• Title/Summary/Keyword: Molecular Characteristics

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New red light-emitting copolymer based on polyfluorene

  • Cho, Nam-Sung;Hwang, Do-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.721-723
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    • 2002
  • We report a new red light emitting fluorene-based copolymer, poly{9,9-bis(2'-ethylhexyl)fluorene-2,7-diyl-co-2, 5-bis(2-thienyl-1-cyanovinyl}-1-(2'-ethylhexyloxy)-4methoxybenzene-5",5'''-diyl} (PFTCVB). The synthesized copolymers showed the absorption maxima at about 380 nm and the absorption between 425 and 600 nm increased as the fraction of the thiophene-containing monomer (BTCVB) increased. In PL, the emission maxima of the copolymers were red-shifted as the fraction of BTCVB increased, despite the similar absorption characteristics were shown in the UV-visible spectra. The copolymer containing 15 mol% of BTCVB showed a maximum PL and EL emission at 620 and 630 nm.

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Electro-optic Properties of Holographic PDLC with Various PUA Structures

  • Park, Min-Sang;Kim, Eun-Hee;Woo, Ju-Yeon;Kim, Byung-Kyu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.437-440
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    • 2002
  • Characteristics of holographic polymer dispersed liquid crystal(HPDLC) were studied according to various matrix materials to improve the electro-optic properties. Various types of polyurethane acrylates (PUAs) have been designed and synthesized. The morphologies of these gratings were measured by atomic force microscopy(AFM) and electro-optic properties were obtained with UV-visible spectroscopy. Real time measurements of grating fabrication have been obtained according to PUA structures. High reflection efficiency was obtained by modifying the molecular structure.

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The Effect of Chitosan on the Rheological Properties of Soymilk and Quality Characteristics of Tofu

  • Han, Jin-Suk;Kim. Mee-Ra
    • Preventive Nutrition and Food Science
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    • v.10 no.3
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    • pp.224-230
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    • 2005
  • The effects of low viscosity chitosan on the rheological properties of soymilk using a model system and on tofu qualities were examined. The flow behavior of soy milk with chitosan closed the Newtonian flow and stabilized according to increasing chitosan concentration. The soymilk containing $glucono-\delta-lactone$ exhibited a more pseudoplastic flow behavior compared with that of the control soymilk. The addition of low viscosity chitosan to the tofu preparation did not significantly affect its physicochemical properties. However, the results of the TEM image and instrumental textural properties showed that low viscosity chitosan affected the construction of the tofu structure. Chitosan tofu had low scores across the whole field of appearance in the sensory evaluation, and its overall eating quality was scored significantly lower. These results suggest that the addition of low viscosity chit os an affects the quality of tofu, which changes according to the degree of polymerization and concentration of chitosan.

LGMD2E with a novel nonsense variant in SGCB gene: a case of LGMD2E with a novel variant

  • La, Yun Kyung;Oh, Eun Kyoung;Lyou, Hyun Ji;Hong, Ji Man;Choi, Young-Chul
    • Annals of Clinical Neurophysiology
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    • v.22 no.1
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    • pp.29-32
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    • 2020
  • Sarcoglycanopathies are a rare group of autosomal recessive limb-girdle muscular dystrophies (LGMDs) caused by genetic variants in α-, β-, γ-, or δ-sarcoglycan that maintain membrane integrity and contribute to molecular signal processing. High-throughput nucleotide sequencing was performed in patients with slowly progressive proximal muscle weakness from early childhood with respiratory involvement, which detected a novel homozygous nonsense variant (c.601C>T;p.Gln201Ter) in SGCB. This report informs about the clinical characteristics of LGMD2E (type-2E LGMD) in Korea and provides genetic confirmation of the disease.

Purification and Characterization of Proteinaceous ${\beta}-Lactamase$ Inhibitor from the Culture Broth of Streptomyces sp. SMF-19

  • Kim, Myung-Kuk;Kang, Hee-Il;Lee, Kye-Joon
    • Journal of Microbiology and Biotechnology
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    • v.1 no.2
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    • pp.85-89
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    • 1991
  • The aim of this study is to elucidate characteristics of ${\beta}-lactamase$ inhibitor produced by Streptomyces sp. SMF-19 isolated from soil was found to produce proteinaceous extracellular ${\beta}-lactamase$ inhibitor. The ${\beta}-lactamase$ inhibitor was purified through ammonium sulfate fractionation, gel filtration, anion exchange chromatography and fast performace liquid chromatography. The molecular weight of the ${\beta}-lactamase$ inhibitor was estimated to be about 48,000 by SDS-PAGE. The mode of inhibition against penicillin G as a substrate was uncompetitive. The ${\beta}-lactamase$ inhibitor was stable in wide pH range but unstable at high temperature above $50^{\circ}C$.

