• Title/Summary/Keyword: Mixed layer

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Room Temperature Luminescence from ion Beam or Atmospheric Pressure Plasma Treated SrTiO3

  • Song, Jin-Ho;Seok, Jae-Gwon;Yeo, Chang-Su;Lee, Gwan-Ho;Song, Jong-Han;Sin, Sang-Won;Choe, Jin-Mun;Jo, Man-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.530-531
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    • 2013
  • 3 MeV protonirradiated SrTiO3 (STO) single crystal exhibits a blue and green mixed luminescence. However, the same proton irradiated STO deposited with very thin Pt layer does not show any luminescence. This Pt layer involved in preventing the damage caused by arcingthat comes from tens of kV surface voltage build-up due to secondary electron induced charge up at the surface of insulator during ion beam irradiation. It implies that luminescence of ion irradiated STO originated from the modified STO surface layer caused by arcing rather than direct ion beam irradiation effect. Atmospheric pressure plasma, a simple and cost-effective method, treated STO also exhibits the same kind of blue and green mixed luminescence as the ion beam treated STO, because this plasma also creates a surface damage layer by arcing.

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High operating temperature stable OLEDs with reduced reflectivity cathodes

  • Popovic, Zoran D.;Aziz, Hany;Vamvounis, George;Hu, Nan-Xing;Paine, Tony
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.21-24
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    • 2003
  • The understanding of the mechanism of device degradation has been accomplished recently, for devices using $AlQ_3$ electron transport and emitter molecule. In this presentation the experimental evidence for the degradation mechanism of $AlQ_3$ based devices will be reviewed, showing that the hypothesis of an unstable $AlQ_3^+$ cation explains a large amount of experimental data. This hypothesis, however, explains not only the room temperature device degradation in time but also sheds light on temperature stability of OLEDs. Dependence of half-life of a series of devices with an emitter layer composed of a mixture of $AlQ_3$ and different hole transport molecules (mixed emitter layer) will be discussed when they are operated at elevated temperatures. These results can also be explained in the framework of an unstable $AlQ_3^+$ species. An OLED structure containing a doped mixed emitter layer will be described, which shows extraordinary stability, half-life of 1200 hours at operating temperature of 70 C and initial luminance of 1650 $cd/m^2$. We will also discuss a novel Black $Cathode^{TM}$ OLED with reduced optical reflectivity, which is also stable at elevated temperatures. The new cathode utilizes a conductive light-absorbing layer made of a mixture of metals and organic materials.

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A Numerical Study on Shock Wave Turbulent Boundary Layer Interactions in High-Speed Flows (고속 흐름에서의 충격파와 난류경계층의 상호작용에 관한 수치적 연구)

  • Mun, Su-Yeon;Son, Chang-Hyeon;Lee, Chung-Won
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.3
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    • pp.322-329
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    • 2001
  • A study of the shock wave turbulent boundary layer interaction is presented. The focus of the study is the interactions of the shock waves with the turbulent boundary layer on the falt plate. Three examples are investigated. The computations are performed, using mixed explicit-implicit generalized Galerkin finite element method. The linear equations at each time step are solved by a preconditioned GMRES algorithm. Numerical results indicate that the implicit scheme converges to the asymptotic steady state much faster than the explicit counterpart. The computed surface pressures and skin friction coefficients display good agreement with experimental data. The flowfield manifests a complex shock wave system and a pair of counter-rotating vortices.

Room-Temperature Luminescence from Ion Beam or Atmospheric Pressure Plasma-Treated SrTiO3

  • Song, J.H.;Choi, J.M.;Cho, M.H.;Choi, E.J.;Kim, J.;Song, J.H.
    • Applied Science and Convergence Technology
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    • v.23 no.5
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    • pp.261-264
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    • 2014
  • $SrTiO_3$ (STO) single crystal irradiated with a 3-MeV proton beam exhibits blue and green mixed luminescence. However, the same proton beam when used to irradiate STO with a very thin layer of deposited Pt does not show any luminescence. This Pt layer prevents any damage which may otherwise be caused by arcing, which stems from the accumulated surface voltage of tens of kV due to the charge induced by secondary electrons on the surface of the insulator during the ion beam irradiation process. Hence, the luminescence of ion-irradiated STO originates from the modification of the STO surface layer caused by arcing rather than from any direct ion beam irradiation effect. STO treated with atmospheric-pressure plasma, a simple and cost-effective method, also exhibits the same type of blue and green mixed luminescence as STO treated with an ion beam, as the plasma also creates a layer of surface damage due to arcing.

Corrosion of Fe-9%Cr-1%Mo Steel at 600 and 700℃ in N2/(0.5, 2.5)%H2S-mixed Gas

  • Lee, Dong Bok;Abro, Muhammad Ali;Yadav, Poonam;Bak, Sang Hwan;Shi, Yuke;Kim, Min Jung
    • Journal of the Korean institute of surface engineering
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    • v.49 no.2
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    • pp.147-151
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    • 2016
  • The T91 steel (Fe-9%Cr-1%Mo) was corroded at 600 and $700^{\circ}C$ for 5 - 70 h in the $N_2$/(0.5, 2.5)%$H_2$Smixed gas at one atm. It was corroded fast, forming the outer FeS layer and the inner (FeS, $FeCr_2O_4$)-mixed layer. The formation of the outer FeS layer facilitated the oxidation of Cr to $FeCr_2O_4$ in the inner layer. Since the nonprotective FeS scale was present over the whole scale, T91 steel displayed poor corrosion resistance.

