• Title/Summary/Keyword: Modified PP

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Interfacial Evaluation of Surface Treated Jute Fiber/Polypropylene Composites Before and After Hydration Using Micromechanical Test (미세역학적 시험법을 이용한 표면처리된 Jute 섬유 강화 폴리프로필렌 복합재료의 수화 전·후 계면물성 평가)

  • Kim, Pyung-Gee;Jang, Jung-Hoon;Park, Joung-Man;Hwang, Byung-Sun
    • Journal of Adhesion and Interface
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    • v.8 no.3
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    • pp.9-15
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    • 2007
  • The interfacial evaluation of surface modified Jute fiber/polypropylene (PP) composites before and after hydration was investigated using micromechanical test and dynamic contact angle measurement. The IFSS of alkaline and silane-treated Jute fiber/PP composites increased, whereas after hydration, the IFSS of the untreated, alkaline- and silane-treated Jute fibers/PP composites decreased due to swelled fibrils by water infiltration. The interfacial adhesion of silane treated fiber/PP composites was higher than alkaline-treated or the untreated cases. The surface energies of Jute fiber treated under various conditions were obtained using dynamic contact angle measurement. Especially after hydration, the thermodynamic work of adhesion was calculated by considering water interlayer, which indicated the stability of IFSS between silane treated Jute fiber and PP matrix showing better than others.

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Determination of Molecular Weight and Molecular Weight Distribution of Polypropylene Using Rheological Properties (유변학적 물성을 이용한 폴리프로필렌의 분자량과 분자량 분포를 결정하는 방법)

  • Lee, Young Sil;Yoon, Kwan Han
    • Polymer(Korea)
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    • v.38 no.6
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    • pp.735-743
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    • 2014
  • The rheological measurement of polypropylene (PP) has been performed using a rheometer, an intrinsic viscometer, and an MI machine to predict the molecular weight and the molecular weight distribution. Also, GPC has been used for the determination of the molecular structure. The distribution broadness parameter using modified Carreau model has been used to make the correlation between the rheological parameter and the molecular structure instead of the rheological PI (polydispersity index) which is determined from the cross of modulus from the dynamic oscillatory measurement. Even though the rheological PI is useful to determine the molecular weight distribution of the PP using controlled rheology, which has narrow and uniform molecular weight distribution, but not suitable to determine the molecular weight distribution of the PP made from direct polymerization which has broad and various molecular weight distribution. However the distribution broadness parameter which determined from the index of the shear thinning of the PP melt well predicts the molecular weight distribution of PP.

Interfacial Evaluation of Modified Jute and Hemp Fibers/Polypropylene (PP)-Maleic Anhydride Polypropylene Copolymers (PP-MAPP) Composites Using Micromechanical Test and Nondestructive Acoustic Emission (Micromechanical 시험법과 음향방출을 이용한 Flax 와 Hemp 섬유 강화 에폭시 복합재료의 계명 물성 평가)

  • Son, Tran Quang;Hwang, Byung-Sun;Park, Joung-Man
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.157-160
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    • 2005
  • The surface energies and acid-base interaction between the untreated and treated Jute or Hemp fibers and different matrix compositions of polypropylene-maleic anhydride polypropylene copolymers (PP-MAPP) were investigated using dynamic contact angle measurement. The contribution of the acid-base property into the interfacial adhesion of the natural fibers/matrix systems were characterized by calculating the work adhesion coming from the acid-base interaction. On the other hand, microfailure mechanism of both single Jute and Hemp fiber bundles were investigated using the combination of single fiber tensile test and acoustic emission. Distinctly different micro failure modes of the different natural fiber/polypropylene systems wet ε observed using optical microscope and determined indirectly by AE and their FFT analysis.

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Temperature Dependence of Conductivities of Recyclable Polyethylene and Polypropylene and its Effects on Electric Field Distribution in Power Cable (재활용 가능한 폴리에틸렌과 폴리프로필렌의 전도도 온도의존성과 전력케이블 내의 전계분포에 미치는 영향)

  • Lee, June-Ho;Kong, Tae-Sik;Kim, Seong-Jung;Kwon, Ki-Hyung;Cho, Kyu-Cheol;Hozumi, Naohiro
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.10
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    • pp.1881-1887
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    • 2011
  • In this work the recyclable new polyethylene(PE) and polypropylene(PP), which are thermoplastic, have been investigated as the eco-friendly insulating candidates to replace the cross-linked polyethylene (XLPE). The temperature dependence of conductivities of these materials has been measured and its effects on electric field and space charge distribution in polymeric insulated power cable under temperature gradient have been calculated. It is shown that the sensitivity of conductivity to temperature change has more critical influence to determine the electric field distribution in the power cable than the absolute value of conductivity does and it can be said that the temperature dependence is one of most important factors for the power cable design.

Hydrophilic Modification of Polypropylene Hollow Fiber Membrane by Dip Coating, UV Irradiation and Plasma Treatment

  • Kim Hyun-Il;Kim Jin Ho;Kim Sung Soo
    • Korean Membrane Journal
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    • v.7 no.1
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    • pp.19-27
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    • 2005
  • PP hollow fiber membrane was hydrophilized by EVOH dip coating followed by low temperature plasma treatment and UV irradiation. EVOH coating attained high water flux without any prewetting but its stability did not guaranteed at high water permeation rate. At high water permeation rate, water flux declined gradually due to swelling and delamination of the EVOH coating layer causing pore blocking effect. However, plasma treatment reduces the swelling, which suppress delamination of the EVOH coating layer from PP support result in relieving the flux decline. Also, UV irradiation helped the crosslinking of the EVOH coating layer to enhance the performance at low water permeation rate. FT-IR and ESCA analyses reveal that EVOH dip coating performed homogeneously through not only membrane surface but also matrix. Thermogram of EVOH film modified plasma treatment and W irradiation show that crosslinking density of EVOH layer increased. Chemical modification by plasma treatment and UV irradiation stabilized the hydrophilic coating layer to increase the critical flux of the submerged membrane.

