• Title/Summary/Keyword: Model compound

Search Result 878, Processing Time 0.027 seconds

Development and Application of an In Situ Technology to Treat Various Soil and Groundwater Contaminants

  • Goltz, Mark N.
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 2003.10a
    • /
    • pp.89-110
    • /
    • 2003
  • The limitations of conventional soil and groundwater contamination remediation technologies have motivated a search for innovative technologies; particularly in situ technologies that do not require extraction of contaminants from the subsurface. All engineered in situ remediation systems require that the contaminant be mixed with a remedial compound. Horizontal flow treatment wells (HFTWs), an innovative technology that consists of a pair of dual-screened treatment wells, were used at a trichloroethylene (TCE) contaminated site to efficiently achieve this mixing of contaminant and remedial compound in order to effect in situ bioremediation (McCarty et al., 1998). In this paper, the potential of HFTWs to treat chlorinated aliphatic hydrocarbons (CAHs) as well as other soil and groundwater contaminants of concern, such as nitroaromatic compounds (NACs), perchlorate, and methyl-tert-butyl ether (MTBE), is examined. Through a combination of laboratory studies, model analyses, and field evaluations, the effectiveness of this innovative technology to manage these contaminants is investigated.

  • PDF

Experimental and Numerical Studies of the Flowfield around an Axisymmetric Body (축대칭 물체 주위유동의 실험적·수치적 연구)

  • Ahn, Jong-Woo;Song, In-Haeng;Park, Tae-Sun
    • Journal of the Society of Naval Architects of Korea
    • /
    • v.34 no.3
    • /
    • pp.9-18
    • /
    • 1997
  • Experimental and numerical studies are carried out to investigate flow characteristics around an axisymmetric body with and without a compound propulsor. The effects of a compound propulsor are investigated as measuring the surface pressure distribution and the velocity profiles using LDV system in the cavitation tunnel of KRISO. The incompressible Reynolds-Averaged Navier-Stokes(RANS) equations are also solved using the finite volume method. The standard k-${\varepsilon}$ turbulence model is adopted for turbulence closure. In order to calculate propeller-hull interaction, the induced velocity calculated by lifting surface theory is considered as the boundary condition at the propeller plane. The experimental data obtained in this study can provide a useful database for development and validation of CFD code.

  • PDF

Ferromagnic Transitition Temperature of Diluted Magnetic III-V Based Semiconductor (III-V 화합물 자성 반도체의 강자성체 천이온도에 관한 연구)

  • Lee, Hwa-Yong;Kim, Song-Gang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2001.05c
    • /
    • pp.143-147
    • /
    • 2001
  • Ferromagnetism in manganese compound semiconductors open prospects for tailoring magnetic and spin-related phenomena in semiconductors with a precision specific to III-V compounds. Also it addresses a question about the origin of the magnetic interactions that lead to a Curie temperature(Tc) as high as 110 K for a manganese concentration of just 5%. Zener's model of ferromagnetism, originally suggested for transition metals in 1950, can explain Tc of $Ga_{1-x}Mn_x$ As and that of its IT-VI counterpart $Zn_{1-x}Mn_x$ Te and is used to predict materials with Tc exceeding room temperature, an important step toward semiconductor electronics that use both charge and spin. In this article, we present not only the experimental result but calculated Curie temperature by RKKY interaction. The problem in making III-V semiconductor has been the low solubility of magnetic elements, such as manganese, in the compound, since the magnetic effects are roughly proportional to the concentration of the magnetic ions. Low solubility of magnetic elements was overcome by low-temperature nonequilibrium MBE{molecular beam epitaxy) growth, and ferromagnetic (Ga,Mn)As was realized. Magnetotransport measurements revealed that the magnetic transition temperature can be as high as 110 K for a small manganese concentration.

  • PDF

Molecular and Crystal Structure of' Metalaxyl, $C_{15}H_{21}NO_4$ (Metalaxyl, $C_{15}H_{21}NO_4$의 분자 및 결정구조)

  • Keun Il Park;Young Kie Kim;Sung Il Cho;Man Hyung Yoo
    • Korean Journal of Crystallography
    • /
    • v.13 no.3_4
    • /
    • pp.148-151
    • /
    • 2002
  • The molecular and crystal structure of metalaxyl C/sub15/H/sub21/NO₄, was determined by single crystal x-ray diffraction study. Crystallographic data for, title compound P2₁/c, a=7.849(4) Å, b=13.081(5) Å, c=15.100(3) Å, β=101.8(2)°, V= 1517.6(3) ų, Z=4. The molecular. Structure model was solved by direct method and refined by full-matrix least- squares. The final reliable factor, R, is 0.067 for 1694 independent reflections (F/sub o//sup 2/>4σ(F/sub o//sup 2/)). The molecular structure of title compound shows an intramolecular hydrogen bond: Cl2-Hl2A…O1.

