• Title/Summary/Keyword: Molecular Characteristics

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Control of Pore Characteristics of Porous Glass in the $ZrO_2.SiO_2$ System Prepared by the Sol-Gel Method (졸-겔법으로 제조한 $ZrO_2.SiO_2$다공질유리의 세공제어)

  • 신대용;한상목
    • Journal of the Korean Ceramic Society
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    • v.30 no.6
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    • pp.485-491
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    • 1993
  • Porous glass in the ZrO2.SiO2 system containning up to 30mol% zirconia were prepared by the sol-gel method from metal alkoxides and their pore characteristics with reaction parameters were investigated. The gels were made by hydrolyzing and condensation of the mixed metla alkoxides and were converted into the porous glass by heating up to $700^{\circ}C$. As a results, the mean pore radius became larger with increasing contents of HCl, H2O and hydrolysis temperature, and an alcohol with a large molecular weight for making the porous glass. In the case of 20ZrO2.80SiO2 porous glass with heated at $700^{\circ}C$, HCl and H2O content was 0.3mol and 4mol, the specific surface area was 284$m^2$/g, average mean pore radius was about 19.4$\AA$, porosity was 22.55% and pore characteristics depended on heating temperature.

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Conduction mechanism in organic light-emitting diode in ITO/PEDOT/PSS/TPD/Alq$_3$/LiAl structure (ITO/PEDOT/PSS/TPD/Alq$_3$/LiAl 구조의 유기 발광 소자에서 전도 메카니즘)

  • 정동회;김상걸;정택균;오현석;이원재
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.198-201
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    • 2002
  • We have studied the temperature dependence of current-voltage and luminance-voltage characteristics of Organic Light Emitting Diodes(OLEDs). The OLEDS are based on the molecular compounds, N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1,1'-biphenyl-4,4'-diamine (TPD) as a hole transport, tris(8-hydroxyquinolinoline) aluminum(III) (Alq$_3$) as an electron transport, and poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) as a buffer layer. The current-voltage and luminance-voltage characteristics were measured in the temperature range of 10[K] and 300[K]. A conduction mechanism in OLEDs has been interpreted in terms of space-charge-limited current(SCLC) and tunneling mechanism.

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A qualitative study of photomemory characteristics of the LB monolayer films of merocyanine dye (메로시아닌 색소 LB 단분자막의 광메모리 특성에 관한 정성적 연구)

  • 박태곤;권영수;강도열
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.44 no.7
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    • pp.889-894
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    • 1995
  • The structural changes of the merocyanine monolayer LB (Langmuir Blodgett) films were investigated. These changes were compared with the typical changes of the molecular structures of merocyanine solutions. The structural changes of quinoid/benzenoid were attained by exposure to atmosphere gases (HCl gas, N $H_{3}$ gas). The photoisomerization was not observed for the monolayer LB film due to their state of $M_{trans}$. But we could obtain the cis/trans photoisomerization characteristics reversibly, after the films were changed to M $H^{+}$$_{trans}$ structure by exposure to HCl gas. We also found that the cis/trans photoisomerization of the LB monolayer films show the memory characteristics.s.

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Evaluation of Jacket Compounds for Underground Distribution Power Cables (지중 배전케이블용 자켓 컴파운드의 특성평가)

  • 한재홍;송일근;김동명;이재봉;정창수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.8
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    • pp.687-694
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    • 2002
  • In order to replace the jacket material for URD power cables, the 6 kinds of polyethylene compounds were manufactured and evaluated. The characteristics of the compounds were investigated by water vapor transmission (WVT) test, thermal and mechanical test. In WVT test, all the polyethylene compounds showed the superior water resistance to conventional PVC. The molecular structure and density of polyethylene play an important role in WVT. Also, the polyethylene compounds showed the suitable characteristics in thermal and mechanical test. Especially, the linear polyethylene compounds showed the superior characteristics to LDPE ones. Due to the fillers in compounds, the abrasion resistance was decreased and the cut-through resistance was increased. From this study, it can be considered that the polyethylene compounds may be suitable to jacket material for URD power cables.

Macroscopic Breakup Characteristics of Water Gel Simulants with Triplet Impinging Spray Jet (젤 모사 추진제 삼중 충돌 분사 제트의 거시적 분열 특성 연구)

  • Hwang, Tae-Jin;Lee, In-Chul;Koo, Ja-Ye
    • Journal of ILASS-Korea
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    • v.15 no.3
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    • pp.109-114
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    • 2010
  • The implementation of gelled propellants systems offers high performance, energy management of liquid propulsion, storability, and high density impulse of solid propulsion. The present study focused on the macroscopic spray characteristics of liquid sheets formed by triplet impinging jets of non-Newtonian liquids which are mixed by Carbopol 941 0.5%wt. The results are compared to experiments conducted on spray images which formed by triplet impinging jets concerning with airassist effect at center orifice. When gel propellants are injected by doublet impinging jets at low pressure and high pressure, closed rim pattern shape appeared by polymeric effect from molecular force and showed inactive atomization characteristics, because of extensional viscosity related by restriction of atomization process and breakup time delay of turbulence transition. As increasing mass flow rate of the air(increasing GAR), spray breakup level is also increased.

