• Title/Summary/Keyword: Modified polyethylene coating

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Experimental Study on the Adhesion and Performance Evaluation of Joints for Modified Polyethylene Coated Steel Pipes (개질 폴리에틸렌 코팅 강관의 부착 및 체결부 성능 평가 연구)

  • Myung Kue Lee;Sanghwan Cho;Min Ook Kim
    • Composites Research
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    • v.37 no.3
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    • pp.238-245
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    • 2024
  • In this study, as part of the development of a monitoring system for the efficient maintenance of steel pipes, an experimental study was conducted to evaluate the performance of steel pipes treated with modified polyethylene coating. In the case of the conventional mechanical pre-coating method, there was a deterioration in polyethylene adhesion during expansion testing, which led to the application of a chemical pre-treatment process using a calcium-mixed phosphate zinc film to resolve this issue. SEM and EDX analyses showed that the densest structure was observed at a Zn/Ca ratio of 1.0, and improved heat resistance compared to the conventional method was confirmed. Additionally, to prevent coating detachment during expansion, an evaluation of adhesion and elongation was conducted on steel pipes with modified polyethylene coating, incorporating materials such as elastomers based on maleic anhydride grafting, metal oxides, blocking agents, and slip agents. Experimental results showed that the specimen (S4) containing all modified materials exhibited more than a 25% performance improvement compared to the specimen (S2) containing only metal oxides. Lastly, the development and performance evaluation of wedge-shaped socketing and pressing wheels, which are part of the pipe fixing accessories, were conducted to prevent surface coating damage on the completed pipes.

Hydrophilic Modification of Polypropylene Hollow Fiber Membrane by Dip Coating, UV Irradiation and Plasma Treatment

  • Kim Hyun-Il;Kim Jin Ho;Kim Sung Soo
    • Korean Membrane Journal
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    • v.7 no.1
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    • pp.19-27
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    • 2005
  • PP hollow fiber membrane was hydrophilized by EVOH dip coating followed by low temperature plasma treatment and UV irradiation. EVOH coating attained high water flux without any prewetting but its stability did not guaranteed at high water permeation rate. At high water permeation rate, water flux declined gradually due to swelling and delamination of the EVOH coating layer causing pore blocking effect. However, plasma treatment reduces the swelling, which suppress delamination of the EVOH coating layer from PP support result in relieving the flux decline. Also, UV irradiation helped the crosslinking of the EVOH coating layer to enhance the performance at low water permeation rate. FT-IR and ESCA analyses reveal that EVOH dip coating performed homogeneously through not only membrane surface but also matrix. Thermogram of EVOH film modified plasma treatment and W irradiation show that crosslinking density of EVOH layer increased. Chemical modification by plasma treatment and UV irradiation stabilized the hydrophilic coating layer to increase the critical flux of the submerged membrane.

Performance Evaluation of Molten Metal Splash Protective Fabrics (용융금속 방호보호복소재의 성능수준 평가)

  • Park, Pyoung-Kyu;Jin, Lu;Yoon, Kee-Jong
    • Korean Journal of Hazardous Materials
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    • v.6 no.2
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    • pp.55-61
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    • 2018
  • In this study, the molten metal protective performance of various molten metal protective clothing materials such as herringbone twill laminated aluminium foils, oxydized-polyacrylonitrile laminated with aluminium deposited polyethylene terephthalate films, twill fabric laminated with aluminium deposited polyethylene terephthalate films and nonwoven laminated with aluminum deposited polyethylene terephthalate films, were evaluated according to modified EN ISO 9185. The results showed that the molten metal protective performance of tested samples improved with the increase in fabric structure density, weight and thickness. In addition the effect of the thickness of aluminum foil on the molten metal protective performance is not significant. It was found the fabric is more important in the molten metal splash protective clothing.

Micro/Nano Adhesion and Friction Characteristics of PTFE Coating Film Deposited by IBAD Method (IBAD 방법으로 코팅된 PTFE 박막의 마이크로/나노 응착 및 마찰 특성)

  • 윤의성;오현진;한흥구;공호성;장경영
    • Tribology and Lubricants
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    • v.20 no.5
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    • pp.237-244
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    • 2004
  • Micro/nano tribological characteristics of PTFE coating films were experimentally studied. PTFE (polytetrafluoroethylene) modified polyethylene and low molecular weight PTFE were used as a coating materials. These films were deposited on Si-wafer (100) by IBAD (ion beam assisted deposition) method. The Ar ion beam sputtering was performed to change the surface topography of films using a hollow cathode ion gun under different Ar ion dose conditions in a vacuum chamber. Micro/nano tribological characteristics, water wetting angles and roughness were measured with a micro tribotester, SPM (scanning probe microscope), contact anglemeter and profilometer, respectively. The durability of the films were measured with macro tribotester. Results showed that the PTFE coating surfaces were converted to hydrophobic. The water contact angle of coated surfaces and surface roughness increased with the coating thickness. Adhesion and friction in micro and nano scale were governed by magnitude of normal load in soft material such as PTFE films. As the increase of sputtering time on low molecular weight PTFE films, the surface roughness was increased and nano adhesion and friction were decreased. The nano tribological characteristics of surfaces are mainly improved by chemical modification such as PTFE coating and given a synergy effect by the physical modification such as topographic modification.

