• 제목/요약/키워드: Modified electrodes

검색결과 247건 처리시간 0.029초

점토광물을 이용한 산소환원의 전기화학적 촉매성에 관한 연구 (The Electrocatalytic Reduction of Molecular Oxygen with Clay Modified Electrodes)

  • 오성훈;황진연;심윤보;이효민;윤지해
    • 한국광물학회지
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    • 제18권1호
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    • pp.1-9
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    • 2005
  • 몇 가지 점토광물과 메틸바이올로젠 또는 메틸렌블루를 함유시킨 점토수식전극을 이용하여 산소환원에 대한 전기화학적 촉매성을 검토하였다. 점토광물로는 Na-몬모릴로나이트, Ca-몬모릴로나이트, 카오리나이트를 사용하였다. 점토수식전극은 유리탄소전극 표면에 점토 현탁액을 입히고 메틸바이올로젠을 흡착시킨 것을 사용하였으며, 전기화학적 산소환원의 정도는 순환 전압전류법(cyclic voltammetry)으로 측정하였다. 실험결과, 다른 점토시료에 비하여 Na-몬모릴로나이트가 메틸바이올로젠의 흡착효과가 가장 크게 나타났고, 메틸바이올로젠을 흡착시킨 점토수식전극이 산소환원에 대한 촉매성이 월등히 우수하였다. 즉 촉매산소환원 피크가 242.6 mV 만큼 +방향으로 이동하였다. 메틸바이올로젠을 흡착시킨 점토수식전극이 메틸렌블루를 흡착시킨 점토수식전극보다 산소환원에 대한 촉매성이 더 높게 나타났다. Ca-몬모릴로나이트의 경우는 변화가 없었으나 Na-몬모릴로나이트의 구조는 메틸바이올로젠의 흡착으로 변화되었다. 메틸바이올로젠- Na-몬모릴로나이트 점토수식전극은 현탁액의 점토 농도가 약 0.87 g/10 mL이고. 메틸바이올로젠의 수용액의 농도가 대략 2.5 mM일 때 산소환원 촉매 효과가 가장 탁월하였다. 지지전해질의 pH에 따른 점토수식 전극의 산소 환원 촉매성은 중성의 pH 범위(6.3과 8.3)에서보다 산성인 pH 3.7과 알칼리성인 pH 12.7에서 월등히 크게 나타났다.

Organic Thin-Film Transistors with Screen Printed Silver Source/Drain Electrodes

  • Kim, Sam-Soo;Kim, Min-Soo;Choi, Gyu-Seok;Kim, Heon-Gon;Kim, Yong-Bae;Lee, Dong-Gu;Roh, Jae-Seong
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
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    • pp.1305-1307
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    • 2007
  • We show that the electrical properties of organic thinfilm transistors(OTFTs) can be enhanced by controlling the morphology of interface between screen printed electrodes and gate dielectrics. Modified surface of the insulator layer($SiO_2$) affect on the interface energy of electrode on $SiO_2$ layer. Contact angle measurement and FT-IR spectrum shows that the interface is properly modified. OTFTs device with high efficiency has been realized through modification of interface layer.

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Modified Ramp Reset Waveform for High Contrast Ratio in AC PDPs

  • Kim, Jae-Sung;Yang, Jin-Ho;Ha, Chang-Hoon;Whang, Ki-Woong
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.199-202
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    • 2002
  • In general, the background light produced during the reset period deteriorates the dark room contrast ratio in AC PDP. In this paper, we propose a modified ramp reset pulse that can reduce the background light to imperceptible level. In the new reset waveform, the discharges between the scan and sustain electrodes are minimized by applying a positive bias voltage to the sustain electrode and only the weak discharges between the scan and address electrodes occur during the reset period. We adopted a MgO coated phosphor layer to get the same level of voltage margin in the new reset pulse scheme compared to that of the conventional ramp reset pulse one. As a result, the voltage margin is maintained at the same level and the dark room contrast ratio is improved dramatically.

