• Journal of the Korean Society of Tobacco Science
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• v.17 no.2
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• pp.177-183
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• 1995

This study was conducted to develop the most precise NIR(near infrared spectrometric) calibration for rapid determination of chemical composition in ground samples of toasted burley tobacco using stepwise, stepup, principal component regression(PCR), partial least square(PLS) and modified partial least square(MPLS) calibration method. The number of wavelength(W) selected by stepup multiple linear regression using: second derivative spectra was as follows: total sugar(TS)-4 W, nicotine-9 W, total nitrogen(TN)-2 W, ash-8 W, total volatile base(TVB)-5 W, chlorine4 W, L of color-6 W, a of color-6 W and b of color-7 W. Comparing the calibration equations followed by each chemical components, the most precise calibration equation was MPLS for 75, a and b of color, PLS for nicotine, ash, TVB, chlorine and L of color and stepup for TN. The standard error of calibration(SEC) and standard error of performance(SEP) between result of near infrared analysis and standard laboratory analysis were 0.18, 0.40% for 75, 0.06, 0.08% for nicotine, 0.18, 0.16% for TN, 0.33, 0.46% for ash, 0.04, 0.03% for TVB, 0.08, 0.06% for chlorine, 0.54, 0.58 for L of color, 0.22, 0.22 for a of color and 0.27, 0.27 for b of color, respectively. The SEC and SEP of ash and TVB were within allowable error of standard laboratory analysis, nicotine, TN and chlorine were 1.2-2.0 times and 75 were 2.1-4.0 times larger than allowable error of standard laboratory analysis. The ratio of SEC and SEP to mean were 1.5, 1.6% for L of color, 3.7, 3.8% for a of color and 1.8, 1.8% for b of color, respectively. Key words : burley tobacco chemistry, near infrared spectroscopy.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.3 no.4
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• pp.228-233
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• 1998

This study presents a close-range photogrammetry that is applicable to beach profile estimation using a non-metric camera. Based on the analysis of oblique video image in which the video camera was installed on a horizontal plane and the field of view was fixed, a new equation to analyze a photograph was developed considering the following aspects: (1) camera is allowed to be rotated about its optical axis and (2) a simple error model is adopted to correct lens distortion and other systematic errors associated with the non-metric camera, which improves accuracy of non-metric imageries. To test the modified technique, photographs of the beach were taken near the Donghae City in February, 1998. In addition, beach profiles were surveyed with conventional dumpy level and surveying staff. RMS error between the estimated and measured beach profiles is less than 10 cm in elevation.

• Journal of Photoscience
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• v.4 no.3
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• pp.97-103
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• 1997

The effect of temperature on the fluorescence quenching of 2-(4-Methoxyphenyl)-5-(1-naphthyl)-1,3,4-oxadiazole (MPNO1), 2-(4-Methoxyphenyl)-5-(2-naphthyl)-1,3,4-oxadiazote(MPNO2), by aniline, and 2-Phenylindole (2-PI) by CCk, in toluene by steady state method and in benzene by time-resolved method have been carried out in the temperature range 30 - 70$\circ$C. The Stem-Volmer (S-V) plots, I$_0$/I against quencher concentration [Q] at different temperanares show positive deviations. The fluorescence lifetimes determined at different temperatures show no systematic variations and the variations being within the experimental error, the average values of lifetimes $ $\tau$ (t) are taken for further calculations. Rate constants such as Stem-Volmer quenching constants K$_sv}$, quenching rate parameters k$_q$ and k'$_q$, static quenching constant V and kinetic distance r are determined using the modified Stem-Volmer equation and sphere of action static quenching model. In order to see whether the reactions are diffusion limited, equations k$_q$ = e$^{-Eq/RT}$ and k'$_q$ = e$^{-Eq/RT}$ are used to determine the values of E$_q$ and E'$_q$, the activation energies for collisional quenching and the values of E$_q$ are 14.53. 17.28 and 16.20 kJ mole$^{-1}$ for MPNO1, MPNO2 and 2-PI respectively and the values of E'$_q$ are 14.62 and 17.73 for MPNO1 and MPNO2 respectively. From the magnitudes of various quantities it has been concluded that the reactions are diffusion limited and the observed positive deviations in the S-V plot are due to static and dynamic quenching.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.17 no.12
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• pp.1343-1352
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• 1992

This paper presents a new and easy method to obtain the Fourier transforms of the n-th order cosine-pulses whose maximum amplitudes are uniform. The new method is focused on deriving a formula which is recursively related following their orders and can be well applied to some numerical solutions. On the other hand, this method also offers more compact procedures in view of analytical solutions than the conventional methods because the results are consist of the sum of two functions which are easily calculated. Especially, the formula can be represented as a complete recursion by the separation of coefficients originated by the authors and the resulting difference equation is given by the sum of the original 'sinc' functions shifted by some symmetrical factors and multiplied by some constants. The constants are easily decided from the binomial coefficients and the shifting factors from the corresponding exponential differences in the expansion of $(a+b)^n$.

