• Title/Summary/Keyword: Molecular structures

Search Result 1,356, Processing Time 0.026 seconds

Nanostructured Materials and Nanotechnology : Overview

  • Muhammed, Mamoun;Tsakalakos, Thomas
    • Journal of the Korean Ceramic Society
    • /
    • v.40 no.11
    • /
    • pp.1027-1046
    • /
    • 2003
  • Nanostructured materials can be engineered by the controlled assembly of several suitable nano-objects as the building blocks. While, materials properties are determined by their atomic and molecular constituents and structure, their functionalities emerge when the microstructure of these early ensembles is in the nanometer regime. The properties and functionalities of these ensembles may be different as their size grows from the nano-regime to the micron regime and bulk structures. Nanotechnology, offers a unique possibility to manipulate the properties through the fabrication of materials using the nano-objects as building blocks. Nanotechnology is therefore considered an enabling technology by which existing materials, virtually all man-made materials, can acquire novel properties and functionalities making them suitable for numerous novel applications varying from structural and functional to advanced biomedical in-vivo and in-vitro applications.

A study on the growth and the molecular orientation and the surface Characterization of $\alpha$-Sexithiophene thin films by OMBD technique (유기빔성막법을 이용한 $\alpha$-Sexithiophene 박막의 제조 및 분자 배향과 표면 특성에 관한 연구)

  • 권오관;오세운;박미경;김영관;신동명;최종선;손병청
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1997.11a
    • /
    • pp.328-330
    • /
    • 1997
  • Organic semiconductors such as conjugated polymers and oligomers have been studied many research groups. The band structures of conjugated polymers and oligomers are similar to those of conventional inorganic semiconductors Thin films based on these materials show a promising potential for Field Effect Transistors(FETs) and Light Emitting Diodes(LED) because fabrication processes are simple and cheaper for large electronic devices and flexible devices are also possible.

  • PDF

Molecular Modeling of the Subtype Dopamine Receptor-ligand Interactions

  • Baek, Minkyung;Shin, Woong-Hee
    • Proceeding of EDISON Challenge
    • /
    • 2013.04a
    • /
    • pp.13-24
    • /
    • 2013
  • Dopamine agonists and antagonists and its receptor play a critical role in the information transfer in the nervous system, and dopamine receptor-ligands interactions are deeply related to Parkinson's disease, schizophrenia and some other mental diseases. However, the only experimental 3D structure available for dopamine receptors is human D3 dopamine receptor. Therefore, it is important to create model of subtype dopamine receptor-ligands interactions. We report here the 3D structures of the human D1 and D2 dopamine receptor predicted by using GalaxyTBM, and its predicted binding site determined by using GalaxyDock. The highly conserved Asp on TM 3 and Phe on TM 6 have critical role in ligand binding. Also, highly conserved serines on TM 5 are essential for binding agonists and some kinds of antagonists. We identify differences between binding sites of agonists and antagonists of human D1 and D2 dopamine receptor, and find the reasons of selective binding of antagonists.

  • PDF

The Effects of Electron Beam Exposure Time on Transmission Electron Microscopy Imaging of Negatively Stained Biological Samples

  • Kim, Kyumin;Chung, Jeong Min;Lee, Sangmin;Jung, Hyun Suk
    • Applied Microscopy
    • /
    • v.45 no.3
    • /
    • pp.150-154
    • /
    • 2015
  • Negative staining electron microscopy facilitates the visualization of small bio-materials such as proteins; thus, many electron microscopists have used this conventional method to visualize the morphologies and structures of biological materials. To achieve sufficient contrast of the materials, a number of imaging parameters must be considered. Here, we examined the effects of one of the fundamental imaging parameters, electron beam exposure time, on electron densities generated using transmission electron microscopy. A single site of a negatively stained biological sample was illuminated with the electron beam for different times (1, 2, or 4 seconds) and sets of micrographs were collected. Computational image processing demonstrated that longer exposure times provide better electron densities at the molecular level. This report describes technical procedures for testing parameters that allow enhanced evaluations of the densities of electron microscopy images.

FT-IR and XRD Analyses of Commercial Methionine-Mineral Chelates

  • Han, Jae-Hong;Chi, Yong-Seok;Shin, Bok-Kyu;Kim, Sang-Kyu;Paik, In-Kee
    • Journal of Applied Biological Chemistry
    • /
    • v.49 no.1
    • /
    • pp.8-10
    • /
    • 2006
  • Compositions of methionine-metal chelates have been investigated by FT-IR and XRD studies to elucidate their molecular structures. It was concluded that Copamin and Zincamin contain a high percentage of crystalline products, presumably 2:1 Methionine-Cu or Zn complexes. On the contrary, FT-IR and XRD spectra of Ferramin didn't show any characteristics of the chelate and it was concluded to contain major components of starting $FeSO_4$ and methionine without chelation.

