• Title/Summary/Keyword: Mn-Al

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Mixing effect on Properties of NTC Thermistor in Mn-Co-0 System (Mn-Co-0계 NTC 써 미스터의 물성에 미치는 혼합의 영향)

  • 윤상식;김경식;윤상옥
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.459-462
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    • 2001
  • Interface effects on properties of NTC thermistors having Mn-Co-O spinel crystal structure system are analyzed by a mixing rule in case of mixed types and layered types between CuO and Al$_2$O$_3$ added compounds. With adding CuO and Al$_2$O$_3$, The compounds form completely solid solution and their resistance and B constant are changed due to the variation of conduction electrons by their ionic substitutions. The properties of mixed NTC thermistors are depended on the logarithmic mixing rule by a dispersed phase and they show slightly lower values due to the lattice mixing affect in compared with calculated values. The resistance of layered NTC thermistors is depended upon the series mixing rule containing the value of an interface layer and effected by the variation of its thickness, and it is changed rapidly to the logarithmic mixing rule by the connection between two layers with increasing the interface layer

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PRESSURE DEPENDENCE OF THE CURIE TEMPERATURE IN MnAlGe

  • Endo, S.;Matsuzaki, H.;Ono, F.;Kanomata, T.;Kaneko, T.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.380-382
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    • 1995
  • The pressure dependence of the Curie temperature was determined in 2-dimensional like ferromagnet, MnAlGe up to a maximum pressure of 7.5 Gpa through measurements of electric resistance vs temperature curves. The pressure coefficient was positive with a considerably high rate of 9 K/GPa in the low pressure ragion, while it decreased gradually down to one order of magnitude smaller value at the maximum pressure. It was concluded that ther is an upper limit of about 550 K in the super-exchange type ferromagnetic interaction between Mn layers.

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The Relationship between Microstructure and Property of Rapidly Solidified Al-Mg-X(X=Cr, Zr or Mn) Asloys (급속응고 Al-Mg-X(X=Cr, Zr or Mn) 합금의 미세구조와 특성간의 관계)

  • 맹덕영
    • Journal of Powder Materials
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    • v.3 no.4
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    • pp.271-278
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    • 1996
  • In this study, the effect of the transition elements on the microstructure and mechanical properties of rapidly solidified Al-Mg-X alloys was investigated. As a result of the rapid solidification processing, fine equiaxed grains with a mean diameter of 2 $\mu$m were observed in these alloys. Many fine particles were found to be distributed rather homogeneously throughout the matrix with relatively large particles occasionally at grain boundaries. The ultimate tensile strengths of Al-Mg-X alloys were found to decrease rather remarkably at 150 $^{\circ}C$ without the gain of the ductility at 150 $^{\circ}C$, which may result from segregation of $\beta$ ($Al_{3}Mg_{2}$) precipitates. Fine dimples were observed on the fracture surfaces for all alloy systems and the variation of the size and shape of dimples was not observed upon alloy systems. The ductility at 530 $^{\circ}C$ was found to be ~100%, suggesting that grain boundary sliding did not contribute to ductiliy despite he grain size stabilization. The absence of superplastic behavior may be associated with low boundary misorientation in rapidly solidified Al-Mg-X alloys.

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Gahnite-Sillimanite-Garnet Mineral Assemblage from the Host Rocks of the Cannington Deposit, North Queensland, Australia: Relationship between Metamorphism and Zn-Mineralization (호주 퀸즈랜드 주 캔닝턴 광상 모암의 아연-첨정석-규선석-석류석에 관한 연구 :변성작용과 아연-광화작용에 대해서)

  • Kim Hyeong Soo
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.4
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    • pp.309-325
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    • 2004
  • The Cannington Ag-Pb-Zn deposit, northwest Queensland, Australia developed around the host rocks composing banded and migmatitic gneisses, sillimanite-garnet schist and amphibolite. Three crystal habits of sillimanite, gahnite (Zn-spinel) and garnet porphyroblasts occurred on the host rocks of the Cannington deposit could be used to delineate metamorphism that closely associated with Zn-mineralization in the deposit. Linkages the metamorphism to Zinc-mineralization is determined in four chemical systems, KFMASH (K$_2$O-FeO-MgO-Al$_2$O$_3$-SiO$_2$-$H_2O$), KFMASHTO (K$_2$O-FeO-MgO-Al$_2$O$_3$-SiO$_2$-$H_2O$-TiO$_2$-Fe$_2$O$_3$), NCKFMASH (Na$_2$O-CaO-K$_2$O-FeO-MgO-AlO$_3$-SiO$_2$-$H_2O$) and MnNCK-FMASH (MnO-Na$_2$O-CaO-K$_2$O-FeO-MgO-AlO$_3$-SiO$_2$-$H_2O$), using THERMOCALC program (version 3.1; Powell and Holland 1988). Partial melting in MnNCKFMASH and NCKFMASH systems occurs at lower temperature than in the KFMASH and KFMASHTO systems. The partial melting temperature decreases with increasing of Na/(Na+Ca+K) of the bulk rock compositions in the MnNCKFMASH system. The host rocks have melted ca 15 vol.% in the MnNCKFMASH system at peak metamorphic conditions (634$\pm$62$^{\circ}C$ and 4.8$\pm$1.3 kbar), but partial melting have not occurred in KFMASHTO system. Based on calculations of sillimanite isograd in different systems and sillimanite modal pro-portion, prismatic and rhombic sillimanite and gahnite porphyroblasts including prismatic sillimanite inclusion probably have resulted from pressure and temperature increasing through partial melting (from 550~$600^{\circ}C$, 2.0~3.0 kbar to 700~75$0^{\circ}C$, 5.0~7.0 kbar), furthermore have experienced N-S then W-E crustal shortening during D$_1$ and D$_2$ deformation. Consequently, Zinc mineralization related to gahnite growth occurred during D$_2$ and was redistributed and upgraded by partial melting and retrograde metamorphism into structural and rheological sites during shearing in D$_3$.

