• The Transactions of the Korean Institute of Electrical Engineers C
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• v.53 no.9
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• pp.455-458
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• 2004

In this paper, we investigated impurities content and physical properties showing by changing the content of carbon black that is semiconductive materials for underground power transmission. Specimens were made of sheet form with the three of existing resins and the nine of specimens for measurement. Impurities content of specimens was measured by ICP-AES (Inductively Coupled Plasma Atomic Emission Spectrometer), and density of specimens were measured by density meter And then specific heat (Cp) was measured by DSC (Differential Scanning Calorimetry). A ranges of measurement temperature were from $0^{\circ}[C]$ to $200^{\circ}[C]$, and heating temperature was $4^{\circ}[C/min]$. Impurities content was highly measured according to increasing the content of carbon black from this experimental result, also density was increased according to these properties. Especially impurities content values of the Al and A2 of existing resins were measured more than 4000［ppm］. Specific heat from the DSC results was decreased according to increasing the content of carbon black. Because ionic impurities of carbon black having Fe, Co, Mn, Al and Zn are rapidly passed kinetic energy increasing the number of times breaking during the unit time with the near particles according to increasing vibration of particles by the applied heat energy.

• Journal of the Korean Society for Heat Treatment
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• v.17 no.5
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• pp.299-304
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• 2004

Influence of Ca addition on microstructure and room temperature mechanical properties has been studied for AZ31(Mg-3%Al-1%Zn-0.2%Mn)-(0~0.5)%Ca wrought alloys, based on experimental results from metallography, X-ray diffractometry and mechanical tests. Yield strength, ultimate tensile strength and hardness of the alloys increased remarkably with increasing Ca content, whereas elongation was deteriorated continuously. Microstructural examination revealed that Ca addition efficiently refined grains of ${\alpha}$(Mg) phase and that some of the Ca dissolved in ${\beta}(Mg_{17}Al_{12})$ precipitates. The former and the latter facts are thought to be responsible for improved strength and loss of ductility of the AZ31+Ca wrought alloys, respectively.

• Journal of Welding and Joining
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• v.26 no.6
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• pp.54-58
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• 2008

Laser welding with AZ61 filler wire was carried out to improve formability though reduction of porosity and formation of under fill bead. Optimum welding condition and mechanical properties of butt joint for $400{\times}500{\times}1.3mm$ magnesium sheets were studied. Optimal welding conditions of laser power, welding speed, and defocusing length are 1000W, 3m/min, and 2mm, respectively. Results of tensile test indicated that both tensile strength and elongation of specimens welded with filler wire were improved at room temperature because of reduction of porosity and under-filled bead formation in addition to the precipitation hardening and microstructure refinement by Al-Mn and Mg-Al-Zn precipitates. At elevated temperature of $200{\sim}350^{\circ}C$, fracture location of tensile specimen was shifted from weld metal to base metal, indicating less softening of weld metal than base metal.

• 한국신재생에너지학회:학술대회논문집
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• 2008.10a
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• pp.200-202
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• 2008

동해 울릉분지에서는 시추선 RemEtive를 사용하여 UBGH-X-01 가스하이드레이트 탐사가 2007년에 실시되었다. 본 연구에서는 천부 가스하이드레이트가 확인된 UBGH1-10 정점에서 무인잠수정(Quantam WROV)을 사용하여 획득된 푸쉬코어와 해저지형 분석을 수행되었다.UBGH1-10 정점은 seismic chimneys의 탄성파 특성이 발달된 지역이다. 이곳에서는 해저표면으로부터 수 m 하부에서 가스하이드레이트가 발견되었다. 이 정점은 수 m 높이의 얕은 둔덕들이 무인잠수정에 부착된 비디오 카메라에 의해서 관찰되었다.이곳에서 채취된 길이 약40 cm의 푸쉬코어는 생물교란된 뻘질 퇴적물로 구성되어 있으며, 가스하이드레이트와 chemosynthetic community는 관찰되지 않았다. 푸쉬코어는 X-ray fluorescence scanner를 사용하여 퇴적물의 26가지 원소 조성을 분석하였다. UBGH1-10 정점의 산화환원환경은 Mo/Al과 Mn/Ti 원소비를 이용하여 천부 가스하이드레이트가 발견되지 않은 UBGH1-9와 UBGH1-1 정점과 대비하였다. 이 정점의 일차생산력은 Ba/Al 원소비를 이용하여 다른 정점과 대비하였다. 천부 가스하이드레이트가 발견된 UBGH1-10 정점은 활발한 가스방출과 관련된 생물집단 서식 또는 자생광물 형성의 흔적이 발견되지 않으며, 퇴적물에서도 산화환원환경과 일차생산력의 큰 차이가 관찰되지 않는다.

• Corrosion Science and Technology
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• v.9 no.4
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• pp.164-170
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• 2010

Thermodynamic consideration was performed for Alloy 617 exposed to an impure helium ($H_2$ 20pa, $H_2O$ 0.5pa, $CH_4$ 2pa and CO 5pa) at $950^{\circ}C$. Oxidation power was decreased in the order Al > Ti > Si > Cr > Mn. Decarburization and carburization reactions were available leading to carbon activity decrease and increase, respectively, depending on carbon and Cr activities. The thermodynamic prediction was compared with the experimental results obtained in similar conditions (($H_2$ 20pa, $H_2O$ 0.05pa, $CH_4$ 5pa and CO 2pa) and $950^{\circ}C$) by others for Alloy 617. The driving force for oxidation of Al, Ti and Si is very large to be oxidized at a given impure helium and the environment is actually carburizing towards the structural alloy, which is consistent with this work.

