• 폴리머
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• 제37권6호
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• pp.753-763
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• 2013

동종 혹은 이종의 고분자를 레이저로 접착시키는 방법은 레이저 접착이 가지는 장점들로 인해 많은 산업분야에서 광범위하게 사용되고 있다. 산업적으로 많이 사용되는 폴리프로필렌(PP)과 폴리카보네이트(PC)가 레이저 투과용접이 가능하다면 자동차 헤드램프에 큰 이점을 갖고 적용할 수 있을 것이다. 하지만, 폴리프로필렌과 폴리카보네이트는 상용성이 낮아 레이저 접착을 시켜도 강도가 낮은 문제점이 있다. 본 연구에서는 반응압출을 통해 폴리프로필렌을 글리시딜메타크릴레이트(GMA)로 개질하고, 폴리카보네이트와의 상용성, 기계적 물성 및 레이저 투과 용접을 통해 접착성을 조사하였다.

• 한국세라믹학회지
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• 제41권6호
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• pp.430-434
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• 2004

The values of fracture energy and mechanical flexural strength of Fiber Reinforced Cement (FRC) with polypropylene (PP) fiber modified by Ion Assisted Reaction (JAR), by which functional groups were grafted on the surface of PP fiber, was improved about 2 times as those of fracture energy and flexural strength of cement reinforced by untreated PP fiber. PP fiber was irradiated in O$_2$ environment by Ar$\^$+/ ion. The contact angle of PP treated by IAR decreased largely when compared with untreated PP. From this result, we expected that surface energy and interfacial adhesion force of treated PP fiber increased. The strain hardening occurred in the strain-stress curve of FRC including PP treated by IAR when compared with that of FRC with untreated PP. These enhanced mechanical properties might be due to strong interaction between hydrophilic group on modified PP fiber and hydroxyl group in cement matrix. This hydrophilic group on surface modified PP fiber was confirmed by XPS analysis. We clearly observed hydration products that were fixed at modified PP fiber due to the strong adhesion force of interface in cement reinforced modified PP by SEM (Scanning Electron Microscopy) study.

• 접착 및 계면
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• 제13권4호
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• pp.156-162
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• 2012

UV 경화형 우레탄아크릴레이트 수지와 유기화클레이를 혼합한 후 UV를 조사하여 경화시킴으로써 폴리우레탄-클레이 나노복합체를 제조하였다. 유기화클레이로서는 Closite20A (C20A) 및 이를 실란처리하여 표면에 아크릴기를 도입한 아크릴변성 C20A를 사용하였다. XRD와 TEM 분석으로부터 제조된 나노복합체는 삽입형 나노복합체이며, 아크릴 변성시킨 C20A가 변성시키지 않은 C20A에 비해 더 잘 분산되는 것을 알 수 있었다. DMTA, 연필경도분석, PET 필름에의 부착성 시험으로부터 클레이 첨가에 의해 유리전이온도와 저장탄성률 및 연필경도가 증가하고 PET 필름에의 부착성이 향상되며, 이러한 물리적 특성의 증가는 아크릴 변성시킨 C20A를 함유한 나노복합체에서 더 크게 발현됨을 알 수 있었다. 또한, 클레이 첨가에 의해 UV경화 시 수반되는 수축을 저하시킬 수 있음을 알았다. 한편, 제조된 나노복합체는 우수한 광투과도를 나타내었으나, 광택도는 나노입자를 함유하지 않은 경우에 비해 다소 저하되었다.

• 접착 및 계면
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• 제22권1호
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• pp.8-15
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• 2021

본 연구에서는 우레탄 변성 에폭시의 유연성 부여를 위해 propylene glycol(PPG) 기반 diamine인 Jeffamine D-400을 이용하여 폴리올을 만들고 이를 이용하여 우레탄 변성 에폭시를 합성하였다. Bisphenol A diglycidyl ether(BADGE)에 합성한 우레탄 변성 에폭시와 경화제, 경화촉진제를 배합하여 에폭시 접착제를 제조하고 접착강도 측정으로 전단 강도를 측정하였다. 측정 결과 합성한 우레탄 변성 에폭시의 우레탄 결합과 PPG사슬 도입을 통한 유연성 부여 효과로 인해 전단 강도와 전단 신율이 증가하는 경향을 보였다. 이러한 결과는 높은 가교 밀도로 인해 사용에 제약을 받고 있는 구조용 접착제에 적용이 가능할 것으로 판단된다.

• Korean Chemical Engineering Research
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• 제50권1호
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• pp.6-10
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• 2012

본 연구의 목적은 styrene-butadiene-styrene(SBS) 블록공중합체와 폐타이어 고무분말(crumb rubber, CR)로 개질한 아스팔트의 저온접착특성에 대해 파라핀오일 가소제의 영향에 대한 것이다. SBS/CR로 개질한 아스팔트 블렌드와 파라핀오일/SBS/CR 아스팔트 블렌드의 온도 민감성을 침입도와 연화점으로 측정하였다. 형광현미경으로 파라핀오일/SBS/CR 아스팔트 블렌드에 대한 개질제들의 분산 상태와 만능시험기로 저온에서 접착성질을 각각 측정하였다. 저온접착시험에서 SBS 함량의 증가와 파라핀오일 함량 5 wt % 및 10 wt %에서 접착강도와 변형률이 증가하였다. $-20^{\circ}C$에서 측정한 접착강도와 강인성은 파라핀오일이 10 wt %와 SBS 공중합체의 양이 6 wt %인 조성에서 최대값을 얻었다. SBS/CR/아스팔트 블렌드에서 파라핀오일의 첨가는 유연성을 부여하는 효과를 나타내고, 저온에서 강인성의 증가를 가져오는 것을 확인하였다.

