• Title/Summary/Keyword: Mixing coefficient

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Practical Classification of Herbicide by Two-dimensional Ordination Analysis in Transplanted Lowland Rice Field (Two-dimensional Ordination 분석법(分析法)에 의한 제초제(除草劑) 살초(殺草) Spectrum 분류(分類)에 관한 연구(硏究))

  • Kim, Soon-Chul;Park, Rae-Kyeong
    • Korean Journal of Weed Science
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    • v.2 no.2
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    • pp.129-140
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    • 1982
  • Herbicides were classified by two-dimensional ordination analysis based on the weed flora which was not controlled by application of a particular herbicide. The number of herbicide group was varied depending upon the weed community type and the experiment site. The technique of the two-dimensional ordination analysis gave more comprehensive informations about selecting of herbicides for increasing the herbicidal efficacy, for increasing the weed spectrum and for reducing the herbicide cost by mixing of herbicides. The two-dimensional ordination analysis could be used not only herbicide classification and selecting effective herbicide or herbicide combination but also can be used for the evaluation of systematic application of herbicides.

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The Effect of ${\pi}$ Bonds on the Calculated Dipole Moments for Tetrahedral and Square Planar [M(Ⅱ)$O_2S_2$] Type Complexes [M(II) = Co(II), Ni(II), Cu(II) and Zn(II)] (사면체 및 사각형 [M(II)$O_2S_2$]형태 착물의 쌍극자 모멘트에 대한 ${\pi}$결합의 영향 [M(II) = Co(II), Ni(II), Cu(II) 및 Zn])

  • Sangwoon Ahn;Jin Ha Park;Chang Jin Choi
    • Journal of the Korean Chemical Society
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    • v.26 no.5
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    • pp.265-273
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    • 1982
  • The effect of ${\pi}$ bonds on the calculated dipole moments for square planar and tetrahedral [M(II)$O_2S_2$]] type complexes has been investigated by two different approaches. One is the approximate molecular orbital method based on the assumption that the mixing coefficient CM of the valence basis sets for the central metal ion and the appropriate ligand orbitals is equal for all ${\sigma}$ and ${\pi}$ bonding molecular orbitals. The other is the more refined calculation based on the semiempirical LCAO-MO method. If ${\sigma}$ bonds only are assumed to be formed, the calculated dipole moments for square planar and tetrahedral complexes are lower than those of the experimental values. If the contribution of ${\pi}$ bonds to the calculated dipole moments are fully considered, the calculated dipole moments for both square planar and tetrahedral [M(II)$O_2S_2$]] type complexes are higher than the experimental values. However if ${\pi}$ bonds are assumed to be delocalzed, the calculated dipole moments for tetrahedral [M(II$O_2S_2$]] type complexes fall in the range of the experimental values, but those for square planar complexes deviate from the experimental values. These results suggest that [M(II)$O_2S_2$]] type complexes may have the tetrahedral structure in inert solvent solution. This structure is in agreement with the experimental one. The calculated dipole moments for tetrahedral [M(II)$O_2S_2$]] type complexes indicate that the contribution of ${\pi}$ bonds to the calculated dipole moments may not be neglected.

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The Post Annealing Effect of Organic Thin Film Solar Cells with P3HT:PCBM Active Layer (P3HT:PCBM 활성층을 갖는 유기 박막태양전지의 후속 열처리 효과)