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Electrocatalytic Reduction of Dioxygen at Schiff base Co(II) Complexes supported Glassy Carbon Electrode in various pH Solution

  • Park, Kyoung-Hee;Rim, Chae-Pyeong;Chjo, Ki-Hyung;Jeon, Seungwon;Choi, Yong-Kook
    • 분석과학
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    • 제8권4호
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    • pp.617-622
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    • 1995
  • Electrocatalytic reduction of dioxygen has been investigated by cyclic voltammetry at glassy carbon electrode modified with new Co(II)-Schiff base complexes in aqueous solutions of various pH. The reduction potentials of dioxygen at chemically adsorbed electrodes show the dependence of pH between pH 4 and 14. The catalytic effect is large and the reaction occurs via two or four electron transfer in various pH solution.

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다중방전 경로를 이용한 편상접지체의 접지저항 및 전류특성 (Grounding Resistance and Current Characteristics of the Planar Earth Structure using Multiple Discharge Paths)

  • 김영선;김동민;이기식
    • 전기학회논문지
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    • 제65권9호
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    • pp.1564-1570
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    • 2016
  • This study proposes a newly modified form of existing ground electrodes in order to secure trust of grounding system for large current caused by a stroke of lightning. Proposed planar earth structure has a several needle electrodes around a circular rod and 4 plane electrodes in all directions. The plane electrodes are fused with the insulator on the linear rod, so that they're electrically isolated. The concept is to increase the discharge amount of earth structure using multiple discharge paths like needle and plane electrodes. To check the discharge efficiency of the suggested scheme, the discharge currents are compared with typically used two kinds of ground rods. To ensure accuracy in the measurement of the discharge current, the same material was used for the comparison model. Also, the ground resistance are simulated by CDEGS commercial software and the results are compared with measured data. Based on this kind of experimental study, the suggested ground rod can be used when designing a ground system or when constructing a ground system at the site.

대지구조 모델에 따른 봉형 접지전극의 접지저항값 변화 (The Variations of Grounding Resistance of the Vertical Electrodes by Soil Models)

  • 심건보;김원배;서길모;조금배
    • 조명전기설비학회논문지
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    • 제26권9호
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    • pp.57-63
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    • 2012
  • The basic purpose of grounding is for human safety and normal operation of system related to electrical shock hazard by faults of electrical equipments. A grounding electrode is defined as a conducting element that connects electrical systems and/or equipment to the earth. The lowest possible resistance connection to the earth is sought from the grounding electrode. The grounding electrode is the foundation of the electrical safety system. The resistance to ground of vertical electrodes buried in the two deference soil structures has been analyzed for a length of electrodes and soil parameters. The equation of ground resistance of vertical electrodes are Tagg's equation for uniform soil models, and modified equation of Dwight equation for two-layer soil model. In this paper, compared with results of two equations are calculated values of vertical electrode in uniform and two-layer soil models.

광전극 두께와 표면적 변형에 따른 DSSC의 효율 특성 (DSSCs Efficiencies of Photo Electrode Thickness and Modified Photo Electrode Surface Area)

  • 권성열;양욱;주택원
    • 한국전기전자재료학회논문지
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    • 제27권2호
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    • pp.115-120
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    • 2014
  • Photo electrode is an important component for DSSC. DSSCs electrical characteristics and efficiencies fabricated with different $TiO_2$ photo electrodes thickness and modified phoro electrode surface area were studied. $11{\mu}m$ $TiO_2$ photo electrode shows a 4.956% efficiency. The highest short circuit current density was a $9.949mA/cm^2$. Efficiencies and short circuit current density increased as tape casting thickness decreased. Modified surface area of the photo electrode by needle stamp processing were studied. 200 times needle stamp processing on photo electrodes shows a highest 5.168% efficiency. Also the short circuit current density was a $10.261mA/cm^2$.