Optimization of Chemical Coagulation for Wastewater Treatment in a Confectionery Factory (제과공장 폐수의 화학적 응집공정 최적화)

  • Keum, Seung-Hae;Chang, Kyu-Sub;Song, Kyung-Bin;An, Gil-Hwan
    • Korean Journal of Food Science and Technology
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    • v.27 no.3
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    • pp.318-323
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    • 1995
  • To improve wastewater treatment in a confectionery factory and to optimize chemical coagulation process, this study was performed. $COD_{Mn}$ and total solid of untreated wastewater were $200{\sim}820ppm\;and\;860{\sim}1350ppm$, respectively. Composition of total solid was sugar 40%, protein 10%, hexane-soluble 20%, and ash 30%. Turbidity at 650 nm and the amount of suspended solid (SS) showed correlation, thus turbidity could be used for the on-line measurement of SS. The most effective combination of coagulants for the removal of $COD_{Mn}$ and SS was that of $Al_2(SO_4)_3\;and\;Ca(OH)_2$. The optimal concentration of $Al_2(SO_4)_3\;and\;Ca(OH)_2$ was 480 ppm and 200 ppm, respectively. Optimal retention time of wastewater for $Al_2(SO_4)_3$ addition $Ca(OH)_2$ addition : flocculation was 2 : 2 : 10 min. Multiple treatment of $Al_2(SO_4)_3:Ca(OH)_2$ overcame coagulation inhibition by gelatin and detergent, and addition of microbial sludge reduced it.

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Chemical pretreatment for anaerobic treatment of abandoned mine drainage (폐광산폐수의 혐기성 처리를 위한 화학적 전처리)

  • 김은호;김형석
    • Journal of environmental and Sanitary engineering
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    • v.14 no.3
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    • pp.99-106
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    • 1999
  • This research was carried out to investigate chemical pretreatment using lime and limestone in treating abandoned mine drainage with anaerobic treatment. If treating lime with abandoned mine drainage, after 2day, pH was increased to 5.6, and $SO_4^{2-}$, Fe, Al, Pb and Mn were removed 5.7%, 63%, 57, 45% and 28%, respectively. It was estimated that lime dosage was 2,000mg/L for increasing to pH 7. If treating limestone with abandoned mine drainage, after 2day, pH was increased to 3.67, and $SO_4^{2-}$, Fe, Al, Pb and Mn were removed 4.7%, 26%, 22% 18% and 8%, respectively. It could be showed that limestone did slowly react with temperature increasing. If treating anaerobic limestone packing column with abandoned mine drainage, for experimental period, average pH was 4.51, and average $SO_4^{2-}$, Fe, Al, Pb and Mn were removed 4.5%, 15.3%, 20.1%, 23.7% and 5.87%, respectively. So, it would not be suitable for abandoned mine drainage. But if utilizing limestone as pretreatment process for treating abandoned mine drainage with SRB, because it did initally neutralize abandoned mine drainage, it could forward to stabilize system.

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Effect of Grain Size on the Damping Capacity of Fe-26Mn-4Co-2Al Damping Alloy (Fe-26Mn-4Co-2Al 제진합금의 감쇠능에 미치는 결정립 크기의 영향)

  • Jeong, Kyu-Seong;Kim, Doe-Hoon;Kwon, Soon-Doo;Kang, Chang-Yong
    • Korean Journal of Materials Research
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    • v.28 no.3
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    • pp.129-134
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    • 2018
  • This study was carried out to investigate the effect of grain size on the damping capacity of the Fe-26Mn-4Co-2Al damping alloy. ${\alpha}^{\prime}$ and ${\varepsilon}-martensite$ were formed by cold working, and these martensites were formed with a specific direction and surface relief. With an increase in grain size, the volume fraction of ${\alpha}^{\prime}$ and ${\varepsilon}-martensite$ increased by decrement the austenite phase stability. This volume fraction more rapidly increased in cold-rolled specimen than in the specimen that was not cold-rolled. The damping capacity also increased more with the augmentation an increased grain size and more rapidly increased in cold-rolled specimen than in the specimen that was not cold rolled. The effect of grain size on the damping capacity was larger in the cold-rolled specimen than the specimen that was not cold-rolled. Damping capacity linearly increased with an increase in volume fraction of ${\varepsilon}-martensite$. Thus, the damping capacity was affected by the ${\varepsilon}-martensite$.

