• 품질경영학회지
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• 제48권2호
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• pp.269-282
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• 2020

Purpose: The practical design for experiments with mixtures of q components is consisted in the four types of design points, vertex, center of edge, axial, and center points in a (q-1)-dimensional simplex space. We propose a sequential method for the successful construction of the design space in Quality by Design (QbD) by allowing the different number of replicates at the four types of design points in the practical design when the quadratic canonical polynomial model is assumed. Methods: To compare the mixture designs efficiency, fraction of design space (FDS) plot is used. We search for the practical mixture designs whose the minimal half-width of the tolerance interval per a standard deviation, which is denoted as d₂, is less than 4.5 at 0.8 fraction of the design space. They are found by adding the different number of replicates at the four types of the design points in the practical design. Results: The practical efficient mixture designs for the number of components between three and five are listed. The sequential method to establish a design space is illustrated with the two examples based on the simulated data. Conclusion: The designs with the center of edge points replications are more efficient than those with the vertex points replication. We propose the sample size of at least 23 for three components, 28 for four components, and 33 for the five components based on the list of efficient mixture designs.

• 대한원격탐사학회지
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• 제19권6호
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• pp.411-419
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• 2003

광학영상에서 개별 화소에 해당하는 공간은 반사특성이 상이한 두 개 이상의 지표물이 존재하는 경우가 대부분이나, 기존의 영상처리는 각 화소를 단일의 지표물로 가정하여 처리하였다. 본 연구에서는 분광혼합분석(spectral mixture analysis)을 이용하여 개개의 화소를 구성하고 있는 두 가지 이상의 지표물을 점유비율에 따라 분해하고 그 결과의 활용 가능성을 분석하였다. 경기도 광릉시 험림을 대상으로 Landsat-7 ETM+ 영상을 획득하여 대기보정 및 지형효과에 의한 복사보정을 실시하였다. 선형혼합모델을 통하여 각 화소를 6개 단위지표물(endmember)의 점유비율로 분해하였다. 각 endmember의 점유비율을 나타내는 영상들을 조합하여 보다 세부적인 임상분류가 가능하였다. 토양의 점유비율을 이용하여 수관울폐도와 관련된 정보의 추출도 가능하다고 판단된다. 또한 침엽수림의 화소값에 그늘에 의한 영향이 많다는 것을 알 수 있었다. 산림의 다양하고 복잡한 구성요소를 감안한다면 분광혼합분석은 기존의 영상처리방법에서 얻을 수 없었던 세부적인 산림정보의 추출을 위한 새로운 도구로 기대 된다.

• 공업화학
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• 제18권2호
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• pp.168-172
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• 2007

회분 병류 5단 평형추출에 의해 4종류의 질소고리화합물[indole(In), quinoline(Q), iso-quinoline(iQ), quinaldine(Qu)], 3종류의 2환 방향족화합물[1-methylnaphthalene(1MN), 2-methylnaphthalene(2MN), dimethyl naphthalene(DMN)], biphenyl과 phenyl ether로 구성된 모델 혼합물로부터 In의 분리를 검토했다. 본 연구의 원료로서 사용된 모델 혼합물은 콜타르 유분(유출온도범위: $240{\sim}265^{\circ}C$)을 구성하고 있는 성분 및 조성을 고려하여 작성했다. 추출용매로서는 Formamide 수용액을 사용했다. 4단 평형추출을 통해 In을 99% 이상 회수할 수 있었다. 5단 평형추출을 통해 얻어진 DMN을 기준성분으로한 In의 선택도는 63~118의 범위를 나타냈다. 본 연구를 통해 얻어진 실험적 결과와 이전의 연구결과를 이용하여 콜타르 중에 함유된 In의 분리 및 회수공정을 검토했다.

• 한국연소학회지
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• 제19권4호
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• pp.49-55
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• 2014

Design criterion for the size of micro Pt-catalytic combustor is investigated in terms of heat release rate. One-dimensional plug flow model is applied to determine the surface reaction constants using the experimental data at stoichiometric butane-air mixture. With these reaction constants, the mass fraction of butane and heat release rate predicted by the plug flow model are in good agreement with the experimental data at the combustor exit. The relationship between the size of micro catalytic combustor and mixture flowrate is introduced in the form of product of two terms-the effect of fuel conversion efficiency, and the effect of chemical reaction rate and mass transfer rate.

• EDISON SW 활용 경진대회 논문집
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• 제5회(2016년)
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• pp.147-154
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• 2016

Co-nonsolvency is a puzzling phenomenon that a polymer swells in a good solvent individually, but it collapses in a mixture of good solvents. This structural transition with changing solvent environment has been drawing attention due to practical application for stimuli-responsive polymer. The aim of this work is to describe the physical origin of the co-nonsolvency. In this work, we present Monte Carlo simulations for polymer solutions by using simple and general model. We simulate linear and ring polymers to compare their co-nonsolvency behaviors. Calculating Flory exponents and bridging fractions gives a good description for polymer structures. While the polymer structure shows non-monotonous behavior with increasing the cosolvent fraction, the chemical potential decreases monotonously. This indicates that coil-to-globule transition of polymers is purely controlled by free energy and can be regarded as a thermodynamics transition. We also present that ring polymers have higher looping probability than linear polymers, thus the bridging fraction remains higher at high cosolvent fraction. Our study provides a new perspective to understand polymer structure when the polymer "dissolves well" in any solvent.