  • Jang, Seong-Kyu;Gong, Su-Cheol;Chang, Ho-Jung
    • Journal of the Microelectronics and Packaging Society
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    • v.17 no.2
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    • pp.63-67
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    • 2010
  • The organic solar cells with Glass/ITO/PEDOT:PSS/P3HT:PCBM/Al structure were fabricated using regioregular poly (3-hexylthiophene) (P3HT) polymer:(6,6)- phenyl $C_{61}$-butyric acid methyl ester (PCBM) fullerene polymer as the bulk hetero-junction layer. The P3HT and PCBM as the electron donor and acceptor materials were spin casted on the indium tin oxide (ITO) coated glass substrates. The optimum mixing concentration ratio of photovoltaic layer was found to be P3HT:PCBM = 4:4 in wt%, indicating that the short circuit current density ($J_{SC}$), open circuit voltage ($V_{OC}$), fill factor (FF) and power conversion efficiency (PCE) values were about 4.7 $mA/cm^2$, 0.48 V, 43.1% and 0.97%, respectively. To investigate the effects of the post annealing treatment, as prepared organic solar cells were post annealed at the treatment time range from 5min to 20min at $150^{\circ}C$. $J_{SC}$ and $V_{OC}$ increased with increasing the post annealing time from 5min to 15min, which may be originated from the improvement of the light absorption coefficient of P3HT and improved ohmic contact between photo voltaic layer and Al electrode. The maximum $J_{SC},\;V_{OC}$, FF and PCE values of organic solar cell, which was post annealed for 15min at $150^{\circ}C$, were found to be about 7.8 $mA/cm^2$, 0.55 V, 47% and 2.0%, respectively.

Investigation of Thermal Stability of Epoxy Composite Reinforced with Multi-Walled Carbon Nanotubes and Micrometer-Sized Silica Particles (다중벽 탄소나노튜브와 마이크로미터 크기 실리카 입자로 강화된 에폭시 복합재료의 열 안정성에 관한 연구)

  • Oh, Ryun;You, Byeong Il;Ahn, Ji Ho;Lee, Gyo Woo
    • Composites Research
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    • v.29 no.5
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    • pp.306-314
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    • 2016
  • In this study, to improve the thermal stabilities of the epoxy composite specimens in addition to the enhanced mechanical properties, those were reinforced with carbon nanotubes and micrometer-sized silica particles. To disperse the filler in matrix relatively simple physical process, specimens were fabricated using shear mixing and sonication. Tensile strength, coefficients of thermal expansion and thermal conductivity of the specimens were measured with varied contents of the two fillers. The mechanical and thermal properties were also discussed, and the experimental results of thermal expansion related to the thermal stability of the specimens were compared with those from several micromechanics models. The hybrid composites specimens incorporating 0.6 wt% of carbon nanotubes and 50 wt% of silica particles showed better mechanical properties than the others with increase in tensile strength up to 11%, with respect to those of the baseline specimens. As the silica contents were increased the thermal expansion was reduced down to 36%, and the thermal stability was improved with the decreased thermal deformation. Thermal conductivity of the epoxy composite specimens incorporating 50 wt% of silica particles was enhanced, which demonstrate improvement of 72%. The mechanical and thermal properties of the hybrid composites specimens incorporating the two fillers were improved simultaneously.

Studies on the Fishery Biology of Pomfrets, Pampus spp. in the Korean Waters 5. Distribution and Fishing Condition (한국근해 병어류의 자원생물학적 연구 5. 분포와 어황)

  • CHO Kyu Dae;KIM Jeong Chang;CHOE Yong Kyu
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.22 no.5
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    • pp.294-305
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    • 1989
  • Basedon statistical data of pomfret (Pampus spp.) catches by the stow net during $1970\~1985$, the distribution and migration of pomfrets and fishing conditions were investigated in relation to oceanographic conditions, in the East China Sea and the Yellow Sea. The main fishing grounds of Pomfrets were formed around the Great Yangtze Sand Bank which locates between the Cheju Island and the mouth of the Yangtze River. Its area occupied only 11 percent of all fishing grounds, and about 70 percent of total catch was found there. The coefficient of variation(CV) in catch was below 0.01 in the whole fishing grounds and that of tile main fishing grounds (14 fishing areas) was $0.001\~0.003$. This area was indicated markedly by the inflow of Yellow Sea Warm Current from spring to autumn, and this mixing area which formed the oceanic front among the China Continental Shelf Water, the Yellow Sea Bottom Cold Water and the Tsushima Warm Current. The pomfrets migrates to south-north according to the expansion and contraction of the Tsushima Warm Current including the Yellow Sea Warm Current and the Yellow Sea Bottom Cold Water. Therefore, it migrates to north of the Yellow Sea in summer and to southern part of the East China Sea in winter. The most frequent range of the water type for high catch was $10\~12^{\circ}C$ in temperature and $32.4\~33.4\%_{circ}$ in salinity. The ranges was occupied more than 70 percent of total catch on fishing season. The frequency range of the water type was not different between the abundant fishing periods and the poor fishing periods in terms of the maximum catches.

