application of high-temperature fuel cell power generation systems, we have recently built a pilot-scale molten carbonate fuel cell power plant and tested it. The stack test system is composed of diverse peripheral units such as reformer, pre-heater, water purifier, electrical loader, gas supplier, and recycling systems. The stack itself was made of 40cells of $6000cm^2$ area each. The stack showed an output higher than 25kW power and a reliable performance at atmospheric operation. A pressurized performance was also tested, and it turned out the cell performance increased though a few cells have shown a symptom of gas crossover. The pressurized operation characteristics could be analyzed with numerical computation results of a stack model.

• Journal of the Korean institute of surface engineering
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• v.28 no.4
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• pp.243-254
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• 1995

The fabrication process of Cu-base anode for replacing Ni-base anode of molten carbonate fuel cell was investigated. Electrochemical performance and thermal stability of Cu-base anode were also investigated. Green sheet was prepared by mixing Cu and Ni powder with 1.5wt% methylcellulose and 100wt% water. The pore-size distribution of the Cu-base anode sintered at $800^{\circ}C$ for 30min showed almost uniform pore-size ranging from 4 to 20$\mu\textrm{m}$ and it was considered suitable for MCFC anode. Cu-Ni anode containing between 35 to 50wt% Ni exhibited current density of 111mA/$\textrm{cm}^2$ at 100mV overpotential and it was almost the some value for pure Ni anode. The sintering resistance of Cu-Ni increased with an increase of Ni addition. It was considered that the increase of sintering resistance was due to the decrease of diffusion rate of Cu and Ni with increasing the addition of Ni in Cu-Ni alloy.

• Applied Chemistry for Engineering
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• v.3 no.4
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• pp.535-546
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• 1992

The molten carbonate fuel cell(MCFC) has been under Intensive development for the last decade as a second generation fuel cell. The advantages of the MCFC over the phophoric acid fuel cell are higher efficiency, its ability to accept CO and $H_2$ as a fuel, lower material costs, and high operating temperature making internal reforming possible. These features, along with low atmospheric emissions, will open up a significant market as an attractive means of developing highly efficient power plant. This article reviews a status of the MCFC research and development, a principle of the MCFC, and cell and stack technology including the status of electrodes, matrices and electrolytes. Several technical difficulties which must be resolved to be commercialized art mainly focused.

• Journal of the Korean institute of surface engineering
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• v.27 no.3
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• pp.166-175
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• 1994

The effect of Co addition on the electrochemical performance and structural stability of porous Ni anode for molten carbonate fuel cell(MCFC) was evaluated by the anodic polarization and the sintering test in the simulated MCFC anode condition ($650^{\circ}C$, 80% $H_2$+20%$CO_2$). The anode current density ranged from 110mA/$cm^2$ to 144mA/$cm^2$ was obtained at +100mV overpotential by additions of Co up to 10 wt.%. The sintering resistance of Ni-Co anodes was higher than that of the pure Ni anode. The increase of sintering resistance seemed to be to the lower diffusion coefficient of Co than that of Ni.

• Proceedings of the KIEE Conference
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• 1997.07d
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• pp.1387-1388
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• 1997

The MCFC has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at $650^{\circ}C$ have many problem. Systematic investigation on corrosion behavior of Fe/20Cr/Ti alloys has been done in (62+38)mol% (Li+K)CO3 melt at 923K by using steady state polarization and electrochemical impedance spectroscopy method.

• Journal of the Korean Professional Engineers Association
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• v.44 no.1
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• pp.48-52
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• 2011

The KEPCO Research Institute has developed Molten Carbonate Fuel Cell(MCFC) since 1993. Recently, an 125-kW MCFC system was operated at Boryeong thermal power plant, Korea from December, 2009 to March, 2010, This system is composed of an 125-kW stack, mechanical balance of plant (MBOP), and Power Conditioning System. The stack has 200 unit cells of which effective area is 10,000 cm2. Especially, MBOP is mainly made up of ejector and catalytic combustor which help this system to be supplied with cathode inlet gas using anode tail gas and fresh air. After the pretreatment of this system was performed for about 20 days, initial load operation was performed at January. 2010. Moreover, this system had been operated for 3,270 hours.