• Tribology and Lubricants
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• 제18권1호
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• pp.1-8
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• 2002

Nano adhesion and friction between a $Si_{3}N_{4}$ AFM(atomic force microscope) tip and thin silver films were experimentally studied. Tests were performed to measure the nano adhesion and friction in both AFM and LFM(lateral force microscope) modes in various range of normal loads. Thin silver films deposited by IBAD (ion beam assisted deposition) on Si-wafer (100) and other Si-wafers of different surface roughness were used. Results showed that nano adhesion and friction decreased with the surface roughness. When the Si surfaces were coated by pure silver, the adhesion and friction decreased. But the adhesion and friction were not affected by the thickness of IBAD silver coating. As the normal force increased, the adhesion forces of bare Si-wafer and IBAD silver coating film remained constant, but the friction forces increased linearly. Test results suggested that the friction was mainly governed by the adhesion as long as the load was low.

• 접착 및 계면
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• 제3권1호
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• pp.13-19
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• 2002

We have studied on the surface and adhesion properties for acrylic terpolymers, having both hydrophobic and hydrophilic side chains, synthesized via solution polymerization. In order to develop a waterborne material. we tried to synthesize these terpolymers via emulsion polymerization. The polymeric emulsion synthesized was mainly composed of methyl methacrylate (MMA), methoxy-polyethyleneglycol methacrylate (MPEGMA) having hydrophilic side chains and methoxypolypropyleneglycol methacrylate (MPEGMA) having hydrophobic side chains. The viscosities of this series increased with an increase in the content of the co-monomer such as MPEGMA and (MPEGMA). This behavior resulted in the increase in the diameter and heterogeneity of the emulsion particle via AFM observation. Furthermore. the tensile adhesion strength and 90-degree peel strength of the adhesive of these polymeric emulsions were measured. In the case of polymeric emulsion composed of the same content of both hydrophilic and hydrophobic component, the adhesion property showed the highest value. However, since the adhesion properties as a practical applicable adhesive were poor, some improvements were required. When the composition above was modified with butyl acrylate (BA), the improvement effect on adhesion strength was accepted. In particular, 90-degree peel strength increased up to a maximum of 400% of the original value.

• International Journal of Concrete Structures and Materials
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• 제2권1호
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• pp.3-8
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• 2008

Polymer-cement composites are known repair materials. The aim of this work is to investigate the influence of various amount of dispersion of carboxylated styrene-butadience copolymer on the selected mechanical properties of polymer-cement concrete (PCC) and on its adhesion to ordinary concrete. The compressive, flexural and tensile strengths as well as frost resistance and fracture resistance of the composites are tested. Adhesion strength of PCC to ordinary concrete, as one of most important performance of good repair material is evaluated and analyzed using three test methods. The results obtained in standard pull-off test are compared with the two other tests. The first one, which is an adaptation of WST (wedge splitting test) characterizes crack propagation in the plane of bond created during repair. In the second test the resistance to shear is a measure of adhesion strength.

• Macromolecular Research
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• 제8권4호
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• pp.179-185
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• 2000

Generally vascular grafts with a relatively large inner diameter (> 5 mm) have been successfully employed for replacement in the human body. However, the use of small diameter grafts is limited, because these grafts rapidly occlude due to the thrombosis. The ideal blood-contacting surface of a prosthesis would be an endothelial cell (EC) lining, because the confluent monolayer of healthy ECs that culture natural blood vessels represents the ideal nonthrombogenic surface. For vascular graft application, the stable EC adhesion on surface under How conditions is very important. In this study, the adhesive strength of ECs attached on polymer surfaces coated with collagen type IV (Col IV), fibronectin (Fn), laminin (Ln), and treated with corona was investigated onto polyurethane (PU) films. The EC-attached PU surfaces were mounted on parallel-plate flow chambers in a How system prepared for cell adhesiveness test. Three different shear stresses (100, 150, and 200 dyne/㎠) were applied to the How chambers and each shear stress was maintained for 120 min to investigate the effect of shear stress and surface treatment condition on the EC adhesion strength. It was observed that the EC adhesion strength on the surface-modified PU films was in the order of Ln≡Fn > Col IV > corona 》 control. More than 70% of the adhered cells were remained on surface-modified PU surface after applying the shear stress,200 dyne/㎠ for 2 hrs, whereas the cells were completely detached on the control PU surface within 10 min after applying the same shear stress. It seems that the type of adsorbed proteins and hydrophilicitv onto the PU surfaces play very important roles for cell adhesion strength.

• 한국도로학회:학술대회논문집
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• 한국도로학회 2008년도 추계학술대회 논문집
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• pp.455-458
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• 2008