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Study on the Steam Line Break Accident for Kori Unit-1 (고리 1호기에 대한 증기배관 파열사고 연구)

  • Tae Woon Kim;Jung In Choi;Un Chul Lee;Ki In Han
    • Nuclear Engineering and Technology
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    • v.14 no.4
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    • pp.186-195
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    • 1982
  • The steam line break accident for Kori Unit 1 is analyzed by a code SYSRAN which calculates nuclear power and heat flux using the point kinetics equation and the lumped-parameter model and calculates system transient using the mass and energy balance equation with the assumption of uniform reactor coolant system pressure. The 1.4 f $t^2$ steam line break accident is analyzed at EOL (End of Life), hot shutdown condition in which case the accident would be most severe. The steam discharge rate is assumed to follow the Moody critical flow model. The results reveal the peak heat flux of 38% of nominal full power value at 60 second after the accident initiates, which is higher than the FSAR result of 26%. Trends for the transient are in good agreement with FSAR results. A sensitivity study shows that this accident is most sensitive to the moderator density coefficient and the lower plenum mixing factor. The DNBR calculation under the assumption of $F_{{\Delta}H}$=3.66, which is used in the FSAR with all the control and the shutdown assemblies inserted except one B bank assembly and of Fz=1.55 shows that minimum DNBR reaches 1.62 at 60 second, indicating that the fuel failure is not anticipated to occur. The point kinetics equation, the lumped-parameter model and the system transient model which uses the mass and energy balance equation are verified to be effective to follow the system transient phenomena of the nuclear power plants.lear power plants.

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Analysis of Optimal Mixing Ratios in Tortilla Preparations with Rice and Wheat Flour (Tortilla의 제조를 위한 쌀가루와 밀가루의 최적 혼합비 분석)

  • Han, Gyu-Hong;Yoo, Jin-Hyun
    • The Korean Journal of Food And Nutrition
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    • v.20 no.1
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    • pp.1-8
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    • 2007
  • Tortillas were prepared using rice and wheat flour. The experimental design incorporated thee independent variables(rice, wheat flour and moisture content) producing 14 samples of different proportions of each variable for each tortilla. The following were analysed using Design Expert 6 to unveil the influences of these variables on tensile strength and color(L, a, b). Results indicated that tensile strength increased with increasing rice and wheat flour content, however, decreased with increasing moisture content. Lighteness(L), of the tortilla increased with increased rice content whereas yellowness(b) increased with increased wheat flour content. The model suggests that tensile strength and color(L, a, b) in tortillas are highly correlated(SD Comment - give correlation coefficient and p-value). As well, the numerical optimization method suggests that the ratio of wheat flour to rice flour to moisture content which maximizes the three responses(tensile strenth, L and b) is 18.26 : 33.92 : 39.24%, 28.15 : 25.77 : 37.50%.

