• Title/Summary/Keyword: MnS

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The Detection of Magnetic Properties in Blood and Nanoparticles using Spin Valve Biosensor (스핀밸브 바이오 센서를 이용한 혈액과 나노입자의 자성특성 검출)

  • Park, Sang-Hyun;Soh, Kwang-Sup;Ahn, Myung-Cheon;Hwang, Do-Guwn;Lee, Sang-Suk
    • Journal of the Korean Magnetics Society
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    • v.16 no.3
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    • pp.157-162
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    • 2006
  • In this study, a high sensitive giant magnetoresistance-spin valve (GMR-SV) bio-sensing device with high linearity and very low hysteresis was fabricated by photolithography and ion beam deposition sputtering system. Detection of the Fe-hemoglobin inside in a red blood and magnetic nanoparticles using the GMR-SV bio-sensing device was investigated. Here a human's red blood includes hemoglobin, and the nanoparticles are the Co-ferrite magnetic particles coated with a shell of amorphous silica which the average size of the water-soluble bare cobalt nanoparticles was about 9 nm with total size of about 50 nm. When 1 mA sensing current was applied to the current electrode in the patterned active GMR-SV devices with areas of $5x10{\mu}m^2 $ and $2x6{\mu}m^2 $, the output signals of the GMRSV sensor were about 100 mV and 14 mV, respectively. In addition, the maximum sensitivity of the fabricated GMR-SV sensor was about $0.1{\sim}0.8%/Oe$. The magnitude of output voltage signals was obtained from four-probe magnetoresistive measured system, and the picture of real-time motion images was monitored by an optical microscope. Even one drop of human blood and nanopartices in distilled water were found to be enough for detecting and analyzing their signals clearly.

Shear bond strength of dentin bonding agents cured with a plasma arc curing light (전단접착강도와 관련된 Plasma Arc Curing Light의 중합효율평가)

  • Kwon, Young-Chul;Kim, Sun-Young;Chung, Sae-Joon;Han, Young-Chul;Lee, In-Bog;Son, Ho-Hyun;Um, Chung-Moon;Cho, Byeong-Hoon
    • Restorative Dentistry and Endodontics
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    • v.33 no.3
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    • pp.213-223
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    • 2008
  • The objective of this study was to compare dentin shear bond strength (DSBS) of dentin bonding agents (DBAs) cured with a plasma arc (PAC) light curing unit (LCU) and those cured with a light emitting diode (LED) LCU. Optical properties were also analyzed for Elipar freelight 2 (3M ESPE); LED LCU, Apollo 95E (DMT Systems); PAC LCU and VIP Junior (Bisco); Halogen LCU. The DBAs used for DSBS test were Scotchbond Multipurpose (3M ESPE), Singlebond 2 (3M ESPE) and Clearfil SE Bond (Kuraray). After DSBS testing, fractured specimens were analyzed for failure modes with SEM. The total irradiance and irradiance between 450 nm and 490 nm of the LCUs were different. LED LCU showed narrow spectral distribution around its peak at 462 nm whereas PAC and Halogen LCU showed a broad spectrum. There were no significant differences in mean shear bond strength among different LCUs (P > 0.05) but were significant differences among different DBAs (P < 0.001)

Comparison of Chemical Compositions of Size-segregated Atmospheric Aerosols between Asian Dust and Non-Asian Dust Periods at Background Area of Korea

