• 제목/요약/키워드: Modified materials

검색결과 2,815건 처리시간 0.032초

Interfaces Between Rubber and Metallic or Textile Tire Cords

  • Ooij Wim J. Van;Luo Shijian;Jayaseelan Senthil K,
    • Elastomers and Composites
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    • 제34권4호
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    • pp.299-314
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    • 1999
  • Bonding metal and textile components to rubber has always posed a problem. In this paper, an attempt had been made to modify textile and metal surfaces for bonding with rubber. The metal surfaces were modified using silane coupling agents and textile fibers were modified using plasma polymerization techniques. Some results on adhesion of metals to a range of sulfur-cured rubber compounds using a combination of organofunctional silanes are given here. The treatment was not only effective for high-sulfur compounds but also for low-sulfur com pounds as used in engine mounts and even for some semi-EV compounds. Coatings of plasmapolymerized pyrrole or acetylene were deposited on aramid and polyester tire cords. Standard pull-out force adhesion measurements were used to determine adhesion of tire cords to rubber compounds. The plasma coatings were characterized by various techniques and the performance results are explained in an interpenetrating network model.

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석회석 미분말이 염소고함유시멘트의 수화반응에 미치는 영향 (Influence of Limestone Powder on the Hydration of Cement Contained much Chloride)

  • 정찬일;이의학;이경희
    • 한국세라믹학회지
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    • 제43권9호
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    • pp.537-543
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    • 2006
  • Length change, hydration heat, setting time and compressive strength of OPC were measured by adding KCl and replacing limestone powder so as to examine the influence of limestone powder on hydration of the OPC contained much chloride. In general, the chloride modified cement was high in heat of hydration, short in its setting time, low in its fluidity and low in its strength at 28 days due to the sudden hydration in its initial stage. As a result of the experiment, it has been demonstrated that heat of hydration, became low as one replaced limestone powder to the chloride modified cement, and the fluidity and shrinkage rate of mortar decreased without change in setting time; furthermore, the compressive strength at 28 days was improved.

Modified-Polyol Synthesis of Nanocrystalline $LaPO_4:Ce^{3+}$, $Tb^{3+}$ Phosphors for Transparent Display

  • Song, Woo-Seuk;Byun, Ho-June;Yang, Hee-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.1290-1292
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    • 2009
  • Modified-polyol protocol was utilized for synthesis of green-emitting ($^5D_4-^7F_j$ transitions of $Tb^{3+}$ ion) nanocrystalline $LaPO_4:Ce^{3+}$, $Tb^{3+}$ phosphors. Experimental parameters including chemical composition and annealing temperature were optimized to produce highly efficient, uniformly sized nanophosphors. Spin-deposited layer of $LaPO_4:Ce^{3+}$, $Tb^{3+}$ nanophosphors on glass substrate exhibited a transmittance of more than 80 %, indicating their efficacy for transparent display.

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Novel Approaches of Modified Poly (4-vinylphenol) for Low Hysteresis Organic Thin Film Transistors

  • Kim, Hyoung-Jin;Kim, Doo-Hyun;Kim, Byung-Uk;Kim, We-Yong;Kim, Ho-Jin;Hong, Mun-Pyo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.1305-1307
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    • 2009
  • We have investigated the new modification of poly (vinyl phenol) (PVP) for low hysteresis organic thin film transistors (OTFTs). In order to suppression of hysteresis phenomenon, synthesized various backbone structure polymeric gate dielectric. The modified polymeric dielectric was synthesized by inducing ringshape phenol backbone structure instead of conventional chain. We could be observed that relieved hysteresis and excellent air stability from ring-shape phenol backbone structure.

