• 제목/요약/키워드: Modified adhesion

검색결과 377건 처리시간 0.026초

염증성 치은조직에서 Cell Adhesion Molecule의 발현에 관한 연구 (Expression of Adhesion Molecule in Inflammatory Gingival Tissue)

  • 박경근;김은철;유형근;신형식
    • Journal of Periodontal and Implant Science
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    • 제26권3호
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    • pp.655-668
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    • 1996
  • The change in vascular adhesion molecule expression and number of infiltrating leukocytes were investigated irnmunohistochemically in clinically healthy and inflammed gingiva. Monoclonal antibodies to ICAM-1, VCAM-1 and E-cadherin were used to identify positive vessels and leukocyte within gingival biopsies. 10 healthy gingiva and 30 inflammed gingiva was resected by clinical crown lengthening and modified Widman flap operation, respectively. Leukocyte entry into tissues at sites of inflammation is controlled by the interaction between adhesion molecule and endothelium. Because of rapid and severe destructive periodontal disease that is remarkable leukocyte adhesion deficiency, it is very important to unerdstand the mechanism of host defence against periodontal disease. The purpose of this investigation was the characterization of the presence and distribution of the adhesion molecule(ICAM-1, VCAM-1 and Evcadherin) in inflammatory gingival tissues compared to clinically healthy gingiva. The results were as followed; 1. ICAM-1 was distributed on basal layer, endothelium and mononuclear cells 10 healthy gingiva but inflammed gingiva was observed stronger stain than healthy gingiva. 2. Rare expression was observed in both group but few positive VCAM-1 cells were investigated in inflammatory gingival tissues 3. E-cadherin was expressed in only epithelium and reduced expression was observed in inflammatory gingival tissues. ICAM-1, VCAM-1 showed more expression in inflammatory tissues compared to healthy gingiva. Conversely, E-cadherin revealed a opposite result. These finding demonstrate a characteristic distribution and degree of adhesion molecule in healthy and inflammatory gingival tissues. But it is suggested that more detail study be progressive associated with leukocyte adhesion molecule to determine characterization of periodontal disease.

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이온빔 및 이미다졸-실란 화합물에 의한 폴리이미드 필름과 구리의 접착 특성 (Adhesion Properties between Polyimide Film and Copper by Ion Beam Treatment and Imidazole-Silane Compound)

  • 강형대;김화진;이재흥;서동학;홍영택
    • 접착 및 계면
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    • 제8권1호
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    • pp.15-27
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    • 2007
  • 폴리이미드 필름과 구리의 접착력을 향상시키기 위하여 이온빔과 실란-이미다졸 커플링제를 사용하여 폴리이미드 표면개질을 실시하였다. 실란-이미다졸 커플링제는 구리와의 배위결합을 형성하는 이미다졸 그룹과 실록산 폴리머를 형성하는 메톡시 실란 그룹을 함유한다. 폴리이미드 필름표면은 아르곤/산소 이온빔으로 일차로 처리하여 친수성을 높인 폴리이미드 필름에 커플링제 수용액에 침지하여 폴리이미드 필름 표면에 커플링제를 그라프트시켜 표면개질을 실시하였다. XPS 스펙트럼 분석결과 아르곤/산소 플라즈마 처리는 폴리이미드 표면에 하이드록시 및 카르보닐 그룹과 같은 산소 기능성기를 형성함을 알 수 있었고 폴리이미드 필름 표면에 실란-이미다졸과의 커플링반응에 의하여 표면이 개질되었음을 확인하였다. 이온빔을 사용하여 그라프트된 폴리이미드 필름과 구리와의 접착력은 처리되지 않은 폴리이미드 필름과의 접착력 보다 높은 접착력을 나타내었다. 또한 커플링제로 그라프트된 폴리이미드 필름의 접착력 보다 아르곤/산소의 양자화 이온을 이용하여 개질한 그라프트된 폴리이미드 필름의 시편이 더 높은 접착력을 나타내었다. 구리-폴리이미드 필름의 계면으로부터 박리된 층은 분석결과 완전히 서로 다른 화학적 조성을 나타내었는데 이것으로부터 박리가 접합면의 커플링제 내에서 일어나는 것보다는 폴리이미드와 커플링제의 사이에서 일어남을 확인하였다.