  • Kim, Won-Hyung;Song, Jung-Min;Ko, Hee-Jung;Kim, Jin Seog;Lee, Joung Hae;Kang, Chang-Hee
    • Bulletin of the Korean Chemical Society
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    • v.33 no.11
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    • pp.3651-3656
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    • 2012
  • The size-segregated atmospheric aerosols have been collected at 1100 m site of Mt. Halla in Jeju, a background area in Korea, using 8-stage cascade impact air sampler during Asian dust and non-Asian dust storm periods. Their ionic and elemental species were analyzed, in order to examine the pollution characteristics and composition change between Asian dust and non-Asian dust periods. The major ionic species such as nss-$SO_4{^{2-}}$, $NH_4{^+}$, and $K^+$ were predominantly distributed in the fine particles (below $2.1{\mu}m$ diameter), and besides the $NO_3{^-}$ was distributed more in coarse particle fraction than fine particle. On the other hand, the typical soil and marine species i.e., nss-$Ca^{2+}$, $Na^+$, $Cl^-$, and $Mg^{2+}$, were mostly existed in the coarse particles (over $2.1{\mu}m$ diameter). As well in the elemental analysis of aerosols, the major soil-originated Al, Fe, Ca, and others showed prominently high concentrations in the coarse particle fraction, whereas the anthropogenic S and Pb were relatively high in the fine particle fraction. From the comparison of aerosol compositions between Asian dust and non-Asian dust periods, the concentrations of the soil-originated species such as nss-$Ca^{2+}$, Al, Ca, Fe, Ti, Mn, Ba, Sr have increased as 2.7-4.2 times during the Asian dust periods. Meanwhile the concentrations of nss-$SO_4{^{2-}}$ and $NO_3{^-}$ have increased as 1.4 and 2.0 times, and on the contrary $NH_4{^+}$ concentrations have a little bit decreased during the Asian dust periods. Especially the concentrations of both soil-originated ionic and elemental species increased noticeably in the coarse particle mode during the dust storm periods.

Geochemical Characteristics of Stream Sediments and Waters around the Pungam Landfill in Gwangju City, Korea (광주광역시 풍암매립지 주변 하상퇴적물과 물의 지구화학적 특성)

  • Park, Cheon-Young;Shim, In-Hyun;Bae, Jong-Phill;Ahn, Kun-Sang
    • Journal of the Korean earth science society
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    • v.24 no.4
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    • pp.290-302
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    • 2003
  • This study was carried out to evaluate geochemical properties for stream sediments, surrounding soils, sludge collected in the drainage pipe of leachate and waters (stream water, groundwater, leachate) around the Pungam Landfill in Gwangju city. The stream sediments don't show any systematic trend of contents from upstream to downstream. The most enriched major element in the stream sediments is Fe (up to 7.08wt.% in GJ-23). Though stream sediment GJ-23 and GJ-34 were enriched by some heavy metals (eg. As, Cu, Zn), they do not constitute serious problems for environment consideration. The concentration of Fe (35.lwt.%) and As (38ppm) are significantly high in the GJ-8, which is soil specimen adjacent to leachate reservoir. The sludge (GJ-7) shows very high concentrations of As, Mn, Cr, Pb. In particular, the Cr content is 45.6 ppm, which exceeds the permitted level. The leachate is characterized by high TDS (2210-2470mg/L) and high electric conductivity (468, 530ms/cm), and enriched in both cation (Na, K) and anion (HCO$_3$). The leachate(PK-3) had a relatively high concentration of Cl, and is plotted in Na-Cl type on the Piper's diagram. The NO$_3$-N of the groundwater and stream water exceeded the permitted levels for drinking water.

Concentration of metallic elements in surface sediments at a waste disposal site in the Yellow Sea (황해 폐기물 투기해역(서해병) 표층 퇴적물의 금속원소 분포)

  • Koh, Hyuk-Joon;Choi, Young-Chan;Park, Sung-Eun;Cha, Hyung-Kee;Chang, Dae-Soo;Lee, Chung-Il;Yoon, Han-Sam
    • Journal of Environmental Science International
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    • v.22 no.7
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    • pp.787-799
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    • 2013
  • The aim of this study was to investigate the accumulation of metallic elements and the control effect of marine pollution caused by ocean dumping in the sediments at a waste disposal area in the Yellow Sea. In July 2009, concentrations of organic matter and metallic elements (Al, Fe, As, Cd, Cr, Co, Hg, Ni, Mn, Pb, and Zn) were measured in surface sediments at the site. The ignition loss (IL) in the surface sediments showed a mean value of 15.4%, about 1.5 times higher than the mean value of the sediments in the coastal areas of Korea. The chemical oxygen demand (COD) at some disposal sites exceeded 20 mg $O_2/g{\cdot}dry$, which signifies the initial concentration of marine sediment pollutants in Japan. The disposal sites contain higher concentrations of Cr, Cu and Zn than the sediments of bays and estuaries that might be contaminated. The magnitude of both metal enrichment factors (EF) and adverse biological effects suggest that pollution with Cr and Ni occurred due to the dumping of waste in the study area. In addition, the geoaccumulation index (Igeo) showed that the surface sediments were moderately contaminated. By the mid-2000s, when the amount of waste dumped at this site was the highest, the concentration of metallic elements was higher than ever recorded. On the other hand, in 2008-09, the need for environmental management was relatively low compare with the peak. As a result, the quality of marine sediment has been enhanced, considering the effect of waste reduction and natural dilution in the disposal area.

