• Title/Summary/Keyword: Modified materials

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Crosstalk-Enhanced DOS Integrated with Modified Radiation-Type Attenuators

  • Han, Young-Tak;Shin, Jang-Uk;Park, Sang-Ho;Han, Sang-Pil;Lee, Chul-Hee;Noh, Young-Ouk;Lee, Hyung-Jong;Baek, Yong-Soon
    • ETRI Journal
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    • v.30 no.5
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    • pp.744-746
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    • 2008
  • This letter presents a crosstalk-enhanced polymer thermo-optic digital optical switch operating at a low power consumption. Modified radiation-type attenuators are integrated in a series with a conventional $1{\times}2$ digital optical switch. A low optical crosstalk of less than -45 dB is attained at a low applied switching power of 60 mW, and an insertion loss of about 1.1 dB is exhibited.

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Processing of $Si_3N_4/SiC$ and Boron-Modified Nanocomposites Via Ceramic Precursor Route

  • Lee, Hyung-Bock;Rajiv S. Mishra;Matt J. Gasch;Han, Young-Hwan;Amiya K. Mukherjee
    • The Korean Journal of Ceramics
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    • v.6 no.3
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    • pp.245-249
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    • 2000
  • Consolidation of amorphous powders is emerging as a route for synthesis of high strength composite materials. Diffusion processes necessary for consolidation are expected to be more rapid in amorphous state(SRO) than in the crystalline state(LRO). A new synthesis technique of exploiting polymeric ceramic precursors(polysilazane and polyborosilazane) is derived for Si$_3$N$_4$/SiC and boron-modified nanocomposites for extremely high temperature applications up to 200$0^{\circ}C$. The characterization methods include thermal analysis of DTA, and XRD, NMR, TEM, after pyrolysis, as a function of time and temperature.

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Preparation of Ceria Coated Silica Abrasive by Hydrothermal Treatment and Polishing Rate on Oxide Film (수열처리에 의한 세리아가 코팅된 실리카 연마재의 제조 및 Oxide Film의 연마특성)

  • Ryu Dae Sun;Kim Dae Sung;Lee Seung-Ho
    • Korean Journal of Materials Research
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    • v.15 no.12
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    • pp.818-823
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    • 2005
  • Sub-micron colloidal silica particles coated with nano-sized ceria were prepared by mixing of its silica and cerium salts hydrolysis, and modified by hydrothermal reaction. By using the slurries with and without hydrothermal modification containing above particles, oxide film coated on silicon wafer was polished. The modified slurries had higher polish rate due to increase of ceria fraction to silica through hydrothermal reaction. They revealed higher stability in wide range of pH $2\~10$ than ceria coated silica slurries without its modification.

A Study of Partial Carbonisation for the Development of Pitch Based Carbon Fibres

  • Aggarwal, R.K.;Bhatia, G.;Raman, V.;Saha, M.;Mishra, A.
    • Carbon letters
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    • v.5 no.1
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    • pp.23-26
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    • 2004
  • A study of partial carbonisation of green pitch fibres to temperatures in the range of 500-$1000^{\circ}C$ was carried out on three precursors - a neat pitch and two polymer modified pitches, with a view to find out a suitable temperature at which the fibres acquire considerably improved toughness or handleability (compared to that in the green stage) for their subsequent processing into carbon fibres. A partial carbonisation temperature of 500-$600^{\circ}C$ has been identified to result in a remarkable improvement in the toughness/handleability of the fibres in all the three cases. However, from techno-economical considerations, the neat pitch appears to provide the best precursor system for the production of pitch based carbon fibres.

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Investigation of Co-poly-para-aramid Fiber Dispersion in Chloroprene Rubber Matrix and Improvement of Dispersibility Through Fiber Surface Modification

  • Garam Park;Hyeri Kim;Gayeon Jeong;Dohyeong Kim;Seungchan Noh;Dajeong Gwon;Myung Chan Choi;Jaseung Koo
    • Elastomers and Composites
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    • v.57 no.4
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    • pp.175-180
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    • 2022
  • To produce a co-poly-para-aramid fiber (AF, Technora®)-reinforced neoprene rubber composite, dispersion of AF in a neoprene matrix is investigated. The AF is then surface-modified by mercerization and acetone, plasma, and silane treatments to improve dispersibility. Finally, an internal mixer process is used to disperse the surface-modified fibers in the neoprene rubber matrix.