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Acrylic Modified Hydrocarbon Resin을 함유하고 있는 용제형 폴리우레탄 접착제의 특성 및 응용 연구 (Characterization and Application of Solvent Based Polyurethane Adhesive with Acrylic Modified Hydrocarbon Resin)

  • 천정미;정부영;오상택;김태균;천제환
    • 접착 및 계면
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    • 제11권1호
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    • pp.35-40
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    • 2010
  • 본 연구에서는 hydrocarbon resin과 acrylic modified hydrocarbon resin의 조성비에 따른 용제형 폴리우레탄 접착제를 제조하여 접착제의 열적 기계적 성질, 상용성 및 접착물성을 알아보았다. 폴리우레탄에 tackifier resin을 첨가함에 따라 $T_g$가 상승하였고, 인장강도는 tackifier를 5 phr를 첨가하였을 때 최고의 값을 나타내고 그 이후로는 감소하는 것을 볼 수 있었으며, 필름 표면은 PX-95를 첨가했을 때 균일하였지만 A-1100을 첨가했을 때는 10 phr 이상부터는 불균일한 것을 확인할 수 있었다. 접착강도는 PX-95를 사용한 것이 A-1100을 사용한 것보다 높게 나타났으며 결론적으로, tackifier 함량을 5 phr 첨가한 것의 접착 강도가 가장 우수한 결과를 나타내었다.

Investigation of Adhesion Mechanism at the Metal-Organic Interface Modified by Plasma - Part I

  • Sun, Yong-Bin
    • 한국반도체및디스플레이장비학회:학술대회논문집
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    • 한국반도체및디스플레이장비학회 2002년도 추계학술대회 발표 논문집
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    • pp.123-126
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    • 2002
  • For the mold die sticking mechanism, the major explanation is that EMC filler of silica wears die surface roughened, which results in increase of adhesion strength. As big differences in experimental results from semiconductor manufacturers are dependent on EMC models, however, chemisorptions or acid-base interaction is apt to be also functioning as major mechanisms. In this investigation, the plasma source ion implantation (PSII) using $O_2$, $N_2$, and $CF_4$ modifies sample surface to form a new dense layer and improve surface hardness, and change metal surface condition from hydrophilic to hydrophobic and vice versa. Through surface energy quantification by measuring contact angle and surface ion coupling state analysis by Auger, major governing mechanism for sticking issue was figured out to be a complex of mechanical and chemical factors.

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Carboxylated Nitrile Elastomer/Filler Nanocomposite: Effect of Silica Nanofiller in Thermal, Dynamic Mechanical Behavior, and Interfacial Adhesion

  • Mahaling R. N.;Jana G. K.;Das C. K.;Jeong, H.;Ha C. S.
    • Macromolecular Research
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    • 제13권4호
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    • pp.306-313
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    • 2005
  • Surface modified nanofillers are often used as curative-cum reinforcing agents for functional polymers. The polymer nanofiller interaction depends on the curative systems used. In the present study the carboxylic group of the carboxylated nitrile elastomer participated in the reaction with Zn-ion coated nanosilica filler producing a type of ionomeric elastomer. The interaction at the molecular level thus produced a high modulus vulcanizate. In this case, the S and MBT system, as curative, had an edge over the MDA and DPG curative system. Interfacial adhesion was enhanced in the presence of Zn-ion-coated nanosilica filler associated with dynamic mechanical behavior. The inferior properties obtained in the case of the MDA and DPG curative system were due to the decreased reactivity of the silica surface, thus reducing interfacial adhesion.

Enhancement of Anti-tumorigenic Polysaccharide Production, Adhesion, and Branch Formation of Bifidobacterium bifidum BGN4 by Phytic Acid

  • Ku, Seock-Mo;You, Hyun-Ju;Ji, Geun-Eog
    • Food Science and Biotechnology
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    • 제18권3호
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    • pp.749-754
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    • 2009
  • The polysaccharide (BB-pol) extracted from Bifidobacterium bifidum BGN4 showed growth inhibitory effects on several colon cancer cell lines such as HT-29 and HCT-116. To increase the yield of polysaccharide, B. bifidum BGN4 was cultured in various culture media with different compositions. When B. bifidum BGN4 was cultured in modified MRS broth containing phytic acid, the cells showed increased branch formation and enlarged morphology. The content of total carbohydrate and the ability of adhesion to intestinal epithelial cells were also increased by phytic acid. The polysaccharide obtained from the cells grown in the presence of phytic acid inhibited the proliferation of cancer cell lines such as HT-29 and MCF-7 cells but not normal colon cell line, FHC. Taken together, Bifidobacterium grown in the presence of phytic acid may confer enhanced beneficial function for the host.