Electronic Structure and Properties of High-$T_c$ Substitued YBCO Superconductor: Ⅱ. MO Calculations on Charged Cluster Models Relating to High-$T_c$ Se-Substituted YBCO Superconductors

  • Lee, Kee-Hag;Lee, Wang-Ro;Choi, U-Sung
    • Bulletin of the Korean Chemical Society
    • /
    • v.15 no.7
    • /
    • pp.545-549
    • /
    • 1994
  • Using the extended Hackel molecular orbital method in connection with the tight binding model, we have studied electronic structure and related properties of the charged cluster models relating to superconducting $YBa_{2}Cu_{3}O_{7-x}$, crystals in which O-atoms in regular sites were selectively replaced with Se atoms. In analogy to the isomorphism problem with molecules, we discuss all possible combinations of Se-substitutions in O-sites with one, two, and four Se atoms. The calculations are carried out within charged cluster models for analogues of YBa-copper oxide. Our results suggest that the electronic structure of the symmetrically Se-substituted or Se-added compound is closer to that of the YBCO superconducting compound than that obtained from the unsymmetrical substitution. This applies in particular if O is replaced with Se around the Cu(1) site. Symmetrical substitutions in the $CuO_2$ layers give rise to large variations in the electronic structure of $YBa_{2}Cu_{3}O_{7}$. This is consistent with the fact that superconductivity is very sensitive to the electronic population of the $CuO_2$ layers.

A Study on the Numerical Analysis of VOCs Emission from Plywood Floor Material (수치해석을 활용한 합판마루 바닥재의 VOCs 방출에 관한 연구)

  • Kim Ji-Hye;Kang Dong-Hwa;Choi Dong-Hee;Kim Sun-Sook;Yeo Myoung-Souk;Kim Kwang-Woo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.17 no.12
    • /
    • pp.1123-1131
    • /
    • 2005
  • The floor material is known as the most influential emission source of the residential building, because most floor material is made of wood compound and adhesive like a plywood flooring. Moreover, floor heating system keeps the inside temperature of the material high. As the emission of hazardous chemical compound from the construction material is influenced by many factors, it is necessary to analyze the emission characteristics of the floor material to improve IAQ. In this study, numerical analysis is performed to investigate the emission characteristics of the floor material affected by several factors such as temperature, air exchange rate, initial concentration, and internal diffusion coefficient. A simulation program is also written based on the mass transfer theory. The simulation results show that there is some level of difference on the TVOC concentration when each of the factors is variable.

Synthesis and Liquid Crystalline Properties of the Compounds Consisting of a Schiff Base Type Mesogen and a Dyad Type Aromatic Ester Structure Interconnected Through the Central Hexamethylene Spacer

  • Jung-Il Jin;Hyo-Seok Kim;Jin-Wook Shin;Bong Young Chung;Byung-Wook Jo
    • Bulletin of the Korean Chemical Society
    • /
    • v.11 no.3
    • /
    • pp.209-214
    • /
    • 1990
  • A series of compounds consisting of 4'-oxybenzylidene-4-n-butylaniline, a mesogen, and a p-substituted phenoxyterephthaloyl structure a non-mesogen, interconnected through a central hexamethylene spacer were synthesized and their thermal behavior and liquid crystallinity were studied. p-Substituents included in this study are H, Cl, CN, $NO_2,\;n-C_4H_9O$ and phenyl groups. The compounds having phenyl and $n-C_4H_9O$ substituents are enantiotropic and form smectic-A(SA) and nematic (N) phases. The compound with $NO_2$ substituent is monotropic and forms only a nematic phase on heating the solid, whereas it forms nematic as well as $S_A$ phases on cooling the isotropic liquid. The rest compounds were found to be non-liquid crystalline. This is in great contrast to the fact that the monomesogenic model compound 4'-n-hexyloxybenzylidine-4-n-butylaniline forms $S_B,\;S_C,\;S_A$ and N phases enantiotropically.