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The Effect of Surface Modification with La-M-O (M = Ni, Li) on Electrochemical Performances of Li[Ni0.8Co0.15Al0.05]O2 Cathode

  • Ryu, Jea-Hyeok;Kim, Seuk-Buom;Park, Yong-Joon
    • Bulletin of the Korean Chemical Society
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    • 제30권3호
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    • pp.657-660
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    • 2009
  • The surface of $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ cathode particle was modified by lanthanum based oxide to improve electrochemical property and thermal stability. The XRD pattern of surface layer was indexed with that of $La_4NiLiO_8$. The discharge capacity of modified electrode was higher than that of pristine sample, specially at fast charge-discharge rate and high cut-off voltage. In the DSC profile of the charged sample, the generation of heat by exothermic reaction was decreased by surface modification. Such enhancement may by attributed to the presence of stable lanthanum based oxide, which effectively suppressd the reaction between electrode and electrolyte on the surface of $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ electrode.

Damage propagation for aircraft structural analysis of composite materials

  • Hung, C.C.;Nguyen, T.
    • Advances in aircraft and spacecraft science
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    • 제9권2호
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    • pp.149-167
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    • 2022
  • A Modified fuzzy mechanical control of large-scale multiple time delayed dynamic systems in states is considered in this paper. To do this, at the first level, a two-step strategy is proposed to divide a large system into several interconnected subsystems. And we focus on the damage propagation for aircraft structural analysis of composite materials. As a modified fuzzy control command, the next was received as feedback theory based on the energetic function and the LMI optimal stability criteria which allow researchers to solve this problem and have the whole system in asymptotically stability. And we focus on the results which shows the high effective by the proposed theory utilized for damage propagation for aircraft structural analysis of composite materials.

Fabrication Technique of Nanoemulsion Using Silicone Oil and Application as Hydrophilic Ophthalmic Lens

  • Hye-In Park;A-Young Sung
    • 한국재료학회지
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    • 제34권7호
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    • pp.315-320
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    • 2024
  • In order to maximize the function and increase the compatibility of silicone hydrogel lens, this study compared and analyzed the properties of Amino modified silicone oil using mini and microemulsion technique, respectively. Optical and physical properties were evaluated by spectral transmittance, refractive index, water content, oxygen transmittance and contact angle measurements to evaluate the performance of the manufactured hydrogel lens. The spectral transmittance results revealed the copolymerization method lens showed 31 % of the visible light area, which did not satisfy the basic optical properties. However, the lens using the mini and microemulsion materials showed more than 90 % of the visible light area, satisfying the optical characteristics. In addition, all physical properties were superior to a basic hydrogel lens. The mini and microemulsion techniques effectively improved the stability and function of the ophthalmic hydrogel lens and are considered a promising ways of manufacturing an ophthalmic hydrogel contact lens with increased compatibility and stability.

Study on the Improvement of the Electrochemical Characteristics of Surface-modified V-Ti-Cr alloy by Ball-milling

  • Kim, Jin-Ho;Lee, Sang-Min;Lee, Ho;Lee, Paul S.;Lee, Jai-Young
    • 한국수소및신에너지학회논문집
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    • 제12권1호
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    • pp.39-50
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    • 2001
  • Vanadium based solid solution alloys have been studied as a potential negative electrode of Ni/MH battery due to their high hydrogen storage capacity. In order to improve the kinetic property of V-Ti alloy in KOH electrolyte, the ball-milling process with Ni, which has a catalytic effect of hydrogen absorption/desorption, was carried out to modify the surface properties of V-Ti-Cr alloys with high hydrogen storage capacity. Moreover, to overcome the problem of poor cycle life, V-Ti alloy substituted by Cr, V0.68 Ti0.20 Cr0.12, has been developed showing a good cycle performance (keeping about 80 % of initial discharge capacity after 200 cycles). The cycle life of surface-modified V0.68 Ti0.20 Cr0.12 alloy was improved by suppressing the formation of TiO2 layer on the alloy surface while decreasing the amount of dissolved vanadium in the KOH electrolyte. In order to promote the effect of Ni coating on the surface property of V0.68 Ti 0.20 Cr 0.12 alloy by ball-milling, filamentary-typed Ni, which has higher surface coverage area than sphere-typed Ni was used as a surface modifier. Consequently, the surface-modified V0.68 Ti0.20 Cr0.12 alloy electrode showed a improved discharge capacity of 460 mAh/g.