Binary and Ternary Competitive Adsorption of Basic Dyes from Aqueous Solution onto the Conchiolin Layer (수용액에서의 이성분 및 삼성분 염기성 염료의 진주층에 대한 경쟁흡착)

  • Shin, Choon-Hwan;Song, Dong-Ik
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.3
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    • pp.270-275
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    • 2006
  • The cultivated pearls collected for the study were pretreated through the removal of contaminants and the surface bleaching for easy dyeing. Coloring of pearls are necessary after selecting dyes adsorbable to the Conchiolin layer, a kind of hard protein formed in the seawater, covering the surface of the pretreated pearls. Dyes adsorbable to the Conchiolin layers are mostly basic dyes such as Rhodamine 6G(R6G), Rhodamine B(RB), Methylene Blue(MB) etc. and the binary and ternary competitive adsorption were performed by mixing two or three dyes together. The multi-dye adsorption data were compared with the predictions from the ideal adsorbed solution theory(IASI) combined with the single-dye adsorption model, the Langmuir or the Redlich-Peterson(RP) model. The quality of prediction was compared by using determination coefficient($R^2$) and standard deviation(SSE) values. Predictions from the IAST were found to be in good agreement with the data for the R6G/RB binary adsorption to the pearl layers not fractionated with their size, except for the adsorption data for RB at high concentrations. Among the three binary adsorption systems, R6G/RB, R6G/MB, and MB/RB, only the RB sorption data in the R6G/RB binary system was in poor agreement with the IAST prediction. Competitive adsorption data in ternay systems were in good agreement with the predictions from the IAST except for the RB data.

Isothermal Vapor-liquid Equilibria for the Binary Mixtures of 3-Methylpentane with Ethylene Glycol Monopropyl Ether and Ethylene Glycol Isopropyl Ether (3-메틸펜테인과 에틸렌 글리콜 모노프로필 에테르 및 에틸렌 글리콜 아이소프로필 에테르 혼합물에 대한 2성분계 등온 기-액 상 평형)

  • Hyeong, Seonghoon;Jang, Sunghyun;Kim, Hwayong
    • Korean Chemical Engineering Research
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    • v.53 no.3
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    • pp.302-308
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    • 2015
  • Isothermal vapor liquid equilibria for the binary system of 3-methylpentane with ethylene glycol monopropyl ether ($C_3E_1$) and ethylene glycol isopropyl ether ($iC_3E_1$) were measured at 303.15, 318.15, and 333.15K. In our previous work, phase equilibria for the binary system of $C_3E_1$ mixtures were investigated according to the chain length of alkane, alcohol or those isomer. But in this study, we discussed the different effect of $C_3E_1$ and its isomer, $iC_3E_1$, on the phase equilibria. The measured systems were correlated with a Peng-Robinson equation of state (PR EOS) combined with Wong-Sandler mixing rule for the vapor phase, and NRTL, UNIQUAC, and Wilson activity coefficient models for the liquid phase. All the measured systems showed good agreement with the correlation results. And it was found that the phase equilibria showed very little difference between the $iC_3E_1$ mixture system and the $C_3E_1$ mixture system.

Experimental Study on Engineering Characteristic of the Waste Landfill Soil Admixed Linear (폐기물매립지 토사계 혼합 차수재의 공학적 특성에 대한 실험적 연구)

  • Chang, Yongchai;Kim, Jinchun;Jeong, Ogki
    • Journal of the Korean GEO-environmental Society
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    • v.8 no.1
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    • pp.13-20
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    • 2007
  • Leachates resulting from the waste landfill of waste can possibly cause the second pollution, such as the underground water and environmental pollution. Accordingly, Liner layer has been installed in the reclaimed land of waste to block and purify permeation water to and prevent this second pollution. The material used as Liner layer should have water resistance and be less than permeability coefficient of $1{\times}10^{-7}$ cm/sec. As it is very difficult to get this kind of natural clay with low permeability around the field, the suitable way to get the low permeable material is to use blend with good watertighness by mixing it with natural soil which is spread in the site. While this mixed soil, which can resist water, is commonly used in the site, namely, bentonite and MCG cementious mateiral mixed soil, which is widely used as Liner layer in the reclaimed land of waste, is recognized in Liner and durability. The study was performed to find the effect of additive of the bottom liner in the waste landfill. The aim of this paper is to explain of the field application examples as well as the data of experimental research with the engineering properties of Liner layer of the reclaimed land.

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