Assessing Water Quality of Siheung Stream in Shihwa Industrial Complex Using Both Principal Component Analysis and Multi-Dimensional Scaling Analysis of Korean Water Quality Index and Microbial Community Data (Principal Component Analysis와 Multi-Dimensional Scaling 분석을 이용한 시화공단 시흥천의 수질지표 및 미생물 군집 분포 연구)

  • Seo, Kyeong-Jin;Kim, Ju-Mi;Kim, Min-Jung;Kim, Seong-Keun;Lee, Ji-Eun;Kim, In-Young;Zoh, Kyung-Duk;Ko, Gwang-Pyo
    • Journal of Environmental Health Sciences
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    • v.35 no.6
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    • pp.517-525
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    • 2009
  • The water quality of Lake Shihwa had been rapidly deteriorating since 1994 due to wastewater input from the watersheds, limited water circulation and the lack of a wastewater treatment policy. In 2000, the government decided to open the tidal embankment and make a comprehensive management plan to improve the water quality, especially inflowing stream water around Shihwa and Banwol industrial complex. However, the water quality and microbial community have not as yet been fully evaluated. The purpose of this study is to investigate the influent water quality around the industrial area based on chemical and biological analysis, and collected surface water sample from the Siheung Stream, up-stream to down-stream through the industrial complex, Samples were collected in July 2009. The results show that the downstream site near the industrial complex had higher concentrations of heavy metals (Cu, Mn, Fe, Mg, and Zn) and organic matter than upstream sites. A combination of DGGE (Denaturing Gradient Gel Electrophoresis) gels, lists of K-WQI (Korean Water Quality Index), cluster analysis, MDS (Multi-Dimensional Scaling) and PCA (Principal Component Analysis) has demonstrated clear clustering between Siheung stream 3 and 4 and with a high similarity and detected metal reducing bacteria (Shewanella spp.) and biodegrading bacteria (Acinetobacter spp.). These results suggest that use of both chemical and microbiological marker would be useful to fully evaluate the water quality.

A Study on the Distribution of Heavy Metal Elements in Arc Welding Fume (아크용접 Fume의 중금속 분포에 관한 연구)