Temperature-dependent current-voltage characteristics of Organic Light-Emitting Diodes(OLEDs) (온도 변화에 따른 유기 전기 발광 소자의 전기적 특성)

  • Lee, Ho-Sik;Chung, Taekk-Gyun;Kim, Sang-Keol;Jung, Dong-Hoe;Jang, Kyung-Wook;Lee, Won-Jae;Kim, Tae-Wan;Lee, Joon-Ung;Kang, Dou-Yol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.370-373
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    • 2001
  • Temperature-dependent current-voltage characteristics of Organic Light-Emitting Diodes(OLEDs) were studied. The OLEDs were based on the molecular compounds, N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1,1'-diphenyl-4,4'-diamine (TPD) as a hole transport and tris(8-hydroxyquinoline) aluminum($Alq_3$) as an electron transport and emissive material. The current-voltage characteristics were measured in the temperature range of 10[K] and 300[K]. A conduction mechanism in OLEDs was interpreted in terms of tunneling and trap-filled limited current.

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Development of Jacket Compounds for URD Power Cables (지중 케이블용 외피 컴파운드 개발)

  • Han, Jae-Hong;Kim, Ju-Yong;Kim, Dong-Myung;Song, Il-Keun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05c
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    • pp.7-10
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    • 2002
  • In this study, polyolefin compounds were developed and evaluated for replacing a jacket material of URD power cables. The characteristics of compounds were investigated by water vapor transmission (WVT) test and mechanical test. In WVT test, all polyolefin compounds showed the superior water resistance to conventional PVC. The molecular structure and density of polyolefin play an important role in WVT. Also, polyolefin compounds showed the suitable characteristics in mechanical test. Especially, polyolefin compounds having linear molecules showed the superior characteristics to LDPE ones. From this study, it can be considered that polyolefin compounds may be suitable to jacket material for URD power cables.

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Optoelectronic Characteristics of Hydrogen and Oxygen Annealed Si-O Superlattice Diode

  • Seo, Yong-Jin
    • Transactions on Electrical and Electronic Materials
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    • v.2 no.2
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    • pp.16-20
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    • 2001
  • Optoelectronic characteristics of the superlattice diode as a function of deposition temperature and annealing conditions have been studied. The multilayer nanocrystalline silicon/adsorbed oxygen (nc/Si/O) superlattice formed by molecular beam epitaxy (MBE) system. Experimental results showed that deposition temperature of 550$^{\circ}C$, followed by hydrogen annealing leads to best results, in terms of optical photoluminescence (PL) and electrical current-voltage (I-V) characteristics. Consequently, the experimental results of multilayer Si/O superlattic device showed the stable photoluminescence and good insulating behavior with high breakdown voltage. This is very useful promise for Si-based optoelectronic devices, and can be readily integrated with conventional silicon ULSI processing.

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Characteristics of Bio-diesel according to Irradiation for Ultrasonic Energy (초음파 에너지 조사에 따른 바이오 디젤 특성)

  • Park, Chungyeol;Choi, Dooseuk
    • Transactions of the Korean Society of Automotive Engineers
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    • v.23 no.2
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    • pp.214-220
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    • 2015
  • Since resources of fossil fuels are limited, development of alternative energies is emphasized and research on new-regenerative energy is actively in progress worldwide. In present research, physical and chemical characteristics of mixed fuel are analyzed in detail for the different mixture rate of conventional and bio-diesel and ultrasonic irradiation time. Experimental setup consists of ultrasonic generator, vibrator, horn, and reflector. Various physical and chemical characteristics of fuel are investigated for volumetric mixture rate of bio-diesel from 0 to 100%. As results, viscosity and surface tension is increased as mixture rate of bio-diesel is increased. Also, molecular splits and reunions are increased and decreased repeatedly after some period of time as ultrasonic energy irradiation time is increased. As conclusion of experiments, Olefin rate, Branch index, and Aromatic rate are influenced by ultrasonic irradiation time.

Excitation Energy Transfer Rate Constants in meso-meso Linked Zn(II) Porphyrin Arrays with Energy Accepting 5,15-Bisphenylethynylated Zn(II) Porphyrin

  • Ko, Da-Mee;Kim, Hee-Young;Park, Jin-Hee;Kim, Dong-Ho;Sim, Eun-Ji
    • Bulletin of the Korean Chemical Society
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    • v.26 no.10
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    • pp.1505-1511
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    • 2005
  • The excitation energy transfer process occurring in energy donor-acceptor linked porphyrin array system is theoretically simulated using the on-the-fly filtered propagator path integral method. The compound consists of an energy donating meso-meso linked Zn(II) porphyrin array and an energy accepting 5,15-bisphenylethynylated Zn(II) porphyrin, in which the donor array and the acceptor are linked via a 1,4-phenylene spacer. Real-time path integral simulations provide time-evolution of the site population and the excitation energy transfer rate constants are determined. Simulations and experiments show an excellent agreement indicating that the path integration is a useful tool to investigate the energy transfer dynamics in molecular assemblies.