Heat transfer enhancement of metal hydride $(Mm(La_{0.6-0.8})Ni_{4.0}Co_{0.6}Mn_{0.2}Al_{0.2})$ for hydrogen storage (수소저장용 금속수소화물$(Mm(La_{0.6-0.8})Ni_{4.0}Co_{0.6}Mn_{0.2}Al_{0.2})$의 전열촉진)

  • Bae Sang-Chul;Yang Yang;Masanori Monde
    • New & Renewable Energy
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    • v.2 no.2 s.6
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    • pp.75-80
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    • 2006
  • The effective thermal conductivities of $Mm(La_{0.6-0.8})Ni_{4.0}Co_{0.6}Mn_{0.2}Al_{0.2}$ [TL-492] with hydrogen and helium have been examined. Experiment results show that pressure has great influence on effective thermal conductivity in low pressure range [below 0.5 MPa]. And that influence decreases rapidly with increase of gas pressure. The reason is at low pressure, the mean free path of gas becomes greater than effective thickness of gas film which is important to the heat transfer mechanism in this research. And, carbon fibers have been used to try to enhance the poor thermal conductivity of TL-492. Three types of carbon fibers and three mass fractions have been examined and compared. Naturally, the highest effective thermal conductivity has been reached with carbon fiber which has highest thermal conductivity, and highest mass fraction. This method has acquired 4.33 times higher thermal conductivity than pure metal hydrides with quite low quantity of additives, only 0.99 wt% of carbon fiber. This is a good result comparing to other method which can reach higher effective thermal conductivity but needs much higher mass fraction of additives too.

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Effect of Deformation Induced Martensite on the Damping Capacity of Fe-26Mn-4Co-2Al Alloy (Fe-26Mn-4Co-2Al 합금의 감쇠능에 미치는 가공 유기 마르텐사이트의 영향)

  • Jeong, Kyu-Seong;Kang, Chang-Yong
    • Korean Journal of Materials Research
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    • v.26 no.9
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    • pp.493-497
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    • 2016
  • This study was carried out to investigate the effect of deformation induced martensite on the damping capacity of Fe-26Mn-4Co-2Al damping alloy. ${\alpha}^{\prime}$ and ${\varepsilon}$-martensite were formed by cold working, and; deformation induced martensite was formed with according to the specific direction and the surface relief. With an increasing degree of cold rolling, the volume fraction of ${\alpha}^{\prime}$-martensite increased rapidly, while the volume fraction of ${\varepsilon}$-martensite decreased after rising to a maximum value at a specific level of cold rolling. Damping capacity was increased, and then decreased with an increasing of the degree of cold rolling. Damping capacity was influenced greatly by the volume fraction of ${\varepsilon}$-martensite formed by cold working, but the effect of the volume fraction of ${\alpha}^{\prime}$-martensite have a actually on effect on the damping capacity.

Magnetic Properties of Transition Metal-implanted ZnO Nanotips Grown on Sapphire and Quartz

  • Raley, Jeremy A.;Yeo, Yung-Kee;Hengehold, Robert L.;Ryu, Mee-Yi;Lu, Yicheng;Wu, Pan
    • Journal of Magnetics
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    • v.13 no.1
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    • pp.19-22
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    • 2008
  • ZnO nanotips, grown on c-$Al_2O_3$ and quartz, were implanted variously with 200 keV Fe or Mn ions to a dose level of $5{\times}10^{16}cm^{-2}$. The magnetic properties of these samples were measured using a superconducting quantum interference device (SQUID) magnetometer. Fe-implanted ZnO nanotips grown on c-$Al_2O_3$ showed a coercive field width of 209 Oe and a remanent field of 12% of the saturation magnetization ($2.3{\times}10^{-5}emu$) at 300K for a sample annealed at $700^{\circ}C$ for 20 minutes. The field-cooled and the zero-field-cooled magnetization measurements also showed evidence of ferromagnetism in this sample with an estimated Curie temperature of around 350 K. The Mn-implanted ZnO nanotips grown on c-$Al_2O_3$ showed superparamagnetism resulting from the dominance of a spin-glass phase. The ZnO nanotips grown on quartz and implanted with Fe or Mn showed signs of ferromagnetism, but neither was consistent.