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FLIP CHIP ON ORGANIC BOARD TECHNOLOGY USING MODIFIED ANISOTROPIC CONDUCTIVE FILMS AND ELECTROLESS NICKEL/GOLD BUMP

  • Yim, Myung-Jin;Jeon, Young-Doo;Paik, Kyung-Wook
    • 마이크로전자및패키징학회지
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    • 제6권2호
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    • pp.13-21
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    • 1999
  • Flip chip assembly directly on organic boards offers miniaturization of package size as well as reduction in interconnection distances resulting in a high performance and cost-competitive Packaging method. This paper describes the investigation of alternative low cost flip-chip mounting processes using electroless Ni/Au bump and anisotropic conductive adhesives/films as an interconnection material on organic boards such as FR-4. As bumps for flip chip, electroless Ni/Au plating was performed and characterized in mechanical and metallurgical point of view. Effect of annealing on Ni bump characteristics informed that the formation of crystalline nickel with $Ni_3$P precipitation above $300^{\circ}C$ causes an increase of hardness and an increase of the intrinsic stress resulting in a reliability limitation. As an interconnection material, modified ACFs composed of nickel conductive fillers for electrical conductor and non-conductive inorganic fillers for modification of film properties such as coefficient of thermal expansion(CTE) and tensile strength were formulated for improved electrical and mechanical properties of ACF interconnection. The thermal fatigue life of ACA/F flip chip on organic board limited by the thermal expansion mismatch between the chip and the board could be increased by a modified ACA/F. Three ACF materials with different CTE values were prepared and bonded between Si chip and FR-4 board for the thermal strain measurement using moire interferometry. The thermal strain of ACF interconnection layer induced by temperature excursion of $80^{\circ}C$ was decreased with decreasing CTEs of ACF materials.

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레진강화형 글라스아이오노머의 2 축 굽힘강도 (BI-AXIAL FRACTURE STRENGTH OF RESIN MODIFIED GLASS IONOMERS)

  • 이용근;임미경;구대회;이정식
    • Restorative Dentistry and Endodontics
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    • 제22권2호
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    • pp.751-760
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    • 1997
  • Resin-modified glass ionomers were introduced in 1988 to overcome the problems of moisture sensitivity and low early mechanical strengths of the conventional glass ionomers, and to maintain their dinical advantages. The purpose of this study was to evaluate the bi-axial fracture strength of four resinmodified glass-ionomers(Fuji II LC, Vitremer, Dyract, VariGlass), one resin composite material(Z-100), and one conventional glass-ionomer(Fuji II). Three specimens of each material and shade combination were made according to the manufacturers' instructions. Materials were condensed into metal mold with a diameter of 10mm and a thickness of 2.0mm and pressed between two glass plates. Resin-modified glass ionomers were polymerized using a Visilux II light curing unit by irradiating for 60 seconds from both sides, and conventional glass ionomer was cured chemically. After specimens were removed from the molds, surfaces were polished sequentially on wet sandpapers up to No. 600 silicone carbide paper. The specimens were thermocycled for 2,000 cycles between $5^{\circ}C$ and $55^{\circ}C$ distilled water. After thermocycling, bi-axial fracture strengths were measured using a compressive-tensile tester(Zwick 1456 Z020, Germany) with the cross head speed of 0.5mm/minute. The results were as follows: 1. Two factors of the kind and color of materials had a main effect on bi-axial fracture strength (p<0.01), and bi-axial fracture strength was influenced significantly by the kinds of materials (p<0.01). But there was no significant interaction between two variables of the kind and color of materials (p>0.05). 2. Comparing the mechanical properties of the materials, the elastic modulus of Z100 was higher than any other material, and there was no difference in the displacement at fracture among materials. The bi-axial fracture strength of Z100 was significantly higher than any other material, and that of resin-modified glass ionomers was significantly higher than that of conventional glass ionomer (p<0.05). 3. In the same material group, the color of material had little influence on the mechanical properties.

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