Suppressive Effect of 4-Hydroxy-2-(4-Hydroxyphenethyl) Isoindoline-1,3-Dione on Ovalbumin-Induced Allergic Asthma

  • Huang, Jin;Su, Mingzhi;Lee, Bo-Kyung;Kim, Mee-Jeong;Jung, Jee H.;Im, Dong-Soon
    • Biomolecules & Therapeutics
    • /
    • v.26 no.6
    • /
    • pp.539-545
    • /
    • 2018
  • 4-Hydroxy-2-(4-hydroxyphenethyl)isoindoline-1,3-dione (PD1) is a synthetic phthalimide derivative of a marine compound. PD1 has peroxisome proliferator-activated receptor (PPAR) ${\gamma}$ agonistic and anti-inflammatory effects. This study aimed to investigate the effect of PD1 on allergic asthma using rat basophilic leukemia (RBL)-2H3 mast cells and an ovalbumin (OVA)-induced asthma mouse model. In vitro, PD1 suppressed ${\beta}$-hexosaminidase activity in RBL-2H3 cells. In the OVA-induced allergic asthma mouse model, increased inflammatory cells and elevated Th2 and Th1 cytokine levels were observed in bronchoalveolar lavage fluid (BALF) and lung tissue. PD1 administration decreased the numbers of inflammatory cells, especially eosinophils, and reduced the mRNA and protein levels of the Th2 cytokines including interleukin (IL)-4 and IL-13, in BALF and lung tissue. The severity of inflammation and mucin secretion in the lungs of PD1-treated mice was also less. These findings indicate that PD1 could be a potential compound for anti-allergic therapy.

Theoretical Study of Flourine Doping Effect on the Y-Ba-Cu-O Superconductor (Y-Ba-Cu-O 초전도체의 불소 도핑효과에 대한 이론적 연구)

  • Choi, U-Sung;Park, Choon-Bae;Song, Min-Jong;Lee, Wang-Ro;Lee, Kee-Hag
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1993.05a
    • /
    • pp.134-136
    • /
    • 1993
  • Using the extended H$\ddot{u}$ckel molecular orbital method in connection with the tight binding model, we have studied electronic structure and related properties of superconducting $YBa_2Cu_3O_{7-x}$ crystals in which O-atoms in regular sites were selectively replaced with F atoms. The calculations are based on the crystal structure of Y-Ba-Cu-O obtained by Beno et al.. We use atomic coordinates that refer to the unrelaxed Y-Ba-Cu-O system. In analogy to the isomerism problem with molecules, we discuss all possible combinations of F-substitutions in O-sites with one, two, and four F atoms. The calculations are carried out within charged clusters model for the analogues of the YBa-free copperoxide. Our results suggest that the electronic structure of the symmetrically F-substituted or F-added compound is closer to that of the oxygen-deficient superconducting compound than that obtained from unsymmetrical substitution. This applies in particular if O is replaced with in an O(1) site. This suggests that superconductivity is very sensitive to the oxygen content of the $CuO_2$ layers.

  • PDF

Gymnaster koraiensis and its major components, 3,5-di-O-caffeoylquinic acid and gymnasterkoreayne B, reduce oxidative damage induced by tert-butyl hydroperoxide or acetaminophen in HepG2 cells

  • Jho, Eun Hye;Kang, Kyungsu;Oidovsambuu, Sarangerel;Lee, Eun Ha;Jung, Sang Hoon;Shin, Il-Shik;Nho, Chu Won
    • BMB Reports
    • /
    • v.46 no.10
    • /
    • pp.513-518
    • /
    • 2013
  • We investigated the protective effects of Gymnaster koraiensis against oxidative stress-induced hepatic cell damage. We used two different cytotoxicity models, i.e., the administration of tert-butyl hydroperoxide (t-BHP) and acetaminophen, in HepG2 cells to evaluate the protective effects of G. koraiensis. The ethyl acetate (EA) fraction of G. koraiensis and its major compound, 3,5-di-O-caffeoylquinic acid (DCQA), exerted protective effects in the t-BHP-induced liver cytotoxicity model. The EA fraction and DCQA ameliorated t-BHP-induced reductions in GSH levels and exhibited free radical scavenging activity. The EA fraction and DCQA also significantly reduced t-BHP-induced DNA damage in HepG2 cells. Furthermore, the hexane fraction of G. koraiensis and its major compound, gymnasterkoreayne B (GKB), exerted strong hepatoprotection in the acetaminophen-induced cytotoxicity model. CYP 3A4 enzyme activity was strongly inhibited by the extract, hexane fraction, and GKB. The hexane fraction and GKB ameliorated acetaminophen-induced reductions in GSH levels and protected against cell death.