• 공학논문집
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• 제6권2호
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• pp.85-98
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• 2004

The adsorption equilibrium data for the binary gas mixture system from the pure gas adsorption data of carbon dioxide and ethylene on ZSM-5 prepared were predicted. The binary gas mixture adsorption data have been examined against predicted values by two models-the vacancy solution model(VSM) and the statistical thermodynamic model(STM), using parameters obtained from the single component isotherm. The binary gas mixture data for the carbon dioxide-ethylene system were obtained for cation exchanged forms of ZSM-5 for the gas phase carbon dioxide mole fraction of 0.752 at $37^{\circ}C$ and 1 atm. The experimental adsorption phase diagrams were obtained for carbon dioxide-ethylene on sodium form ZSM-5 synthesized. The single component adsorption isotherms for carbon dioxide and ethylene were also obtained for this zeolite. The single component data were used to obtain parameters derived in two models. These parameters were, in turn, used to predict the binary mixture isotherms for this zeolite. Both the vacancy solution and the statistical thermodynamic models give satisfactory predictions of adsorption phase diagrams for the binary gas mixtures of carbon dioxide and ethylene on sodium exchanged ZSM-5. Also the correlation between the experimental data and the predicted values is generally in good agreement. The system appears to show ideal behavior with a relatively constant separation factor. The slight increase in adsorption capacity with an increase in ionic radius is due, in part, to the higher polarizability associated with larger cations.

• 한국대기환경학회지
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• 제12권5호
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• pp.577-585
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• 1996

A screening study was performed in order to resolve the flow, combustion and emission characteristics of the gas furmace with co-axial diffusion flane burner. A control-valume based finite-difference method with the power-law scheme was employed for discretization. Numerical procedure for the differential equation was used by SIMPLEST to enclosute rapid converge. A k-.varepsilon. model was incorporated for the closure of turbulence. The mass fraction and mixture fraction were calculated by cinserved scalar method. An equilibrium analysis was employed to determine the concentration of radicals in the product stream and conserbation equations were them solved for N amd NO by Zelovich reaction scheme. The method was exercised in a simple one-dimensional case first, to determine the effects of air ratio, temperature and residence time on NO formation and applied to a furnace with co-axial diffusion flame burner.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 춘계학술발표대회 논문집
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• pp.73-76
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• 2002

This study developed SiC/Al composites for electronic packaging to which reinforcements were added with the volume fractions of 49%, 56% and 63% by the squeeze casting method. 0.8 wt.% of the inorganic binder as well as the $Al_2O_3$ fiber and SiC particles with the volume fraction of 1:10 were added to the SiC/Al composites For the produced SiC/Al composites, the CTEs (coefficients of thermal expansion) were measured from 30 to $300^{\circ}C$ and compared with the FEM numerical simulation to analyze the temperature dependent properties. The experiment showed the CTEs of SiC/Al composites that were intermediate values of those of Rule of Mixture and Turner's Model. The CTEs were close to Turner's Model in the room temperature and approached the Rule of Mixture as the temperature increases. These properties analyzed from the difference of the average stress acting between the matrix and the reinforcements proposed in this study

• Food Science and Biotechnology
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• 제16권6호
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• pp.954-957
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• 2007

Gelation mechanism of xanthan-carob mixture (X/C) was investigated based on thermorheological behavior. Three X/C ratios (1:3, 1:1, and 3:1) were studied. Small amplitude oscillatory shear tests were performed to measure linear viscoelastic behavior during gelation. Temperature sweep ($-1^{\circ}C/min$) experiments were conducted. Using a non-isothermal kinetic model, activation energy (Ea) during gelation was calculated. At 1% total concentration, the Ea for xanthan fraction (${\phi}_x$)=0.25, 0.5, and 0.75 were 178, 159, and 123 kJ/mol, respectively. However, a discontinuity was observed in the activation energy plots. Based on this, two gelation mechanisms were presumed-association of xanthan and carob molecules and aggregation of polymer strands. The association process is the primary mechanism to form 3-D networks in the initial stage of gelation and the aggregation of polymer strands played a major role in the later stage.

• Composites Research
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• 제34권2호
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• pp.129-135
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• 2021

본 논문에서는 필라멘트 와인딩 공정에서 발생하는 두께 방향 섬유체적비 불균일이 원통형 복합재 격자 구조의 좌굴하중에 미치는 영향을 확인하기 위해서 Vasiliev가 제안한 원통형 복합재 격자 구조 좌굴하중 이론식을 변형하여 섬유체적비에 따른 좌굴하중 저하를 확인하였다. 섬유체적비에 따라 격자 구조 리브의 각 층의 두께를 달리하였으며, 혼합법칙을 사용하여 각 층별로 물성치를 다르게 적용하였다. 구조물 크기, 두께, 섬유체적비 평균값을 달리한 유한요소모델에 대한 선형좌굴해석을 수행하였다. 최종적으로 이론식을 사용한 등가모델의 좌굴 하중 계산 결과와 유한요소해석 결과를 비교하여 두께 방향 섬유체적비 불균일이 원통형 복합재 격자 구조의 좌굴하중 저하의 원인이 될 수 있음을 확인하였다.