• Title/Summary/Keyword: Mn composition

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The Effect of Paste Composition and Particle Size on the Alumina Ceramics Metallizing (Paste의 조성과 입도 변화가 알루미나 세라믹스의 Metallizing에 미치는 영향에 관한 연구)

  • 김태송;김성태;김종희
    • Journal of the Korean Ceramic Society
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    • v.30 no.5
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    • pp.347-356
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    • 1993
  • In joining alumina ceramics to metal by using Mo-Mn metallizing process the effects of metallizing thickness, temperature, and the composition of paste on the bond strength and the microstructure of joining interface were investigated. The bond strength variation in the range of metallizing temperature, 1350~155$0^{\circ}C$ was more than 150MPa above 145$0^{\circ}C$ and the optimum metallizing thickness was 30${\mu}{\textrm}{m}$. The optimum contents of Mn in Mo-Mn paste was 5% due to the bond strength decrease with the increase of addition. The effect of SiO2 addition in paste on bond strength was saturated around 200MPa. It was also observed that as the particle size of Mo decreased, the joinning with higher bond strength was shown in spite of low metallizing temperature.

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Resistivity-Temperature Properties of Mn-Mg-Fe Oxide Systems (Mn-Mg-Fe 계 산화물 조성의 저항-온도 특성)

  • 이승관;김종령;오영우
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.407-410
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    • 2000
  • (M $n_{l-x}$M $g_{l-x}$)F $e_{2+x}$ $O_4$(x=0.0, 0.025, 0.1, 0.2) for NTC(negative temperature coefficient) thermistor was prepared by calcining at 80$0^{\circ}C$ and sintering at from 1100 to 130$0^{\circ}C$ with 5$0^{\circ}C$ intervals while x was varied from 0.0 to 0.025, 0.1 and 0.2. The best linear property was obtained in the based specimen sintered at 120$0^{\circ}C$ with x=0.1 composition. Thermistor parameter, $B_{25~85^{\circ}C}$, was in the range of 5000~ 7300 [K]. Temperature coefficient of resistance, $\alpha$$_{25^{\circ}C}$, was -5.2 %/$^{\circ}C$. The results showed the possibility that Mn-Ni-Co based thermistor could be substituted by the composition used in this study was confirmed.med.d.

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Magnetic Properties of Mn and La-Mn Substituted Strontium Ferrite (Mn 및 La-Mn 치환 Sr 페라이트의 자기적 특성 변화)

  • 장세동;김종오;김종희
    • Journal of the Korean Magnetics Society
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    • v.11 no.6
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    • pp.267-271
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    • 2001
  • These experiments were carried out to examine the effects of elemental substitution of Mn and La-Mn on Sr-ferrite. The calcined properties for the Mn and La-Mn substitution were examined, and the sintered magnetic properties were compared with the stoichiometric condition. The magnetic properties of calcined SrM and (La-Mn)$_{0.3}$-SrM composition were as follows, respectively; M$_{s}$ : 61.06 emu/g, $_{i}$H$_{c}$ : 4.45 kOe and M$_{s}$ : 61.06 emu/g, $_{i}$H$_{c}$ : 4.46 kOe. Also, the sintered ferrite magnets of Mn$_{0.3}$-SrM and [(La-Mn)$_{0.3}$-SrM exhibited a similar properties to the stoichiometric composition but the coercivity of (La-Mn)$_{x}$-SrM was decreased rapidly with x=0.5.

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Electrical Characteristics of Cathode Li($Mn_{1-\delta}$$M_{\delta}$)$_2$$O_4$ Substituted by Transition Metals in Li-Ion Secondary Batteries (전이금속 치환 리튬이온 이차전지 정극 Li($Mn_{1-\delta}$$M_{\delta}$)$_2$$O_4$의 전기적 특성)

  • 박재홍;김정식;유광수
    • Journal of the Korean Ceramic Society
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    • v.37 no.5
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    • pp.466-472
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    • 2000
  • As cathode materials of LiMn2O4-based lithium-ion secondary batteries, Li(Mn1-$\delta$M$\delta$)2O4 (M=Ni and Co, $\delta$=0, 0.05, 0.1 and 0.2) materials which Co and Ni are substituted for Mn, were syntehsized by the solid state reaction at 80$0^{\circ}C$ for 48 hours. No second phases were formed in Li(Mn1-$\delta$M$\delta$)2O4 system with substitution of Co. However, substitution of Ni caued to form a second phase of NiO when its composition exceeded over 0.2 of $\delta$ in Li(Mn1-$\delta$M$\delta$)2O4. As the results of charging-discharging test, the maximum capacity of Li(Mn1-$\delta$M$\delta$)2O4 appeared in $\delta$=0.1 for both Co and Ni. Also, Li(Mn1-$\delta$M$\delta$)2O4 electrode showed higher capacity and better cycle performance than LiMn2O4.