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Development of Transport Parameters affecting on the Removal of Micro Organic Compounds such as Disinfection By-Products and Pharmaceutically Active Compounds by Low-Pressure Nanofiltration

  • Oh, Jeong-Ik;Yamamoto, Kazuo
    • Environmental Engineering Research
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    • v.14 no.2
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    • pp.126-133
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    • 2009
  • This study investigated the removal characteristics of various micro organic compounds by low-pressure nanofiltration membranes comprised of disinfection by products and pharmaceutically active compounds. The experimental removal of micro organic compounds by low-pressure nanofiltration membranes was compared with the transport model calculations, which consist of diffusion and convection terms including steric hindrance factor. The selected molecule from the disinfection byproducts and pharmaceutical active compounds showed a much lower removal than polysac-charides with a similar molecular size. However,the difference between model calculation and experimental removal of disinfection by-products and pharmaceutically active compounds could be corrected. The correlation of Ks with solute radius was further considered to clarity transport phenomena of micro organic solutes through nanofiltration membranes.

Effect of constitutive equations on theoretical analysis in melt spinning process

  • Kim, Seong-Cheol;Oh, Tae-Hwan;Han, Sung-Soo;Lyoo, Won-Seok
    • Korea-Australia Rheology Journal
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    • v.21 no.3
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    • pp.149-153
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    • 2009
  • Profile development of the melt spinning process of poly(ethylene terephthalate) (PET) was simulated by a numerical method under the consideration of two constitutive equations of Newtonian and upper convected Maxwell (UCM) models. The viscoelastic characteristics of the polymer were considered via UCM constitutive equation that considered relaxation time as a function of temperature and molecular weight. The UCM model predicted the diameter profile better than the Newtonian, while velocity development was slower than the Newtonian model. Viscoelasticity played an important role in accurately predicting diameter profile. However, even though neck-like deformation was observed in the UCM model, the exact position of the deformation under high speed spinning was not obtained.

Surface Modification of Automobile Rubber by Various Plasma Treatments

  • Lee, Seung-Hun;Kim, Seock-Sam
    • KSTLE International Journal
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    • v.9 no.1_2
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    • pp.26-30
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    • 2008
  • This study examined the surface modification characteristics of NBR using sealing in automobile. Surfaces of NBR were modified by RF power Ar plasma treatment. In experiment, pressure, flux, temperature were fixed and RF bias voltage. Treatment time was changed. In friction test, we used PTFE grease. After modification, surfaces of NBR showed many grooves, hydrophilic functional groups, and lipophilic functional groups. As increasing treating voltage and time, the amount of them was increased. And wetting angle and friction coefficient was decreased with increasing treating voltage and time. However, the pattern of changing friction coefficient was not fixed.

Phylogeny, host-parasite relationship and zoogeography

  • Hasegawa, Hideo
    • Parasites, Hosts and Diseases
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    • v.37 no.4
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    • pp.197-213
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    • 1999
  • Phylogeny is the evolutionary history of a group or the lineage of organisms and is reconstructed based on morphological, molecular and other characteristics. The genealogical relationship of a group of taxa is often expressed as a phylogenetic tree. The difficulty in categorizing the phylogeny is mainly due to the existence of frequent homoplasies that deceive observers. At the present time, cladistic analysis is believed to be one of the most effective methods of reconstructing a phylogenetic tree. Excellent computer program software for phylogenetic analysis is available. As an example, cladistic analysis was applied for nematode genera of the family Acuariidae, and the phylogenetic tree formed was compared with the system used currently. Nematodes in the genera Nippostrongylus and Heligmonoides were also analyzed, and the validity of the reconstructed phylogenetic trees was observed from a zoogeographical point of view. Some of the theories of parasite evolution were briefly reviewed as well. Coevolution of parasites and humans was discussed with special reference to the evolutionary relationship between Enterobius and primates.

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PreSMo Target-Binding Signatures in Intrinsically Disordered Proteins

  • Kim, Do-Hyoung;Han, Kyou-Hoon
    • Molecules and Cells
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    • v.41 no.10
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    • pp.889-899
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    • 2018
  • Intrinsically disordered proteins (IDPs) are highly unorthodox proteins that do not form three-dimensional structures under physiological conditions. The discovery of IDPs has destroyed the classical structure-function paradigm in protein science, 3-D structure = function, because IDPs even without well-folded 3-D structures are still capable of performing important biological functions and furthermore are associated with fatal diseases such as cancers, neurodegenerative diseases and viral pandemics. Pre-structured motifs (PreSMos) refer to transient local secondary structural elements present in the target-unbound state of IDPs. During the last two decades PreSMos have been steadily acknowledged as the critical determinants for target binding in dozens of IDPs. To date, the PreSMo concept provides the most convincing structural rationale explaining the IDP-target binding behavior at an atomic resolution. Here we present a brief developmental history of PreSMos and describe their common characteristics. We also provide a list of newly discovered PreSMos along with their functional relevance.