A Study on the Behaviors of Several Layers in a Solar Pond (태양연못안의 각 층의 거동에 관한 연구)

  • 박희용;임경빈
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.11 no.2
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    • pp.304-313
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    • 1987
  • The behaviors of layers developed in a solar pond were studied by experimental and analytical methods. An experimental solar pond heated from below was constructed and operated at the net heat fluxes of 110 and 160W/m$^{2}$ and at the initial salt concentration gradients of 18.2, 27.3 and 36.4%/m. The thicknesses, growth rates, temperature and salt concentration in the top and the bottom mixed layers, the diffusive layer and the upper and the lower interfacial boundary layers were measured. The shadowgraph technique was used in order to observe all layer formation and an electroconductivity-temperature probe consisting of four electrodes was fabricated and used in measuring the salt concentration. Based on the experimental results, a model for the solar pond was developed and the governing equation and the assumptions were established. The governing equations were solved by the numerical method. The calculated results obtained from the analysis were compared with the experimental results.

Characteristics of damaged layer in high speed end milling (고속 엔드밀 가공에서 가공변질층의 특성)

  • 김동은
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2000.04a
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    • pp.326-331
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    • 2000
  • In this study, residual stress was investigated experimentally to evaluate damaged layer in high-sped machining. In machining difficult-to-cut material, residual stress remaining in machined surface was mainly speared as compressive stress. The scale of this damaged layer depends upon cutting speed, feed per tooth and radial cutting depth. Damaged layer was measured by optical microscope. The micro-structure of damaged layer was a mixed maternsite and austenite. depth of damaged layer is increased with increasing of cutting temperature, cutting force and radial depth. On the other hand, that is slightly decreased with decreasing of cutting force. The increase of tool wear causes a shift of the maximum residual stress in machined surface layer.

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Characteristic of the Nocturnal Inversion Layer observed by Tethersonde in Daegu (계류기구로 관측한 대구시 야간 안정층 특성에 관한 사례연구)

  • 김희종;윤일희;권병혁;허만천
    • Journal of Environmental Science International
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    • v.11 no.3
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    • pp.155-160
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    • 2002
  • Using measured data at Daegu by tethersonde for the period of 1984∼1987, we have investigated the lower atmospheric boundary layer structure including relationships between inversion layer and meteorological factors(wind and temperature), and the inversion strength and inversion height. The inversion layer was defined from the vertical temperature profile and its strength was analyzed with the wind shear as well as the vertical temperature gradient. From October to January, measured inversion layer isn't destroyed, however, in June, after sun rise, it is destroyed by surface heating and mixed layer is developed from surface. According to Pasquill stability classes, the moderately stable cases dominated. It's the larger vertical temperature gradient the lower SBL height. We have introduced B(bulk turbulence scale) which indicated SBL height. It's larger B, the higher SBL height and vice versa. It was noted that the bulk turbulence scale (B) is appropriate to determine the stable boundary layer height.

Dioctahedral Chlorite-Smectite Mixed-Layer Minerals in the Sandstones of the Ulleung Basin, Offshore SE Korea (울릉분지 사암 내에 발달된 이팔면체 녹니석 - 스멕타이트 혼합층 광물)

  • Son Byeong-Kook
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.2
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    • pp.73-81
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    • 2005
  • Mineralogical and chemical examinations were performed on chlorite-smectite mixed layer minerals that occur in the sandstones from a petroleum exploration well in the southern part of the Ulleung Basin. X-ray diffraction and chemical analyses show that the chlorite-smectite mixed layer mineral is tosudite, a 1 : 1 R1 ordered interstratification of chlorite and smectite with an overall dioctahedral character. This mineral is almost the same as the tosudite reported from hydrothermally-altered regions, which is rich in Li. This fact indicates that the tosudite area may be affected by hydrothermal events, because the studied well is located in the tectonically-deformed area, in which lots of trust faults and folds are present. In these respects, the formation of tosudite is probably due to the variable effect of hydrothermal fluids from the deeper part of the area.

Hot Corrosion Properties of Heat Resistant Chrome Steels (내열강의 고온부식특성에 대한 크롬함량의 영향)

  • Lee, Han-sang;Jung, Jine-sung;Yoo, Keun-bong;Kim, Eui-hyun
    • Korean Journal of Metals and Materials
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    • v.48 no.4
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    • pp.277-288
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    • 2010
  • The hot corrosion properties of heat-resistant steels were investigated in an oxidation atmosphere including artificial ash and sulfur dioxide. The heat-resistant steels of T22, T92, T122, T347HFG, Super304H and HR3C were evaluated at 620, 670 and $720^{\circ}C$ for 400 hours. The relationship between the corrosion rate and the temperature followed a bell-shaped curve with a peak rate at around $670^{\circ}C$. The corrosion rates showed a decreasing tendency as the chrome contents of these steels increased from 2.15 wt.% to 24.5 wt.%, and austenitic steels had a lower corrosion rate than ferritic steels. Sulfidation by $SO_2$ as well as molten salt corrosion also had an effect on the total corrosion rate, especially showing an increase in the corrosion rate in ferritic steels. Regardless of the chrome content in the steels and irrespective of the test temperature, the corrosion scale was composed of an outer oxide and an artificial ash mixed layer, a middle oxide layer and inner sulfide, and a mixed oxide layer. As the chrome content increased, the proportion of chrome oxide in the corrosion scale increased. Before spalling of the corrosion scale, voids and cracks were initiated in the sulfide and the mixed oxide layer or at the interface with the substrate.