• Journal of the Korean Crystal Growth and Crystal Technology
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• v.33 no.4
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• pp.139-144
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• 2023

Stone papers made of inorganic filler and plastic polymer do not use pulp, which is the main raw material of existing papers, so they contribute to the preservation of nature and can be used as more eco-friendly materials when they have biodegradability. Since most stone papers are manufactured by hot extrusion, the amount of ceramic fillers and related physical properties are limited to control manufacturing workability. In this study, the stone paper composition was prepared in a liquid form using solvents, so that there was little limitation on the amount of ceramic filler added and it was also easy to add additives to control biodegradability. They were fabricated from eco-friendly raw materials using waste oyster shells as an inorganic filler and (recyclable) PVC materials as an organic binder. After making a solution using common solvents for PVC, inorganic filler and cellulose to impart biodegradability were mixed and processed into sheets to prepare solvent-based stone papers, and their paper properties were evaluated.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.1
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• pp.175-180
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• 2016

Waste bumpers from out-of-service vehicles are recycled in the manufacturing process of plastic parts by incorporating pristine materials after removing the coated paint on a bumper. This study examined the chemical properties and mechanical properties of a mixture of recycled bumper and pristine materials as a function of the mixing ratio. When the pristine materials and the recycled bumper pieces were mixed, the stiffness (tensile strength and the flexural modulus) was provided by their composition averages. On the other hand, the toughness (Izod impact strength and the elongation-at-break) was lower than their composition averages (i.e., negative deviation). FTIR analysis showed that these results were due to the absence of the compatibility between the pristine materials and recycled bumper pieces. When the recycled bumper pieces were loaded at more than 30 wt. %, the toughness decreased drastically. A previous study showed that a paint removal efficiency up to 80 wt.% was easily attainable. The other 20 wt.% of paint on the bumper is very difficult to remove. Therefore, this study examined the mechanical properties of a mixture of recycled bumper pieces containing the unremoved paint and recycled bumper pieces without paint. When the recycled bumper pieces containing the unremoved paint were incorporated in only small quantities, the mechanical properties were decreased to a great extent. These results show that the paint removal efficiency is very important in the recycled bumper industry.

• Journal of the Korean Geotechnical Society
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• v.15 no.2
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• pp.43-71
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• 1999

This research is an experimental work of developing a construction material using municipal wastewater sludge as liner and cover materials for waste disposal landfill. Weathered granite soil and flyash, produced as a by-product in the power plant, were used as the primary additives to improve geotechnical engineering properties of sludge. For secondary additives, bentonite and cement were mixed with sludge to decrease the permeability and to increase the shear strength, respectively. Various laboratory test required to evaluate the design criteria for liner and cover materials, were carried out by changing the mixing ratio of sludge with the additives. Basic soil properties such as specific gravity, grain size distribution, liquid and plastic limits were measured to analyze their effects on permeability, compaction, compressibility and shear strength properties of mixtures. Laboratory compaction tests were conducted to find the maximum dry densities and the optimum moisture contents of mixtures, and their effectiveness of compaction in field was consequently evaluated. Permeability tests of variable heads with compacted samples, and the stress-controlled consolidation tests with measuring permeabilities of samples during consolidation process were performed to obtain permeability, and to find the compressibility as well as consolidational coefficients of mixtures, respectively. To evaluate the long term stability of sludges, creep tests were also conducted in parallel with permeability tests of variable heads. On the other hand, for the compacted sludge decomposed for a month, permeability tests were carried out to investigate the effect of decomposition of organic matters in sludges on its permeability. Direct shear tests were performed to evaluate the shear strength parameters of mixed sludge with weathered granite, flyash and bentonite. For the mixture of sludge with cement, unconfined compression tests were carried out to find their strength with varying mixing ratio and curing time. On the other hand, CBR tests for compacted specimen were also conducted to evaluate the trafficability of mixtures. Various test results with mixtures were assessed to evaluate whether their properties meet the requirements as liner and cover materials in waste disposal landfill.

• Journal of the Korean Ceramic Society
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• v.53 no.2
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• pp.194-199
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• 2016

Presently, for the cement industry, studies that seek to reduce $CO_2$, because of the development of the plastic industry and demand for reduction of energy use, have been actively conducted among them, studies attempting to use Gamma-$C_2S({\gamma}-C_2S)$ to fix $CO_2$ have been actively conducted. The ${\gamma}-C_2S$ compound has an important function in reacting to $CO_2$ and stiffening through carbonatization in the air. The ${\gamma}-C_2S$ compound, reacting to $CO_2$ in the air, generates $CaCO_2$ within the pore structure of cement materials and densifies the pore structure this leads to an improvement of the durability and to the characteristic of resistance against neutralization. Therefore, in this experiment, in order to synthesize ${\gamma}-C_2S$, limestone sludge and waste foundry sands are used these materials are plasticized for 30 or 60 minutes at $1450^{\circ}C$, and are prevented from being cooled in the temperature range of $30{\sim}1000^{\circ}C$ when they are about to be cooled. XRD analysis and XRF analysis are used to determine the effects of this process on ${\gamma}-C_2S$ synthesization, the temperature at which a thing is plasticized, and the conditions for cooling that obtain in the plasticized clinker also, in order to confirm the $CO_2$ capture function, analysis of the major hydration products is conducted through an analysis of carbonatization depth and compressive strength, and through MIP analysis and XRD Rietveld analysis. As a result of these analyses, it is found that when ${\gamma}-C_2S$ was synthesized, the clinker that was plasticized at $1450^{\circ}C$ for one hour demonstrated the highest yield rate the sample with which the ${\gamma}-C_2S$ was mixed generated $CaCO_3$ when it reacted with $CO_2$ therefore, carbonatization depth and porosity were reduced, and the compressive strength was increased.