• Title/Summary/Keyword: Molecular Characteristics

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Synthesis of Organic EL Materials with Cyano Group and Evaluation of Emission Characteristics in Organic EL Devices (시안기를 가진 유기 EL 물질들의 합성 및 유기 EL 소자에서의 발광특성평가)

  • Kim, Dong Uk
    • Journal of the Korean Chemical Society
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    • v.43 no.3
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    • pp.315-320
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    • 1999
  • Novel electroluminescent materials, polymer material, PU-BCN and low molar mass material, D-BCN with the same chromophores were designed and synthesized. A molecular structure of chromophore was composed of bisstyrylbenzene derivative with cyano groups as electron injection and transport and phenylamine groups as hole injection and transport. Device structures with PU-BCN and D-BCN as an emission layer were fa-bricated, which were a single-layer device(SL), Indium-tin oxide(ITO)/emission layer/MgAg, and two kinds of double-layer devices which were composed of ITO/emission layer/oxadiazole derivative/MgAg as a DL-E device and ITO/triphenylamine derivative/emission layer/MgAg as a DL-H device. The two emission materials, PU-BCN and D-BCN with the same emission-chromophore were evaluated as having excellent performance of charge injection and transport and revealed almost the same emission characteristics in high current density. EL emission maximum peaks of two material were detected at about 640 nm wavelength of red emission region.

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Studies on the biochemical characteristics and plasmid profiles of Salmonella typhimurium isolated from pigeons and aquatic birds (비둘기 및 수생조류(水生鳥類) 유래(由來) Salmonella typhimurium의 생물화학적(生物化學的) 특성(特性)과 plasmid profile에 관(關)한 연구(硏究))

  • Park, No-chan;Choi, Won-pil
    • Korean Journal of Veterinary Research
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    • v.30 no.2
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    • pp.203-214
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    • 1990
  • A total of 166 strains of Salmonella (S) typhimurium var copenhagen isolated from pigeons (164 strains) and aquatic birds (2 strains) were examined for the biochemical characteristics and plasmid profiles. All the strains were sensitive to ampicillin, chloramphenicol, gentamicin, kanamycin and sulfadimethoxine. But 13 strains(7.8%) were resistant to streptomycin (Sm), 2 (1.2%) to tetracycline, 2 (1.2%) to rifampicin, and 1 (0.6%) to nalidixic acid. Among drug resistant strains, only one strain resistant to Sm contained conjugative R plasmid which was fertility inhibition and incompatibility group $I_{\alpha}$. All the strains were sensitive to cobalt chloride, cupric sulfate, lead nitrate, mercuric chloride and silver nitrate. Of 166 isolates, 6 (3.6%) were resistant to sodium arsenate and 1 (0.6%) to potassium tellurite. Among 166 isolates, 1 (0.6%) was colicinogenic, 12 (7.2%) sucrose fermenters, and 166 (100%) maltose fermenters. Plasmid profiles were confirmed as being 4 or 5 plasmids, and their molecular weight ranged 3.2 to 60 megadalton (MD). All the strains harbored 60 Md plasmid. There are three patterns by the plasmid profile, 150 isolates (90.4%) were pattern I (3.2, 3.5, 33, 60Md), 14 (8.4%) pattern II (3.2, 3.5, 29, 60Md), and 2 (1.2%) pattern III (4.2, 7.8, 8.5, 15, 60Md). S typhimurium var copenhagen strains containing 60Md plasmid were resistant to killing by 90% normal guinea pig serum.

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Prevalence and Characteristics of Antimicrobial-Resistant Staphylococcus aureus and Methicillin-Resistant Staphylococcus aureus from Retail Meat in Korea

  • Kim, Yong Hoon;Kim, Han Sol;Kim, Seokhwan;Kim, Migyeong;Kwak, Hyo Sun
    • Food Science of Animal Resources
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    • v.40 no.5
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    • pp.758-771
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    • 2020
  • This study was to investigate the prevalence and characteristics of antimicrobial-resistant Staphylococcus aureus and methicillin-resistant S. aureus (MRSA) from 4,264 retail meat samples including beef, pork, and chicken in Korea between 2013 and 2018. A broth microdilution antimicrobial susceptibility testing was performed for S. aureus. Molecular typing by multilocus sequence typing (MLST), spa typing, and pulsed-field gel electrophoresis (PFGE), was performed on mecA-positive S. aureus strain. S. aureus was isolated at a rate of 18.2% (777/4,264), of which MRSA comprised 0.7% (29 strains). MLST analysis showed that 11 out of the 29 MRSA isolates were predominantly sequence type (ST) 398 (37.9%). In addition, ST72, ST692, ST188, ST9, and ST630 were identified in the MRSA isolates. The spa typing results were classified into 11 types and showed a high correlation with MLST. The antimicrobial resistance assays revealed that MRSA showed 100% resistance to cefoxitin and penicillin. In addition, resistance to tetracycline (62.1%), clindamycin (55.2%), and erythromycin (55.2%) was relatively high; 27 of the 29 MRSA isolates exhibited multidrug resistance. PFGE analysis of the 18 strains excluding the 11 ST398 strains exhibited a maximum of 100% homology and a minimum of 64.0% homology. Among these, three pairs of isolates showed 100% homology in PFGE; these results were consistent with the MLST and spa typing results. Identification of MRSA at the final consumption stage has potential risks, suggesting that continuous monitoring of retail meat products is required.