Thermal and Dynamic-Mechanical Characterization of Rice-Husk Filled Polypropylene Composites

  • Rosa, Simone M.L.;Nachtigall, Sonia M.B.;Ferreira, Carlos A.
    • Macromolecular Research
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    • v.17 no.1
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    • pp.8-13
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    • 2009
  • Natural fiber-filled polymer composites have attracted great interest due to increasing environmental concerns and their low costs. In this study, the properties of rice husk flour-filled polypropylene (PP) were analysed in view of the large quantities of this agricultural product available as residue in Brazil. The rice husk flour (RHF) was characterized by SEM and particle size distribution. The properties of the composites were studied by MFI, DMA, DSC and TGA analyses. A commercial PP modified with maleic anhydride (MAPP) was used as coupling agent. It was verified that RHF decreased the MFI of the composites and that the coupling agent decreased it even more. The efficiency of MAPP was confirmed by the high storage modulus and high loss factor of the coupled composites.

Fabrication method of PDMS microlensesusing water-based molding method (표면개질에 의한 물방울 접촉각 변화를 이용하여 제작된 PDMS 마이크로 렌즈)

  • Kim, Hong-Ki;Yun, Kwang-Seok
    • Journal of Sensor Science and Technology
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    • v.17 no.5
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    • pp.375-379
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    • 2008
  • This paper reports a new fabrication method of polydimethylsiloxane (PDMS) microlenses with various curvatures by using a water-based mold. The hydrophobic surface of Polypropylene (PP) substrate was modified by corona discharge using tesla coil to have hydrophilic surface. Then hydrophilic surface of PP substrate takes hydrophobic recovery to have various contact angles from less than $25^{\circ}$ to about $84^{\circ}$. By using the water droplets with various contact angles as replica molds for PDMS process, we could obtain PDMS microlenses with various curvatures.

A Study on the Three Phase Glass Fiber/Nylon 6/Polyproylene Composites (나일론 6과 폴리프로필렌 수지에 유리섬유가 보강된삼상 복합재료에 관한 연구)

  • 서문호
    • The Korean Journal of Rheology
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    • v.10 no.2
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    • pp.57-64
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    • 1998
  • A pultrusion resin impregnation (PRI) die, which has been developed recently in our laboratory, was used to pre-pare various composite system. The continuous fiber reinforced composites of glass fiber/polypropylene(GFPP) and glass fiber/polyamide 6 (GFPA) were first manufactured by means of the PRI die and then cut into chopped pellets of predet-ermined length. These pellets and either virgin or modified thermoplastic resin were melt-mixed by a twin screw extruder to prepare GF/PA/PP and GF/PA/PPMA system. The mechanical properties of these blends were investigated and discussed in terms of their morphological observations. These preliminary results revealed that this new impregnation die could be suc-cessfully applied to produce prepregs suitavle for the final shaping process.

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Injection-Acupuncture with Dexamethasone and Modified Moxibustion Treatment of a Downer Cow (기립 불능 우에 있어서 덱사메타손 수침 및 간이 뜸 치료)

  • Kim Duck-Hwan;Liu Jian-Zhu;MacManus Philip;Jennings Padraic;Darcy Karl;Burke Fiona;Slattery Gerry;Rogers Phil A.M.
    • Journal of Veterinary Clinics
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    • v.23 no.1
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    • pp.69-71
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    • 2006
  • An 11-year-old, Shorthorn cow, reared near Gort Co. Galway, Ireland, needed assistance to calve. The cow became a downer on that day postpartum (pp). Injection-acupuncture with dexamethasone was used at lumbo-sacral space, GB30, ST36, GB31, BL40, ST40 and ST41. In addition, modified moxibustion was received at session 1. At session 2, the cow could not stand. At session 3, the cow tried to stand twice by herself but fell down again each time. However, she stood up with slight help on 10 days pp. The present patient was a case with downer cow syndrome which showed improvement of clinical symptoms by injection-acupuncture with dexamethasone plus modified moxibustion.

Preparation and Characterization of Polypropylene/Montmorillionite Nanocomposites (폴리프로필렌/몬모릴로나이트 나노복합체의 제조 및 물성)

  • Lee Sang-Uk;Oh In-Hwan;Lee Jae Heung;Choi Kil-Yeong;Lee Sung-Goo
    • Polymer(Korea)
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    • v.29 no.3
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    • pp.271-276
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    • 2005
  • Polypropylene (PP)/montmorillonite (MMT) nanocomposites were prepared by melt mixing methods. MMT modified by dimethyl hydrogenated tallow 2-ethylhexyl ammonium (Cloisite 15A) was used. Polyolefine oligomer with telechelic OH groups was used as a compatibilizer. The degree of dispersion of MMT in the nanocomposites was measured by X-ray diffractometer and transmission electron microscope (TEM) images. MMT was well exfoliated when the contents of compatibilizer was 25 phr. The thermal stability that observed by thermogravimetric analysis (TGA) increased with the contents of MMT increased up to 5 phr. The complex viscosities and storage moduli of PP nanocomposites enhanced as the contents of compatibilizer decreased and those of MMT increased.