  • 채현병;김정한
    • Proceedings of the Safety Management and Science Conference
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    • 1999.11a
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    • pp.343-343
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    • 1999
  • 아크용접은 산업전반에 걸쳐 그 생산기반에 없어서는 안될 필수기술로써 자동차 및 조선, 항공우주산업에 이르기까지 경제기반에 미치는 파급효과가 매우 크다. 그러나 이 아크용접을 하게 되면 각종 가스와 미세입자로 이루어진 흄이 발생하게 되는데 이들은 작업자들의 건강에 많은 영향을 미치는 것으로 보고되어 있다. 용접흄에는 용접재료 및 용접공정에 따라 다양한 유해원소가 포함되어 있고 그 종류에 따라 인체에 미치는 잠재적 독성효과도 매우 광범위하다. 최근 국내에서는 용접사들 중에 용접흄에 포함된 중금속 중 Mn중독에 의한 파킨스씨병 환자들과 Cr중독에 의하여 콧속 연골에 구멍이 뚫리는 비중격천공(鼻中隔穿孔) 환자들이 직업병으로 판정 받아 산재요양이 승인된 사례가 있다. 이러한 계기로 인하여 용접사들의 용접기피 현상이 심화되고 작업환경에 대한 법적규제는 선진 외국뿐만 아니라 국내에서도 한층 엄격하게 강화되고 있는 실정이다. 따라서 이제는 작업자와 사용자 모두 용접흄에 대한 인식의 전환이 요구되는 때이며 여러 분야에서 이러한 용접흄에 대한 연구가 활발히 진행되어야 한다. 해외에서는 이미 용접흄에 대한 연구가 활발히 진행되어 왔으나 국내의 경우는 매우 미비한 상태이며 용접산업의 미래 영향력이나 필요성을 고려할 때 국내에서도 적극적인 관심을 가져야 할 부분으로 판단된다. 본 연구에서는 아크용접공정에서 발생하는 흄의 특정 중금속 성분이 인체에 치명적인 악영향을 미치는 것에 착안하여 여러 종류의 용접재료에서 발생되는 용접흄의 중금속 분포를 조사하여 비교하였다. 이것은 향후 용접재료별 및 용접공정별 발생되는 흄의 유해원소를 저감시킬 수 있고 또한 각종 유해원소의 노출기준 및 평가기준을 마련할 수 있는 기초data로써 도움이 되리라 사료된다.동, 공정중재고가 줄어드는 결과를 보였고, 가동률 수준이 높을수록 ORR 방법간의 차이가 크게 나타났다. 그리고 부하평준화 기능은 Order Release 정책의 유효성에 별 영향을 주지 않는 것으로 나타났다. 결론적으로, Order Release 방법은 우선순위규칙간의 성능차이를 줄이거나, 대체할 수 통제 기법이라기보다는 우선순위규칙을 보완하여 공정중재고와 작업현장에서의 리드타임, 리드타임의 편차를 줄여주는 역할을 한다고 볼 수 있다. 그리고, 계획시스템이 존재하여 계획오더가 일정기간간격으로 이송되는 환경에서 특히 유용하다는 결론을 얻었다. 알 수 있었다. 것인데, 제조업에서의 심각한 고비용, 저효율 문제 를 해결하기 위해 필수적으로 도입해야만 하는 실정이다. 또한 소비자의 다양한 요구로 인 하여 제품의 종류와 사양면에서 심한 변동을 보이는 시장 수요에, 신속한 정보처리로 대응 하는데도 크게 기여하고 있다. 이에 본 연구에서는, 자동차 Job Shop의 동기화 생산방식을 지원하는 동기화 생산시스템의 구축 모델을 제시하고자 한다.과로 여겨지며, 또한 혈청중의 ALT, ALP 및 LDH활성을 유의성있게 감소시키므로서 감잎 phenolic compounds가 에탄올에 의한 간세포 손상에 대한 해독 및 보호작용이 있는 것으로 사료된다.반적으로 홍삼 제조시 내공의 발생은 제조공정에서 나타나는 경우가 많으며, 내백의 경우는 홍삼으로 가공되면서 발생하는 경우가 있고, 인삼이 성장될 때 부분적인 영양상태의 불충분이나 기후 등에 따른 영향을 받을 수 있기 때문에 앞으로 이에 대한 많은 연구가 이루어져야할 것으로 판단된다.태에도 불구하고 [-wh]의미의 겹의문사는 병렬적 관계의 합성어가 아니라 내부구조를 지니지 않은 단순한 단어(min

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A CLINICAL AND STATISTICAL STUDY OF MAXILLOFACIAL FRACTURE IN THE UIJUNGBU AREA (의정부지역의 악안면 골절에 대한 임상 통계적 연구)