A Study on the bioactive surface modification of PEEK intervertebral fusion cage using various coating techniques (다양한 코팅 처리에 의한 PEEK 추간체유합보형재의 생체 활성 표면에 관한 연구)

  • Su-Bin Noh;Su-Zy Park;Mun-Hwan Lee
    • Journal of the Korean institute of surface engineering
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    • v.56 no.4
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    • pp.273-282
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    • 2023
  • In this study, the surface of Polyetheretherketone (PEEK) disks was modified to have a hydrophilic surface by applying a coating of Polyethylene glycol (PEG), Hyaluronic acid(HA), and Poly-Dopamine(PDA). The investigation aimed to examine whether the coated surfaces showed enhanced bioactivity for orthopedic applications compared to the pure PEEK. The microstructure, surface characteristics, and wettability of PEEK coated with PEG, HA, and PDA were analyzed using scanning electron microscopy(SEM), FT-IR spectrophotometer, Roughness Measurement System, Micro-Vickers, and Contact angle measurement. The mechanical properties were analyzed using a tensile testing machine, while the MTT assay for cell activity was analyzed using a microplate reader to measure optical density. According to the SEM and FT-IR results, the composition and crystal structure of PEG, HA and PDA coated surface were verified. Also, roughness, hardness, and contact angle were all improved in the coating group compared to the pure PEEK. We checked the HepG2 cell proliferation by using MTT assay on 7th days. In MTT assay results, HepG2 cell proliferation was increased with time, at 7 days, cell viability on discs coated with PDA was significantly higher than pure PEEK, PEG, HA coated group. PDA coated PEEK exhibited the highest surface roughness, hardness, contact angle, and cell activity. The mechanical properties were not affected by the presence of the coating.

Fabrication of $(La, Sr)MO_3$ (M=Mn or Co)/YSZ Nanocomposite Thin Film Electrodes for the Exhaust Gas Purification by a Chemically-Modified Sol-Gel Process

  • Hwang, H.J.;Moon, J.W.;Awano, M.;Maeda, K.
    • Journal of Powder Materials
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    • v.8 no.3
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    • pp.201-206
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    • 2001
  • $>LaMnO_3$$(La, Sr)MO_3$, and $(La, Sr)MO_3/YSZ$ gel films were deposited by spin-coating technique on scandium-doped zirconia (YSZ) substrate using the precursor solution prepared from $La(O-i-C_3H_7)_3$, $Co(CH_3COO)_2$or $Mn(O-i-C_3H_7)_2$,2-methoxyethanol, and polyethylene glycol. By heat-treating the gel films, the electrochemical cells, $(La, Sr)MnO_3{\mid}ScSZ{\mid}Pt$ were fabricated. The effect of polyethylene glycol on the microstructure evolution of $$LaCoO_3and $LaMnO_3$thin films was investigated, and NOx decomposition characteristics of the electrochemical cells were investigated at $500^{\circ}C$ to $600^{\circ}C$. By applying a direct current to the $(La, Sr)MnO_3{\mid}ScSZ{\mid}Pt$ electrochemical cell, good NOx conversion rate could be obtained relatively at low current value even if excess oxygen is included in the reaction gas mixture.

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Characterization of Ceramic Composite-Membranes Prepared by TEOS-PEG Coating Sol (TEOS-PEG계 Sol-Gel코팅에 의한 세라믹 분리 막의 제조 및 특성)

  • Kim, Tae-Bong;Choi, Se-Young;Kim, Goo-Dae
    • Journal of the Korean Ceramic Society
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    • v.42 no.3 s.274
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    • pp.165-170
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    • 2005
  • Sol-gel methods offer many advantages over conventional slip-casting, including the ability to produce ceramic membranes. They are purer, more homogeneous, more reactive and contain a wider variety of compositions. We produced ormosil sol using sol-gel process under various molecular weight of polymer species[polyethylene glycol(PEG)] in total system [Tetraethyl ortho silicate(TEOS)-polyethylene glycol(PEG)]. The properties of as-prepared ormosil sol such as viscosity and gelation time are characterized. Also, the ceramic membrane was prepared by dip-coating with synthetic sol and its microstructure was observed by scanning electron microscopy. The permeability and rejection efficiency of membrane for oil/water emulsion were evaluated as cross­flow apparatus. The ormosil sol coated membrane was easily formed by steric effect of polymer and it improved flux efficiency because infiltration into porous support decreased. Its flux efficiency was elevated about $200\;l/m^2h$ compared with colloidal sol coated membrane at point of five minutes from starting test.