Surface Modification of Multi-walled Carbon Nanotubes for Enhancement of Dispersion and Electrochemical Properties

  • Kim, Young-Ja;Zhang, Wentao;Lee, Hong-Ro;Kim, Jong-Hyee
    • Journal of Surface Science and Engineering
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    • v.41 no.5
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    • pp.194-198
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    • 2008
  • Several methods for improving dispersion of carbon nanotubes (CNTs) have been investigated. CNTs modified by acids and hydrogen peroxide ($H_2O_2$) showed improved dispersion. From SEM micrographs and photos of dispersion, CNTs modified with nitric acid and $H_2O_2$, showed no agglomeration in solution even standing for 4 months, which means successfully improved dispersion property. TEM micrographs of surface modified single CNT treated with 69% $HNO_3$ in boiling acid solution as the optimum method were obtained. For confirmation of CNTs' application to EDLC electrode materials, characteristics of EDLC have been analyzed by cyclic voltammetry curve, specific capacitance of unit cell, electrode discharge curves and AC impedance curve. From the results, it could be confirmed that electrochemical properties of CNTs were enhanced after surface modification with 69% $HNO_3$ acid treatment.

Morphology and Formation Mechanism of Sn Nanoparticles Synthesized by Modified Polyol Process at Various pH Values (변형 폴리올 공정에서 pH에 따라 합성된 Sn 나노입자의 형상 변화 및 형성기구)

  • Shin, Yong Moo;Lee, Jong-Hyun
    • Korean Journal of Materials Research
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    • v.24 no.11
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    • pp.578-584
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    • 2014
  • To synthesize Sn nanoparticles (NPs) less than 30 nm in diameter, a modified polyol process was conducted at room temperature using a reducing agent, and the effects of different pH values of the initial solutions on the morphology and size of the synthesized Sn NPs were analyzed. tin(II) 2-ethylhexanoate, diethylene glycol, sodium borohydride, polyvinyl pyrrolidone (PVP), and sodium hydroxide were used as a precursor, reaction medium, reducing agent, capping agent, and pH adjusting agent, respectively. It was found by transmission electron microscopy that the morphology of the synthesized Sn NPs varied according to the pH of the initial solution. Moreover, while the size decreased to 11.32 nm with an increase up to 11.66 of the pH value, the size increased rapidly to 39.25 nm with an increase to 12.69. The pH increase up to 11.66 dominantly promoted generation of electrons and increased the amount of initial nucleation in the solution, finally inducing the reduced-size of the Sn particles. However, the additional increase of pH dominantly induced a decrease of PVP by neutralization, which resulted in acceleration of the agglomeration by collisions between particles.

The Combustion Character of Polymer Modified Cement Mortar (폴리머 시멘트 모르타르의 연소특성 평가)

  • Park, Dong-Cheon;Oh, Kwang-Suek;Kim, Hyo-Youl;Oh, Sang-Gyun;Kang, Byeung-Hee
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.11a
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    • pp.63-66
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    • 2008
  • Not only mechanical properties, bonding properties, electro chemical properties, etc. but also fire safety is required in patch repair materials such as polymer modified cement mortar (PCM) which are used to deteriorated reinforced concrete structure. Unfortunately, it is very difficult to choice the appropriate repair materials because there are not enough information about fire safety properties of PCM. In this study, The combustion characters of PCM were evaluated through the heat release rate test and non-combustibility test. The pyrogenicity test uses the cone calorimeter based on the oxygen consumption method. The non-combustibility test is from the temperature change inside the furnace during the test. The effect of the types of polymer and polymer content were evaluated from the series of test. The results are like followings. 1) The higher the W/C of PCM, the lower the gross calorific value and heat generation rate in the heat release rate test. The amount of heat generation of PCM is like the order of VVA, EVA, and SBR in this study. 2) Some materials such as E45-100, E50-100, E60-100, S50-50, and S50-100 were estimated as not appropriate building materials in the non combustibility test.

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