Effect of pHs on Morphological and Cultural Characteristics of Alkalophilic Coryneform Bacteria TU-19 (호알칼리성 Coryneform Bacteria TU-19의 형태적, 배양적 특성에 미치는 pH효과)

  • Choi, Myoung-Chul;Yang, Jae-Sub;Hwang, Cher-Won;Kang, Sun-Chul
    • Applied Biological Chemistry
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    • v.41 no.5
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    • pp.337-341
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    • 1998
  • The morphological and cultural characteristics of alkalophilic Coryneform bacteria TU-19 were investigated at various pHs. This bacterium showed normal growth pattern at $pH\;9.0{\sim}10.0$, but the cell growth was completely inhibited at extreme pH (12.0 or more). Interestingly, at pH 8.0 the morphology of the bacterial cells seems to form convoluted filaments during the exponential growth phase while at pH 10.0, the optimal pH for the growth of this organism, the bacteria grew with variable paired or single forms, and straight rods during growth stages. Growing in alkaline media $(pH\;9.0{\sim}11.0)$, it adjusted the pH of the culture media to around pH 8.5 by itself.

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Purification of Alkaline Restriction Endonuclease from Alkalophilic Bacillus sp. 8-13 (제한효소 생성능을 지닌 알칼리성 Bacillus sp. 8-13 균주로부터 알칼리성 제한효소의 정제)

  • Bae, Moo;Lee, Jee-Eun;Park, Kyoung-Sook;Lee, Kang-Man
    • Microbiology and Biotechnology Letters
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    • v.20 no.3
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    • pp.289-294
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    • 1992
  • Twenty-four bacterial strains among alkalophillic bacteria isolated from soil samples were examined for the presence of type II restriction endonuclease in aerobic culture. One strain was found to contain specific enzyme to cleave lambda DNA. The characteristics of this microorganism is the ability to grow well in alkalophilic and high temperature condition, that is at pH 10.3 and $50^{\circ}C$. This strain was tentatively identified to Bacillus alkaloPhilus subsp. halodurans when morphological, physiological and biochemical characteristics were examined. The enzyme was purified from crude extract by streptomycin sulfate, ammonium sulfate precipitation, which was followed by DEAE-cellulose and phosphocellulose ion exchange column chromatography, and the subunit molecular weight was about, 32,000 daltons by polyacrylamide gel electrophoresis containing 0.1% SDS.

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The Evaluation of Adsorption Characteristics of Perfluorinated Compounds (PFCs) in GAC Process Using Continuous Column Adsorption Test (연속 컬럼흡착 실험을 이용한 GAC 공정에서의 과불화 화합물(PFCs) 흡착 특성 평가)

  • Son, Hee-Jong;Yoo, Soo-Jeon;Jang, Seung-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.3
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    • pp.206-212
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    • 2013
  • This study accessed the adsorption characteristics of the 11 perfluorinated compounds (PFCs) on coal-based granular activated carbon (GAC). The breakthrough appeared first for PFODA and sequentially for PFHDA, PFTeDA, PFTDA, PFDoDA, PFUnDA, PFDA, PFNA, PFOA, PFOS, and PFHpA. The maximum adsorption capacity (X/M) for the 11 PFCs with apparent breakthrough points ranged from 2.43 ${\mu}g/g$ (for PFODA) to 64.5 ${\mu}g/g$ (for PFHpA). Carbon usage rate (CUR) for PFODA was 0.291 g/day, 11.2 times higher than that for PFHpA (0.026 g/day). The X/M values for the 11 PFCs were fitted well with a linear regression ($r^2$ = 0.89) by their molecular weight (chain length).