The Evaluation of the Packaging Properties and Recyclability with Modified Acrylic Emulsion for Flexible Food Paper Coating (유연 종이 식품 포장재의 개질 아크릴 에멀젼 코팅 특성 및 재활용성 평가)

  • Myungho Lee;In Seok Cho;Dong Cheol Lee;Youn Suk Lee
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.29 no.3
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    • pp.153-161
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    • 2023
  • The worldwide effects of COVID-19 have led to a surge in online shopping and contactless services. The consumption pattern has caused the issues such as the environmental pollution together with the increase of plastic waste. Reducing the reliance on the petroleum based plastic use for the package and replacing it with environmentally friendly material are the simple ways in order to solve those problems. Paper is an eco-friendly product with high recyclability as the food packaging materials but has still poor barrier properties. A barrier coating on surface of the paper can be achieved with the proper packaging materials featuring water, gas and grease barrier. Polyethylene (PE) or polypropylene (PP) coatings which are generally laminated or coated to paper are widely used in food packaging applications to protect products from moisture and provide water or grease resistance. However, recycling of packaging containing PE or PP matrix is limited and costly because those films are difficult to degrade in the environment. This study investigated the recyclability of modified acrylic emulsion coating papers compared to PE and PP polymer matrixes as well as their mechanical and gas barrier properties. The results showed that PE or modified acrylic emulsion coated papers had better mechanical properties compared to the uncoated paper as a control. PE or PP coating papers showed strong oil resistance property, achieving a kit rating of 12. Those papers also had a significantly higher percentage of screen reject during the recycling process than modified acrylic coated paper which had a screen rejection rate of 6.25%. In addition an uncoated paper had similar value of a screen rejection rate. It may suggest that modified acrylic emulsion coating paper can be more easily recycled than PE or PP coating papers. The overall results of the study found that modified acrylic emulsion coating paper would be a viable alternative to suggest a possible solution to an environmental problem as well as enhancing the weak mechanical and poor gas barrier properties of the paper against moisture.

Cycling Performances of Lithium-Ion Polymer Cells Assembled with Surface-Modified Separators Containing Aluminum Fluoride (불화 알루미늄을 포함하는 표면 개질된 분리막으로부터 제조되는 리튬이온폴리머전지의 싸이클 특성에 관한 연구)

  • Eo, Seung-Min;Kim, Dong-Won
    • Journal of the Korean Electrochemical Society
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    • v.11 no.2
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    • pp.125-129
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    • 2008
  • Rechargeable lithium-ion polymer batteries have been considered to be next-generation power sources for portable electronic devices and electric vehicles. In this work, we tried to improve the cycling performances of lithium-ion polymer cells by coating aluminum fluoride and acrylonitrile-methyl methacrylate copolymer to the polyethylene separator. It was found that the addition of aluminum fluoride to the surface-modified separator reduced the interfacial resistances and thus the cell exhibited a less capacity fading and better high rate performance. The cell showed an initial discharge capacity of 150 mAh/g and good capacity retention at 0.5 C rate.

Structural Performance of Coated Steel Pipe Connections Subjected to Various Loading Conditions: An Analytical Study (다양한 하중 조건에 따른 코팅 강관 연결부의 구조성능 평가)

  • Myung Kue Lee;Sanghwan Cho;Min Ook Kim
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.37 no.4
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    • pp.233-241
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    • 2024
  • In this study, finite element analyses of coated steel pipes were conducted to research the development of sensing-based monitoring smart pipes. The coated steel pipes underwent a chemical coating pretreatment process that used modified polyethylene on both the inside and outside surfaces. Furthermore, the steel pipes were designed to minimize damage during the expansion process by incorporating connecting parts. To evaluate structural performance under various loads, four loading conditions were established: static structural analysis by earth pressure, fatigue life evaluation by vehicle load, and resistance to water leakage under both tensile and compressive loads. The analysis estimated a higher fatigue life for the developed steel pipe, compared with that of a steel pipe using ready-made epoxy coatings and joints. In addition, an average maximum displacement reduction of 56.1% and a maximum stress reduction of 61.2% were confirmed under identical conditions and diameters, thereby verifying the safety of the connecting parts of the developed coated steel pipe. Furthermore, the results of stress distribution contour analyses revealed superior water leakage resistance at the fastening parts, compared with the centers of the pipes.