• Journal of Korea Foundry Society
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• v.35 no.1
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• pp.8-14
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• 2015

Variations of nickel contents and microstructures in molten magnesium alloys on the addition of aluminum, zirconium, and manganese have been investigated. Specimens were prepared by melting under $SF_6$ and $CO_2$ atmosphere and casting into a disc of 29 mm diameter with 7~10 mm thickness from the melt acquired at the top of crucible. Before casting, the molten metal was stirred for 3 minutes after each addition of alloying elements and maintained for 30 minutes for settling down. Results showed that zirconium did not significantly affect the content of nickel while aluminum remarkably reduced it by forming $Al_3Ni_2$ phase. When manganese are added to Mg-1wt%Ni alloy along with aluminum, both elements remarkably reduced the content of nickel. The addition of 1.5 wt% manganese to Mg-1wt%Ni alloy containing aluminum further reduced the content of nickel by more than 30%, during which an additional intermetallic phase $Al_{10}Mn_3Ni$ was precipitated in the molten magnesium.

• Journal of the Korean Ceramic Society
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• v.28 no.3
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• pp.189-196
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• 1991

Si(OC2H5)4, commercial AlN and Y2O3 powder were used as the precusor of Si3N4, AlN, Y2O3, respectively. After Si3N4 powder was synthesized by carbothermal reduction and nitridation at 135$0^{\circ}C$ for 13h in N2 atmosphere, characteristics of synthesized powder and the ceramics sintered at 178$0^{\circ}C$ for 1h under 30MPa were investigated. In order to evaluate the reliability of sintered body, Weibull modulus was investigated. Premixing of carbon black as a reduction agent had no effect on Si(OH)4 formation, and Si3N4 powder synthesized from Si(OC2H5)4 was $\alpha$-Si3N4 single phase. Mechanical properties of sintered body were measured as follows : flexural strength ; 750MPa, fracture toughness ; 3.71Mn/3/2, hardness : 17.4GPa, thermal shock resistence temperature ; $600^{\circ}C$. Flexural strength at room temperature was 750MPa and was retained up to 110$0^{\circ}C$. The Weibull modulus of sintered body was 10.7.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.3 no.1
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• pp.31-36
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• 1993

Na-Fe Tourmalene ($NaFe_3Al_6B_3Si_6O_{27}F_4$)single crystals were grown by FZ method. The Growth conditions are counter rotation 20~30rpm, growth rate 1~5mm/hr in the atmospheric environment. The transition elements as Fe(in this research), Mn, Co, etc, are exist in the theoretical fomulae so that dopants were not added. The feed rod was sintered between $1000^{\circ}C$ and $1l00^{\circ}C$, but at higher temperature, it was difficult to manufacture the feed rod because of evaporation of the elements such as F. As grown crystals had a black color and the length of 50~60mm, the diameter of 5~6mm. X-ray powder diffraction pattern indicated that the composition of the feed rod was right to the Tourmaline composition. By FT-IR spectra, the state of bonding of each element was charaterized.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.24 no.3
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• pp.200-207
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• 2011

Abstract: The effect of lead free glass frit compositions on the properties of thick film conductor and resistor pastes were investigated. Two types lead free frits, HBF-A(without $Bi_2O_3$) and HBF-B(with $Bi_2O_3$) were made from $SiO_2$, $B_2O_3$, $Al_2O_3$, CaO, MgO, $Na_2O$, $K_2O$, ZnO, MnO, $ZrO_2$, $Bi_2O_3$. And Ag based conductor pastes and $RuO_2$ based resistor paste were prepared by mixed with these frits and functional phase(Ag and $RuO_2$), and organic vehicle. The properties of thick film conductor and resistor sintered at $850^{\circ}C$ were studied after printing on $Al_2O_3$ substrate. The morphology of the sintered films surface were SEM and EDS were carried out to analysis the chemical composition on resistor surface and state of Ru atom in frit matrix.

• Journal of Powder Materials
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• v.26 no.4
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• pp.319-326
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• 2019

Additive manufacturing (AM) is a highly innovative method for joining dissimilar materials for industrial applications. In the present work, AM of STS630 and Ti-6Al-4V powder alloys on medium entropy alloys (MEAs) NiCrCo and NiCrCoMn is studied. The STS630 and Ti64 powders are deposited on the MEAs. Joint delamination and cracks are observed after the deposition of Ti64 on the MEAs, whereas the deposition of STS630 on the MEAs is successful, without any cracks and joint delamination. The microstructure around the fusion zone interface is characterized by scanning electron microscopy and X-ray diffraction. Intermetallic compounds are formed at the interfacial regions of MEA-Ti64 samples. In addition, Vicker's hardness value increased dramatically at the joint interface between MEAs and Ti-6Al-4V compared to that between MEAs and STS630. This result is attributed to the brittle nature of the joint, which can lead to a decrease in the joint strength.