Characteristics of High Strength Polyethylene Tape Yarns and Their Composites by Solid State Processing Methods (고상공정법에 의한 고강도 폴리에틸렌 테이프사와 그 복합재료의 특성)

  • Lee, Seung-Goo;Cho, Whan;Joo, Yong-Rak;Song, Jae-Kyung;Joo, Chang-Whan
    • Composites Research
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    • v.12 no.2
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    • pp.91-100
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    • 1999
  • The manufacture of high strength polyethylene(HSPE) tape yarns has been accomplished by a solid state processing(SSP) method as the compaction of ultra-high molecular weight polyethylene(UHMWPE) powders and drawing of the compacted film under the melting point without any organic solvents. In this study, the characteristics of HSPE tape yarns produced by SSP which is desirable for production cost and environmental aspect were analyzed. As the results, tensile strengths of HSPE tape yarns increased with increasing the draw ratio and the fracture morphology of highly drawn HSPE tape yarns showed more fibrillar shape than the low drawn one. Interfacial shear strengths of HSPE tape yarns with vinylester resin increased by $O_2$ plasma treatment and maximum interfacial shear strength was obtained in the plasma treatment condition of 100W and 5min. In addition, mechanical properties of HSPE tape yarn reinforced composites were investigated and compared with those of the gel spun HSPE fiber reinforced composites.

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Antioxidative Characteristics of Browning Reaction Products of Glucose-Poly-${\gamma}$-Glutamate (GIu-PGA) obtained from Amino-carbonyl Reaction (Amino-carbonyl 반응에 의한 glucose-poly-${\gamma}$-glutamate (Glu-PGA) 갈변 반응물질의 항산화적 특성 연구)

  • Lee, Nam-Keun;Hahm, Young-Tae
    • Korean Journal of Food Science and Technology
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    • v.37 no.5
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    • pp.812-815
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    • 2005
  • Effects of poly-${\gamma}$-glutamate (PGA) on antioxidative characteristics of amino-carbonyl reaction products of glucose were investigated. Rapid browning reaction was observed under heat and alkaline condition (pH 8.2). Browning products were separated by Sephadex G-50, and brown color intensity and electron-donating ability of DPPH (2,2-diphenyl-1-picrylhydrazyl) of each fraction were measured. Fraction-7 (F-7) and -20 (F-20) showed high DPPH scavenging values. UV-VIS absorption spectrum of F-20 was similar to melanoidin peak, and F-7 showed maximum absorption peak at 270 nm. Molecular weight of F-7 was over 35 kDa as determined by SDS-PAGE. Although F-20 could not be measured on SDS-PAGE, its size was smaller than F-7.

Effect of Neutral Ligand(L) on the Precursor Characteristics of (hfac)Cu(I)L and on Cu MOCVD Process (중성리간드(L)가 (hfac)Cu(I)L 전구체의 특성 및 구리 MOCVD 공정에 미치는 영향)

  • 최경근;김경원;이시우
    • Korean Journal of Materials Research
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    • v.11 no.3
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    • pp.184-184
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    • 2001
  • The effect of neutral ligand(L) on the precursor characteristics of (hfac)Cu(I)-L and on Cu MOCVD Process was studied. The neutral ligands of (hac)Cu(I)-L$_{x}$, such as ATMS(allytrimethylsilane), VTMS(vinyltrimethylsilane), VCH(vinylcyclohexane), MP(4-methyl-1-pentene), ACP(allylcyclopentane), and DMB(3,3-dimethyl-1-butene) were investigated. When the dissociation temperature of Cu(I)-L bond is low, low temperature deposition below $100^{\circ}C$ is possible and the resistivity of the film is low. But thermal stability of the precursor is low in this case. The resistivity is almost the same regardless of L at the deposition temperature range of $125~175^{\circ}C$. The resistivity is increased as the molecular weight of L becomes higher above $225^{\circ}C$ The vapor pressure of the precursor was closely related to the boiling point of L, the lower the boiling point of L, the higher the vapor pressurere.

Effect of Neutral Ligand(L) on the Precursor Characteristics of (hfac)Cu(I)L and on Cu MOCVD Process (중성리간드(L)가 (hfac)Cu(I)L 전구체의 특성 및 구리 MOCVD 공정에 미치는 영향)

  • Choe, Gyeong-Geun;Kim, Gyeong-Won;Lee, Si-U
    • Korean Journal of Materials Research
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    • v.11 no.3
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    • pp.185-190
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    • 2001
  • The effect of neutral ligand(L) on the precursor characteristics of (hfac)Cu(I)-L and on Cu MOCVD Process was studied. The neutral ligands of (hac)Cu(I)-L$_{x}$, such as ATMS(allytrimethylsilane), VTMS(vinyltrimethylsilane), VCH(vinylcyclohexane), MP(4-methyl-1-pentene), ACP(allylcyclopentane), and DMB(3,3-dimethyl-1-butene) were investigated. When the dissociation temperature of Cu(I)-L bond is low, low temperature deposition below $100^{\circ}C$ is possible and the resistivity of the film is low. But thermal stability of the precursor is low in this case. The resistivity is almost the same regardless of L at the deposition temperature range of $125~175^{\circ}C$. The resistivity is increased as the molecular weight of L becomes higher above $225^{\circ}C$ The vapor pressure of the precursor was closely related to the boiling point of L, the lower the boiling point of L, the higher the vapor pressurere.

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