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Synthesis of LiMn2O4 Powders Using Li-Ion Secondary Battery by SHS Process (SHS합성법에 의한 리튬이온이차전지용 정극활물질 LiMn2O4 의 제조)

  • Jang, Chang-Hyun;Nersisyan, Hayk;Kim, Jung-Han;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.42 no.7 s.278
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    • pp.503-508
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    • 2005
  • A simple and effective method for the synthesis of LiMn$_{2}$O$_{4}$ powder as a cathode material for lithium secondary battery is reported. Micrometer size LiMn$_{2}$O$_{4}$ was prepared by combustion synthesis technique employing initial mixture of l.l LiNO$_{3}$ -1.3Mn-0.7MnO$_{2}$-1NaCl composition. Parametric study of the combustion process including molar ratio of Mn/MnO$_{2}$ and NaCl concentration were carried out under air atmosphere. The combustion products obtained were additionally heat treated at the temperature 900$^{\circ}C$ and the washed by distilled water. The results of charging-discharging characteristics revealed that LiMn$_{2}$O$_{4}$ cell synthesized in the presence of NaCl had a high capacity and much better reversibility than one formed without NaCl An approximate chemical mechanism for LiMn$_{2}$O$_{4}$ formation is proposed.

Effect of MnO2 Addition on Electrical Properties and Microstructure in Pb[Cd1/2W1/2)0.02Zr0.505Ti0.475]O3 (Pb[Cd1/2W1/2)0.02Zr0.505Ti0.475]O3조성에서의 MnO2첨가에 대한 영향)

  • 김대웅;김병익;김호기
    • Journal of the Korean Ceramic Society
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    • v.25 no.6
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    • pp.571-576
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    • 1988
  • The microstructure and electrical properties of 0.02Pb[Cd1/2W1/2)O3-0.505PbZrO3-0.475PbTiO3 with MnO2 addition have been investigated. The amount of MnO2 addition was 0, 0.2, 0.4, 0.6, 0.8, 1wt%, respectively. When MnO2 is added up to 0.2wt%, Mn3+ which is substituted for Ti4+ site make hole and act as a acceptor. When MnO2 is added over 0.2wt% Mn3+ which is substituted for Cd2+ site create electron and act as a donor. The variation of grain size show that it was rapidly increased by 0.4wt% addition of MnO2, and while that in the range of over 0.6wt% addition of MnO2 it was decreased. The solid solution range of MnO2 that assumed in this composition according to the variations of microstructure and electrical properties was 0.4-0.6wt%.

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Composition-dependent Magnetic Properties of Si1-xMnx (0.1 < x <0.9) Single Crystals

  • Hwang, Young-Hun;Um, Young-Ho;Park, Hyo-Yeol
    • Journal of Magnetics
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    • v.15 no.2
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    • pp.56-60
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    • 2010
  • In this study, we investigated the optical, magnetic, and electrical transport properties of $Si_{1-x}Mn_x$ (0.1 < x < 0.9) single crystals grown by the vertical Bridgman method. The alloys with a Mn concentration of up to 64% demonstrated weak ferromagnetic ordering around $T_C=30\;K$. The $Si_{0.25}Mn_{0.75}$ and $Si_{0.18}Mn_{0.82}$ alloys showed weak ferromagnetic ordering at 70 K and antiferromagnetic ordering at 104 K, as confirmed by magnetization, neutron diffraction, and transport studies.

Dependence of luminescence property of ZnMgS:Mn thin film phosphor on RTA temperature (ZnMgS:Mn 박막 형광체의 RTA 온도 변화에 따른 발광 특성 의존성)

  • Lee, Dong-Chin;Yun, Sun-Jin;Jeon, Duk-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05a
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    • pp.102-105
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    • 2004
  • With varying rapid thermal annealing (RTA) temperature, luminescent properties of ZnMgS:Mn thin film sputter-deposited with one target were measured. Although all samples have the same composition, $Zn_{1-x}Mg_xS:Mn$ (x=0.25) can emit luminescence between 580 and 614 nm, which is controlled by only RTA temperature. It is understood that the energy band gap shift of ZnMgS:Mn thin film phosphor occurs with varying RTA temperature.

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Oxidation of Chromium(III) to Chromium (VI) by Manganese Oxides : Variability in Mineralogy

  • Kim, Jae Gon
    • Proceedings of the Petrological Society of Korea Conference
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    • 1999.06a
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    • pp.25-29
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    • 1999
  • Manganese (Mn) oxides in soils and sediments differ in structure and composition. The influence of that diversity on the chromium (Cr) oxidation is the subject of this report. Oxidation of Cr(III) to Cr(VI) by coarse clay size Mn oxides (synthetic pyrolusite and natural lithiophorite, todorokite, and bimessite) was studied. Chromium oxidation by Mn oxides was initially fast and followed by a slow reaction. More Cr was oxidized by the Mn oxides at lower pH and higher initial Cr(III) concentration in solution. Birnessite had the highest chromium oxidation capacity per unit external surface area (COCUESA) and lithiophorite had the lowest COCUESA. The kinetics of Cr oxidation and COCUESA of Mn oixdes were apparently controlled by reactivity of surface Mn, mineralogy, and solution properties (pH and Cr(III) concentration).

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