  • Kim, Hyoun-Tae
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.13 no.1
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    • pp.63-68
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    • 1991
  • The author has arrived at the following result after having carried out multilateral study based on a total of 282 maxillofacial fracture patients who have receive treatment at the Euijeongbu general hospital and Shinchun general hospital in the northern district of Kyunggido from march 1988 to august 1990. 1. Sex distribution of Mx. facial fx. patient was higher in male by 4.6:1 and was predominant in the 3rd decade with 40.4% followed in decreasing order by the 2nd decade and the 4th. 2. A majority were in the Mn. with 40.2% followed in decreasing order by zygoma. nasal bone and maxilla. 3. For the sex distribution according to anatomy, make to female ratio was 6.2:1 in the mandible, followed in decreasing order by zygoma, and nasal bone with predominance in male. 4. Car accident with 42.8% was the most common cause of fx. followed in decreasing order by violence, workmen's accident, and fall down. 5. The involvement of other trauma areas are head. 79.0%, abdomen-thorax, and the extremities in decreasing order. 6. In the mandibular fx. a majority were in the symphysis with 73.9% followed in decreasing order by angle, Condyle, and body. 7. Maxillary fx. of the type LeFort II was estimated to be 41.2% 8. Fracture in the zygoma including zygomatic arch was estimated to be 72.5%

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Chemical Components and Physiological Activities of Bamboo (Phyllostachys bambusoides Starf) Extracts Prepared with Different Methods (추출방법에 따른 대나무(왕대) 추출물의 화학성분 및 생리활성)

  • Ju, In-Ok;Jung, Gi-Tai;Ryu, Jeong;Choi, Joung-Sik;Choi, Yeong-Geun
    • Korean Journal of Food Science and Technology
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    • v.37 no.4
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    • pp.542-548
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    • 2005
  • Chemical components and physiological activities Bamboo (Phyllostachys bambusoides Starf) extracts obtained by burning, dry heating or extracting with water or 70% ethanol and were investigated. Contents of soluble solid and total phenolic compounds were highest in the ethanol extract. Contents of polyphenols such as catechin, chlorogenic acid, caffeic acid, 3-hydroxy benzoic acid and ferulic acid were determined. Free sugars consisted of galactose, glucose, fructose, and sucrose. Organic acids including citric, tartaric, malic, succinic, and acetic acid were present in the bamboo extracts. Antioxidant activities of dry heat and ethanol extracts were higher than those of BHA or ${\delta}-tocopherol$. Nitrite- scavenging effect of extracts ranged from 84.7 to 99.6% at pH 1.2 ana 3.0. Tyrosinase-inhibitory activity was higher in the water extract, and SOD-like and ACE-inhibitory activity were highest in tile dry kent extract. Antimicrobial activities of the bamboo extracts were strong against Bacillus subtilis, Escherichia coli O157, and Staphylococcus aureus.

Heavy Metal Contamination Characteristics and Spectral Characteristics of White Precipitation occurring at Miin Falls Drainage (미인폭포 수계에서 발생하는 백색침전물의 중금속 오염 및 분광학적 특성)

  • Lim, Jeong Hwa;Yu, Jaehyung;Shin, Ji Hye;Jeong, Yong Sik;Koh, Sang-Mo;Park, Gyesoon
    • Journal of the Mineralogical Society of Korea
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    • v.30 no.1
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    • pp.31-43
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    • 2017
  • This study investigated mineralogy, spectral characteristics and heavy metal contamination including Cd, Ni, Al, Fe, Mn and S for white precipitation in Miin falls based on XRF, XRD, and spectrometer. As a result, Al concentration was abnormally high at all samples, and most of the samples showed high contamination level in Cd and Ni. XRD results detected quartz, kaolinite, rhomboclase, aluminocoquimbite, and gibbsite which infers that heavy metal elements are distributed by adsorption with clay minerals. Spectral characteristics of white precipitation can be described by increasing pattern of reflectance in visible spectrum and decreasing pattern of reflectance in longer wave length including near infrared and shortwave infrared spectrum. The absorption features reveals that spectral characteristics of white precipitation is mainly controlled by kaolinite, rhomboclase, aluminocoquimbite, and gibbsite. The relationship between heavy metal concentration and absorption depth showed high positive correlation for Al concentration and absorption feature at 2202 nm of Al-OH absorption. This spectral characteristics indicates that absorption depth could be effectively used for estimation of heavy metal concentration.