Investigation of Adhesion Mechanism at the Metal-Organic Interface Modified by Plasma Part I

  • Sun, Yong-Bin
    • 마이크로전자및패키징학회지
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    • 제9권4호
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    • pp.31-34
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    • 2002
  • For the mold die sticking mechanism, the major explanation is that the silica as a filler in EMC (epoxy molding compound) wears die surface to be roughened, which results in increase of adhesion strength. As the sticking behavior, however, showed strong dependency on the EMC models based on the experimental results from different semiconductor manufacturers, chemisorption or acid-base interaction is apt to be also functioning as major mechanisms. In this investigation, the plasma source ion implantation (PSII) using $O_2, N_2$, and $CF_4$ modifies sample surface to form a new dense layer and improve surface hardness, and change metal surface condition from hydrophilic to hydrophobic or vice versa. Through surface energy quantification by measuring contact angle and surface ion coupling state analysis by Auger, major governing mechanism for sticking issue was figured out to be a complex of mechanical and chemical factors.

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급속여과지에 있어서 현탁물 부착모델에 관한 연구 (A Study on the Adhesion Model of the Deposit in Rapid Filter)

  • 강용태;유동선
    • 수도
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    • 통권30호
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    • pp.57-62
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    • 1984
  • 본 연구는 급속여과지에 있어서 현탁물 부착모델에 관한 연구이다. 금회의 연구를 통하여 수정타원형 부착모델을 제안하여 실측치와 잘 일치하는 여과 저항식을 유도했다. 유도된 이 여과저항식은 금후 급속여과지 설계에 있어서 최적 높이 결정에 기여함으로써 경제적인 급속여과지를 설계하는데 중점을 두고 본 연구를 시행하였다.

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계면확산에 의한 고분자 코팅된 탄소섬유의 계면접착력 변화 연구 (Effect of Diffusion on the Adhesion Behavior of Polymer Coated Carbon Fibers with Vinyl Ester Resins)

  • T. H. Yoon;H. M. Kang
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 1999년도 추계학술발표대회 논문집
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    • pp.32-35
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    • 1999
  • Poly(arylene ether phosphin oxide) (PEPO), Udel$^{\circledR}$ P-1700, Ultem$^{\circledR}$ 1000. poly(hydroxy ether) (PHE), carboxy modified poly(hydroxy ether)(C-PHE) and poly(hydroxy ether ethanol amine) (PHEA) were utilized for a coating of carbon fibers. Interfacial shear strength(IFSS) of polymers to carbon fibers was also evaluated in order to understand the adhesion mechanism. IFSS was measured via micro-droplet tests, and failure surfaces were analyzed by SEM. Diffusion between polymer and vinyl ester resin was investigated as a function of styrene content; 33. 40 or 50wt.% and the solubility parameters of polymers were calculated. The results were correlated to the interfacial shear strength. The highly enhanced interfacial shear strength (IFSS) was obtained with PEPO coating, and marginally improved IFSS with PHE, Udel$^{\circledR}$ and C-PHE coatings, but no improvement with PHEA and Ultem$^{\circledR}$ coatings.

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Effects of Silica Fume Content and Polymer-Binder Ratio on Properties of Ultrarapid-Hardening Polymer-Modified Mortars

  • Choi, Jong Yun;Joo, Myung-Ki;Lho, Byeong Cheol
    • International Journal of Concrete Structures and Materials
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    • 제10권2호
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    • pp.249-256
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    • 2016
  • This paper deals with the effects of silica fume content and polymer-binder ratio on the properties of ultrarapid-hardening polymer-modified mortar using silica fume and ethylene-vinyl acetate redispersible polymer powder instead of styrene-butadiene rubber latex to shorten the hardening time. The ultrarapid-hardening polymer-modified mortar was prepared with various silica fume contents and polymer-binder ratios, and tested flexural strength, compressive strength, water absorption, carbonation depth and chloride ion penetration depth. As results, the flexural, compressive and adhesion strengths of the ultrarapid-hardening polymer-modified mortar tended to increase as increasing polymer-binder ratio, and reached the maximums at 4 % of silica fume content. The water absorption, carbonation and chloride ion penetration resistance were improved according to silica fume content and polymer-binder ratio.