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Bragg's equation,
$\lambda$ =$2d_{hkl}$ $sin\theta$ , tells smaller diffraction angle$(\theta)$ produces larger unit cell, because d spacing ($d_{hkl}$ ) determines unit cell parameters. Douglas, B., McDaniel, D. and Alexander, J. (1993) Concepts and models of inorganic chemistry, pp. 262-264, John Wiley & Sons, New York -
Wilson, R. B., de Meester, P. and Hodgson, D. J. (1977) Structural characterization of bis(L-methionato)zinc(II),
$Zn(L-met)_2$ , Inorg. Chem. 16, 1498-1502 https://doi.org/10.1021/ic50172a052