• Journal of Welding and Joining
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• v.17 no.1
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• pp.124-132
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• 1999

Thermal fatigue strength of the solder joints is the most critical issue for TSOP(Thin Small Outline Package) because the leads of this package are extremely short and thermal deformation cannot be absorbed by the deflection of the lead. And the TSOP body can be subject to early fatigue failures in thermal cycle environments. This paper was discussed distribution of thermal stresses at near the joint between silicon chip and die pad and investigated their reliability of solder joints of TSOP with 42 alloy clad lead frame on printed circuit board through FEM and 3 different thermal cycling tests. It has been found that the stress concentration around the encapsulated edge structure for internal crack between the silicon chip and Cu alloy die pad. And using 42 alloy clad, The reliability of TSOP body was improved. In case of using 42 alloy clad die pad(t=0.03mm). $$\sigma$_{VMmax}$ is 69Mpa. It is showed that 15% improvement of the strength in the TSOP body in comparison with using Cu alloy die pad $($\sigma$_{VMmax}$=81MPa). In solder joint of TSOP, the maximum equivalent plastic strain and Von Mises stress concentrate on the heel of solder fillet and crack was initiated in it's region and propagated through the interface between lead and solder. Finally, the modified Manson-Coffin equation and relationship of the ratio of $N_{f}$ to nest(η) and cumulative fracture probability(f) with respect to the deviations of the 50% fracture probability life $(N_{f 50%})$ were achieved.

• Textile Coloration and Finishing
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• v.25 no.4
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• pp.254-261
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• 2013

In this study, we synthesized a new fluorescent polypyridyl dye 2 containing a 2,2'-bipyridine in the center and two 2,2':6',2"-terpyridines at both ends. When exposed to various metal ions, the dye 2 showed selective fluorescence responses. In the presence of $Cu^{2+}$ and $Ni^{2+}$, it exhibited a highly effective fluorescence quenching, leading to large $K_{sv}$ values of up to $10^5$. In response to most other metal ions including $Al^{3+}$, in contrast, its fluorescence changes little, showing a small Ksv value at $10^2$. Meanwhile, the compound 2 revealed a differentiated fluorescence response to $Zn^{2+}$, which is evidenced by a large red shift of > 100 nm. Such a red shift from the ion binding is attributed to the planarization of the bipyridyl unit extending the effective conjugation length in conjunction. A polypyridyl compound will find important usefulness in chemosensor application due to its selective binding to metal ions. Subsequent research concerned with modified derivatives is currently going on, as a way to provide high solubility even after metal-complexing.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.30 no.6
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• pp.92-100
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• 2002

In this study, transonic/supersonic nonlinear flutter analysis system of a complete aircraft including forced harmonic motion pf control surfaces has been effectively developed using the modified transonic small disturbance (TSD) equation. To consider the nonlinear effects, the coupled time marching method (CTM) combining computational structural dynamics (CFD) has been directly applied for aeroelastic computations. The grid system for a complex full aircraft configuration is effectively generated by the developed inhouse code. Intransonic and supersonic flight regimes, the characteristics of static and dynamic aeroelastic effect has been investigated for a complete aircraft model. Also, nonlinear flutter flight simulations for the forced harmonic motion of control surfaces are practically presented in detail.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.43 no.3
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• pp.213-223
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• 2015

The helicopter initial design model was established by using the latest weight estimation equations based on the Tishchenko's methodology through the study existing initial design tools. The sequential decomposition method is used to reduce analysis time in the sizing. Empirical parameters of the weight estimation equation were also extracted from numerical and regression analysis for a helicopter database. Design input and output values were compared with the RISPECT design tool. Finally, comparison of the re-design resulting for several existing helicopters was presented and showed the good agreement within less than 5% in the weight estimation and main rotor sizing. Established initial design model was proved to be effectively used as initial design tool.

• Fire Science and Engineering
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• v.14 no.3
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• pp.6-12
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• 2000

This paper describes the smoke movement of a fire field model based on a self-developed SMEP(Smoke Movement Estimating Program) code to the simulation of fire induced flows in the two types of compartment space containing the radiation effect under smoke movement in room fire. The SMEP using PISO algorithm solves conservation equations for mass, momentum, energy and species, together with those for the modified k-$\varepsilon $ turbulence model with buoyancy term. Also it solves the radiation equation using the discrete ordinates method. The result of the calculated smoke temperature containing radiation effect has shown reasonable agreement compared with the experimental data. On the other hand, a difference of a lot was found between the temperature predicted by the SMEP with only convection effect and obtained by the experimental result. This seems to come from the radiation effect of $H_2$O and $CO_2$ gas under smoke productions. Thus, the consideration of the radiation effect under smoke in fire may be necessary in order to produce more realistic result.

• Journal of the Korean Geosynthetics Society
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• v.9 no.3
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• pp.57-65
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• 2010

The main objective of this study is to investigate the time-dependent deformation of EPS blocks under repeated loading conditions which is the one of the flexible pavement structure. The study comprised of both the experimental work and analytical modeling in order to understand the behavior of EPS blocks under repeated loading. The analytical modeling included the selection of a suitable model for describing the deformation behavior observed under repeated loading conditions, investigating the relationship among the unit weight, deformation and applied stress, analyzing the effect of repeated load on deformation. The test results were compared with the Findley's theory and model analysis with the results of this research under repeated loading conditions. Both Modified Findley's model and the proposed model can be adopted to illustrate the deformation behavior of EPS blocks under repeated loads.