• Title/Summary/Keyword: MnAl

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Chemical pretreatment for anaerobic treatment of abandoned mine drainage (폐광산폐수의 혐기성 처리를 위한 화학적 전처리)

  • 김은호;김형석
    • Journal of environmental and Sanitary engineering
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    • v.14 no.3
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    • pp.99-106
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    • 1999
  • This research was carried out to investigate chemical pretreatment using lime and limestone in treating abandoned mine drainage with anaerobic treatment. If treating lime with abandoned mine drainage, after 2day, pH was increased to 5.6, and $SO_4^{2-}$, Fe, Al, Pb and Mn were removed 5.7%, 63%, 57, 45% and 28%, respectively. It was estimated that lime dosage was 2,000mg/L for increasing to pH 7. If treating limestone with abandoned mine drainage, after 2day, pH was increased to 3.67, and $SO_4^{2-}$, Fe, Al, Pb and Mn were removed 4.7%, 26%, 22% 18% and 8%, respectively. It could be showed that limestone did slowly react with temperature increasing. If treating anaerobic limestone packing column with abandoned mine drainage, for experimental period, average pH was 4.51, and average $SO_4^{2-}$, Fe, Al, Pb and Mn were removed 4.5%, 15.3%, 20.1%, 23.7% and 5.87%, respectively. So, it would not be suitable for abandoned mine drainage. But if utilizing limestone as pretreatment process for treating abandoned mine drainage with SRB, because it did initally neutralize abandoned mine drainage, it could forward to stabilize system.

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Effect of Grain Size on the Damping Capacity of Fe-26Mn-4Co-2Al Damping Alloy (Fe-26Mn-4Co-2Al 제진합금의 감쇠능에 미치는 결정립 크기의 영향)

  • Jeong, Kyu-Seong;Kim, Doe-Hoon;Kwon, Soon-Doo;Kang, Chang-Yong
    • Korean Journal of Materials Research
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    • v.28 no.3
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    • pp.129-134
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    • 2018
  • This study was carried out to investigate the effect of grain size on the damping capacity of the Fe-26Mn-4Co-2Al damping alloy. ${\alpha}^{\prime}$ and ${\varepsilon}-martensite$ were formed by cold working, and these martensites were formed with a specific direction and surface relief. With an increase in grain size, the volume fraction of ${\alpha}^{\prime}$ and ${\varepsilon}-martensite$ increased by decrement the austenite phase stability. This volume fraction more rapidly increased in cold-rolled specimen than in the specimen that was not cold-rolled. The damping capacity also increased more with the augmentation an increased grain size and more rapidly increased in cold-rolled specimen than in the specimen that was not cold rolled. The effect of grain size on the damping capacity was larger in the cold-rolled specimen than the specimen that was not cold-rolled. Damping capacity linearly increased with an increase in volume fraction of ${\varepsilon}-martensite$. Thus, the damping capacity was affected by the ${\varepsilon}-martensite$.

Heat transfer enhancement of metal hydride $(Mm(La_{0.6-0.8})Ni_{4.0}Co_{0.6}Mn_{0.2}Al_{0.2})$ for hydrogen storage (수소저장용 금속수소화물$(Mm(La_{0.6-0.8})Ni_{4.0}Co_{0.6}Mn_{0.2}Al_{0.2})$의 전열촉진)

  • Bae Sang-Chul;Yang Yang;Masanori Monde
    • New & Renewable Energy
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    • v.2 no.2 s.6
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    • pp.75-80
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    • 2006
  • The effective thermal conductivities of $Mm(La_{0.6-0.8})Ni_{4.0}Co_{0.6}Mn_{0.2}Al_{0.2}$ [TL-492] with hydrogen and helium have been examined. Experiment results show that pressure has great influence on effective thermal conductivity in low pressure range [below 0.5 MPa]. And that influence decreases rapidly with increase of gas pressure. The reason is at low pressure, the mean free path of gas becomes greater than effective thickness of gas film which is important to the heat transfer mechanism in this research. And, carbon fibers have been used to try to enhance the poor thermal conductivity of TL-492. Three types of carbon fibers and three mass fractions have been examined and compared. Naturally, the highest effective thermal conductivity has been reached with carbon fiber which has highest thermal conductivity, and highest mass fraction. This method has acquired 4.33 times higher thermal conductivity than pure metal hydrides with quite low quantity of additives, only 0.99 wt% of carbon fiber. This is a good result comparing to other method which can reach higher effective thermal conductivity but needs much higher mass fraction of additives too.