A Study on the Way to Increase Heat Resistance of Teflon Type Thin Film Electret Applied for Industrial Sensor (산업용 센서에 사용하는 Teflon계 박막 일렉트렛의 내열성 향상에 관한 연구)

  • 김병수;이덕출
    • Journal of the Korean Society of Safety
    • /
    • v.18 no.3
    • /
    • pp.60-63
    • /
    • 2003
  • For the increase the charge stability of teflon electrets for used at uncomfortable industrial circumstances with high temperature or humidity, We made an investigation into double layer effect of teflon electrets. Teflon AF film was spincoated on FEP film and then the charge storage property of AF/FEP dual film was investigated to be compared with FEP film. It was found that the AF/FEP dual film has higher surface potential than FEP film on the repeated charging and annealing process. It seems that AF/FEP dual film has higher thermal stability than FEP film through TSC measurement. If the investigations of the double layer effect of Teflon film carried out more closely with it's molecular structures and surface conditions, it may be effectively improved the stability of charge storage.

A Study on Characteristics of Surface Modified Polyimide Film by Wet Process (습식 표면개질 처리된 폴리이미드 필름 표면의 특성에 관한 연구)

  • Koo, S.B.;Lee, H.K.
    • Journal of Surface Science and Engineering
    • /
    • v.39 no.4
    • /
    • pp.166-172
    • /
    • 2006
  • Metallized Polyimide films are extensively used as base materials in microelectronics, optical and automotive applications. However it is difficult to deposit metals on those because of their structural stabilities. In this work, polyimide films are modified by a wet process with alkalinemetalhydroxide and additives to introduce functional groups. The surface molecular structures of polyimide are investigated using X-ray photoelectron spectroscopy(XPS), fourier transform infrared reflection spectroscopy(FTIR-ATR), atomic force micro-scopic(AFM). XPS spectra and FTIR spectra show that the surface structure of polyimide is converted into potassium polyamate. AFM image and AFM cross-sectional analyses reveal the increased roughness on the modified surface of polyimide films. As a result, it is shown that the adhesion strength between polyimide surface and electroless nickel layer is increased by the nano-anchoring effect.

Mesoscopic properties of carbon nanotubes and its applications: The present and future

  • Lee, Young-Hee
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2000.02a
    • /
    • pp.209-209
    • /
    • 2000
  • Carbon nanotubes have been intensively investigated for its fundamental and technical importances. Structural diversities and the related diverse physical properties with large aspect ratios are fascinating, For instance carbon nanotubes are metal and semiconductors depending on its chirality and furthermore the band gap can be tailored by the diamters. Several issues on its fundamental properties have been discussed. We will review some fundamental problems for band structures, molecular quantum wires, homojunctions, single electron tunneling, and quantum conductance. Several issues related to syntheis of carbon nanotubes including arc discharge, chemical vapor deposition, laser ablation will be extentively discussed. We will further review the applicability of carbon nanotubes on resonator, nanobalance, FET-type transistor, field emission displays electrode for secondary battery and hydrogen storage.

  • PDF

Fabrication of Large-Scale Single-Crystal Organic Nanowire Arrays for High-Integrated Flexible Electronics

  • Park, Gyeong-Seon;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.08a
    • /
    • pp.266.1-266.1
    • /
    • 2013
  • Large-scale single-crystal organic nanowire arrays were generated using a direct printing method (liquidbridge- mediated nanotransfer molding) that enables the simultaneous synthesis, alignment and patterning of nanowires from molecular ink solutions. Using this method, single-crystal organic nanowires can easily be synthesized by self-assembly and crystallization of organic molecules within the nanoscale channels of molds, and these nanowires can then be directly transferred to specific positions on substrates to generate nanowire arrays by a direct printing process. Repeated application of the direct printing process can be used to produce organic nanowire-integrated electronics with two- or three-dimensional complex structures on large-area flexible substrates. This efficient manufacturing method is used to fabricate all-organic nanowire field-effect transistors that are integrated into device arrays and inverters on flexible plastic substrates.

  • PDF

Molecular Orbital Calculation for Polymeric Beryllium Hydride, Polyeithylene and Polymeric Boron Hydride According to the Pseudo-Lattice Method

  • Oh, Seok-Heon;Jhang, Man-Chai;Jhon, Mu-Shik
    • Bulletin of the Korean Chemical Society
    • /
    • v.5 no.1
    • /
    • pp.37-41
    • /
    • 1984
  • The pseudolattice calculations in the CNDO/2 level of approximation are carried out for polymeric beryllium hydride, polyethylene and polymeric boron hydride. Since there is no evidence on the geometry for polymeric boron hydride, the two possible geometries are assumed. One is a polyethylene-type geometry and the other is a polymeric beryllium hydride-type geometry. In order to compare their relative stability, we calculate polyethylene and polymeric beryllium hydride and then compare with polymeric boron hydride having the assumed structures. The total energy calculation indicates that a polymeric beryllium bydride-type geometry is more stable than a polyethylene-type geometry. Our results obtained for polyethylene are in good agreement with those given by CNDO/2 crystal orbital. From the convergence problem with respect to the number of unit cells (M), the calculation with value of 4 for M can be considered to give the convergence limit results.