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Effect of Deformation Induced Martensite on the Damping Capacity of Fe-26Mn-4Co-2Al Alloy (Fe-26Mn-4Co-2Al 합금의 감쇠능에 미치는 가공 유기 마르텐사이트의 영향)

  • Jeong, Kyu-Seong;Kang, Chang-Yong
    • Korean Journal of Materials Research
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    • v.26 no.9
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    • pp.493-497
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    • 2016
  • This study was carried out to investigate the effect of deformation induced martensite on the damping capacity of Fe-26Mn-4Co-2Al damping alloy. ${\alpha}^{\prime}$ and ${\varepsilon}$-martensite were formed by cold working, and; deformation induced martensite was formed with according to the specific direction and the surface relief. With an increasing degree of cold rolling, the volume fraction of ${\alpha}^{\prime}$-martensite increased rapidly, while the volume fraction of ${\varepsilon}$-martensite decreased after rising to a maximum value at a specific level of cold rolling. Damping capacity was increased, and then decreased with an increasing of the degree of cold rolling. Damping capacity was influenced greatly by the volume fraction of ${\varepsilon}$-martensite formed by cold working, but the effect of the volume fraction of ${\alpha}^{\prime}$-martensite have a actually on effect on the damping capacity.

Magnetic Properties of Transition Metal-implanted ZnO Nanotips Grown on Sapphire and Quartz

  • Raley, Jeremy A.;Yeo, Yung-Kee;Hengehold, Robert L.;Ryu, Mee-Yi;Lu, Yicheng;Wu, Pan
    • Journal of Magnetics
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    • v.13 no.1
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    • pp.19-22
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    • 2008
  • ZnO nanotips, grown on c-$Al_2O_3$ and quartz, were implanted variously with 200 keV Fe or Mn ions to a dose level of $5{\times}10^{16}cm^{-2}$. The magnetic properties of these samples were measured using a superconducting quantum interference device (SQUID) magnetometer. Fe-implanted ZnO nanotips grown on c-$Al_2O_3$ showed a coercive field width of 209 Oe and a remanent field of 12% of the saturation magnetization ($2.3{\times}10^{-5}emu$) at 300K for a sample annealed at $700^{\circ}C$ for 20 minutes. The field-cooled and the zero-field-cooled magnetization measurements also showed evidence of ferromagnetism in this sample with an estimated Curie temperature of around 350 K. The Mn-implanted ZnO nanotips grown on c-$Al_2O_3$ showed superparamagnetism resulting from the dominance of a spin-glass phase. The ZnO nanotips grown on quartz and implanted with Fe or Mn showed signs of ferromagnetism, but neither was consistent.

Effect of Cold Working on the Tensile Strength of Fe-26Mn-4Co-2Al Damping Alloy (Fe-26Mn-4Co-2Al 제진합금의 인장강도에 미치는 냉간가공의 영향)

  • Kang, Chang-Yong;Kim, Seong-Hwi;Jeong, Gyu-Seong
    • Journal of Power System Engineering
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    • v.20 no.6
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    • pp.46-50
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    • 2016
  • This study was carried out to investigate the effect of cold working on the tensile strength of Fe-26Mn-4Co-2Al damping alloy. ${\alpha}^{\prime}$ and ${\varepsilon}$-martensite were formed by cold working, and martensite was formed with the specific direction and surface relief. With the increasing degree of cold rolling, volume fraction of ${\alpha}^{\prime}$-martensite was increased, whereas the volume fraction of ${\varepsilon}$-martensite was decreased after rising to maximum value at specific lever of cold rolling. Tensile strength was linearly increased with an increasing of degree of cold rolling. Tensile strength was strongly affected to the volume fraction of ${\varepsilon}$-martensite formed by cold working, but the effect of volume fraction of ${\varepsilon}$-martensite on the tensile strength was not observed.

Effect of pH and Drying Temperature on Luminescent Properties of Zn2SiO4:Mn,Al Green Phosphors by Sol-Gel Technique (졸-겔 합성에서 pH 및 건조온도가 Zn2SiO4:Mn,Al 녹색 형광체의 발광특성에 미치는 영향)

  • Sung, Bu-Yong;Han, Cheong-Hwa;Park, Hee-Dong
    • Journal of the Korean Ceramic Society
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    • v.42 no.5 s.276
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    • pp.333-337
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    • 2005
  • In order to improve the performance of green emitting phosphors for plasma display panel, the $Zn_2SiO_4:Mn,Al$ phosphors were synthesized using sol-gel technique and studied using SEM and VUV photoluminescence spectrometer. pH values of the starting solutions (pH = 0.5$\~$2.34) were controled by HCl as the catalysis of hydrolysis and wet gels were dried at $80^{\circ}C$ and $120^{\circ}C$, respectively. We investigated the effects of pH and drying temperatures during sol-gel processes. The results indicated that the phosphor prepared at pH = 1 showed the maximum emission intensity in both drying conditions and the effect of pH of the starting solution on morphology were increased with particle size as HCl and phosphor dried at high temperature showed more spherical and smaller particles than at low.

Electrode Characteristics of the (Mm)Ni5-Based Hydrogen Storage Alloys ((Mm)Ni5계 수소저장합금의 전극 특성)

  • Han, D.S.;Choi, S.J.;Chang, M.H.;Choi, J.;Park, C.N.
    • Transactions of the Korean hydrogen and new energy society
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    • v.6 no.1
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    • pp.35-41
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    • 1995
  • The MmNi-based alloy electrode was studied for use as a negative electrode in Ni-MH battery. Alloys with $MmNi_5-_xM_x$(M=Co,Al,Mn) composition were synthesized, and their electrode charateristics of activation rate, temperature dependence, electrode capacity and cycle life were investigated. With increasing Al content and decreasing Mn content in the alloys, the discharge capacity increased while the cycle life decreased. As x in $MmNi_5-_xM_x$ increased from 1.5 to 2.0, decreasing the Ni content, the discharge capacity, the low temperature property and the rate capability decreased. However its cycle life was improved. Increasing Co content resulted in a prolonged cycle life and decrease of high rate discharge capacity. It can be concluded that the most promising alloy in view of discharge capacity and cycle life is $MmNi_{3.5}Co_{0.7}Al_{0.5}Mn_{0.3}$.

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An Experimental Study for Mechanical Properties of Al-Mg-Mn-Si Alloy by ECA pressing (ECA기법을 활용한 Al-Mg-Mn-Si 합금의 기계적 성질에 관한 연구)

  • Kook, Jong-Han
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.20 no.6
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    • pp.785-792
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    • 2011
  • Equal channel angular(ECA) pressing is the established processing technique in which a polycrystalline metal is pressed through the die to achieve a very high plastic strain. Therefore, the capability to produce an ultra-fine grain size in the materials is provided. To investigate that mechanical properties at elevated temperature have the ultrafine grain ECA pressing, experiments were conducted on an Al-4.8% Mg-0.07% Mn-O.06% Si alloy. After having been solution treated at 773K for 2hrs, the billet for ECA pressing was inserted into the die. And it was pressed through two channel of equal to cross section intersecting at a 90 degree angle. The billet can be extrude repeatedly because of 1:1 extrusion ratio. Since the billet is passed through the cannel for 2 times, a large strain is accumulated in the alloy. The tensile tests on elevated temperature were carried out with initial strain rate of $10^{-3}s^{-1}$ at eight temperature distributed from 293K to 673K.

The Microstructural Evolution of Mg-10Al-Mn Alloy by Cooling Plate During Homogenization Treatment (냉각판법에 의한 Mg-10Al-Mn 합금의 균질화 처리에 따른 미세조직 변화)

  • Kim, Dae-Hwan;Choi, Seung-Hwa;Kim, Hee-Kyung;Shim, Sung-Young;Lim, Su-Gun
    • Journal of Korea Foundry Society
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    • v.30 no.6
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    • pp.235-240
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    • 2010
  • The evolution of microstructure and phases of Mg-10Al-Mn alloy by cooling plate method during homogenization treatment have been investigated with metallographic analysis, scanning electron microscopy and energy dispersive spectroscopy. The ingots used for this experiment were prepared by cooling plate and homogenization heat treatment was performed at 300 and $400^{\circ}C$ for various holding times (0, 1, 4, 8 and 12h). The casting ingots were consisted of the fine grains and eutectic phases. And, these eutectic phases were dissolved into the matrix during homogenization treatment at $400^{\circ}C$ but the lower temperature (at $300^{\circ}C$) did not be.