• 제목/요약/키워드: Mixed Heavy Metal

검색결과 211건 처리시간 0.022초

미처리하수지구 논에서의 수질 및 토양 특성 분석 (Analysis of Water Quality and Soil Environment in Paddy Fields Partially Irrigated with Untreated Wastewater)

  • 송정헌;정한석;박지훈;송인홍;강문성;박승우
    • 한국농공학회논문집
    • /
    • 제56권6호
    • /
    • pp.19-29
    • /
    • 2014
  • The objectives of this study were to monitor and analyse water quality and soil property in paddy fields where untreated wastewater is irrigated. Three paddy fields where streamflow mixed with untreated wastewater has been irrigated (untreated wastewater district, UWD) were selected for monitoring, and five paddy fields in Yongin area (Yongin district, YID) where water from Idong agricultural reservoir (well-managed) has been irrigated were selected for comparative evaluation. Electronic conductivity (EC), suspended solids (SS), total nitrogen (T-N), total phosphorous (T-P), $NO_3-N$, $Ca^{2+}$, $Mg^{2+}$, $Na^+$, total coliform (TC), fecal coliform (FC), and E. coli of the irrigation water in the UWD were significantly higher than those in the YID. Relatively high concentrations of EC, T-N, T-P, TC, FC, E. coli, copper (Cu), lead (Pb), zinc (Zn), and aluminium (Al) were shown in the irrigation water of the UWD especially during May to June. In general, the paddy soil in the UWD contained more Pb, Zn, and Cu than in the YID although the soil heavy metal contents in the UWD still meet the Korean soil contamination warning standards. No temporal trends in the heavy metal concentrations were found in paddy soils of the UWD. This study showed that the use of untreated wastewater to paddy fields has the possibility of negative impacts on water quality and soil, although long-term monitoring is needed to fully evaluate its effects.

생활폐기물 소각재를 이용하여 합성한 클링커의 중금속 및 수화반응 거동에 관한 연구 (A Study on the Behavior of Heavy Metal Ions and Hydration of Clinker Utilizing Municipal Solid Waste Incineration Ash)

  • 안지환;한기천;한기석
    • 자원리싸이클링
    • /
    • 제13권4호
    • /
    • pp.3-10
    • /
    • 2004
  • 생활폐기물 소각재(바닥재+비산재)를 이용하여 보통 포틀랜드 시멘트를 제조하고자 하였다. 주원료로는 석회석, 폐주물사, shale, 전로슬래그 및 fly ash를 이용하였으며, modulus를 LSF 91.0, SM 2.40, IM 1.80의 수준으로 배합하였다. 바닥재의 경우는 배합물에 1, 2, 3wt.%까지 첨가하였으며, 바닥재와 비산재의 혼합시료는 각각의 함량을 0.9 및 0.1 wt.%로 하여 첨가하였다. 클링커 분석결과 소성성 지수(B.I)는 소각재가 많이 첨가 될수록 낮아지는 것으로 나타났으며, calcium silicate 광물의 발달이 저하되는 것을 확인 할 수 있었다 또한, 압축강도 측정결과, 소각재 사용량이 증가함에 따라 강도가 저하되는 것으로 확인되었다.

Contrast Effect of Citric Acid and Ethylenediaminetetraacetic Acid on Cadmium Extractability in Arable Soil

  • Lee, Hyun Ho;Hong, Chang Oh
    • 한국토양비료학회지
    • /
    • 제48권6호
    • /
    • pp.634-640
    • /
    • 2015
  • Chelating agents have been proposed to improve the efficiency of phytoextraction of heavy metal hyperaccumulator. However, little studies to elucidate mechanism of chelating agents to increase cadmium (Cd) extractability have been conducted. The objectives of this study were to evaluate effect of different chelating agents on Cd extractability and to determine mechanism of Cd mobilization affected by these agents. An arable soil was spiked with inorganic Cd ($CdCl_2$) to give a total Cd concentration of $20mgCdkg^{-1}$. Ethylenediaminetetraacetic acid (EDTA) and citric acid (CA) were selected and mixed with the arable soil at the rates of 0 and $5mmolkg^{-1}$. The mixture soils were incubated at $25^{\circ}C$ for 4 weeks in dark condition. Concentration of F1 Cd fractions (water soluble) significantly increased with addition of EDTA but did not changed with addition of CA. Especially; concentration of F5 Cd fractions (residual) significantly increased with addition of CA. Increase in water soluble with EDTA might be attributed to complexation of Cd and EDTA. Dissolved organic carbon concentration significantly increased with EDTA addition, but did not with CA implying that considerable amount of CA was decomposed to inorganic carbon by microorganism. Log activity of carbonate ($CO_3{^{2-}}$) which might be generated from CA increased with addition of CA. Increase in residual Cd fraction might be due to precipitation of Cd as $CdCO_3$. As a result, EDTA was effective in increasing Cd extractability, by contrast CA had significant effect in reducing Cd extractability.

피스톤 크라운용 단강에 인코넬 718 용접재료로 용접된 용접부의 특성 평가 (Evaluation of Characteristics of Welding Zones Welded with Inconel 718 Filler Metal to Piston Crown Forged Material)

  • 이성열;문경만;정재현;이명훈;백태실
    • 한국해양공학회지
    • /
    • 제30권4호
    • /
    • pp.334-340
    • /
    • 2016
  • The combustion chamber of a diesel engine is often exposed to a more serious wear and corrosion environment than other parts of the engine because its temperature increases as a result of using heavy oil of low quality. Therefore, repair and built-up welding methods must be performed on worn or corroded parts of the piston crown, exhaust valve, etc. from an economical point of view. In this study, Inconel 718 filler metal was used in repair welding on the groove of a forged steel specimen for a piston crown, along with built-up welding on the surface of another forged steel specimen. Then, the corrosion characteristics of the weld metal zone for the repair welding and the deposited metal zone for the built-up welding were investigated using electrochemical methods in a 35% H2SO4 solution. The deposited metal zone indicated better corrosion resistance than the weld metal zone, showing a nobler corrosion potential, higher impedance, and smaller corrosion current density. It is considered that metal elements with good corrosion resistance were generally included in the filler metal, and these elements were also greatly involved in the deposited meta by built-up welding, whereas the weld metal consisted of metal elements mixed with both the filler metal and base metal elements because of the molten pool produced by the repair welding. Finally, it is considered that the hardness of the weld metal was increased by the repair welding, whereas the built-up welding improved the corrosion resistance of the deposited metal.

전기로제강분진(EAF Dust)을 혼화재로 배합한 콘크리트 공시체의 재료특성 (Material Properties of Concrete Specimens with Electric Arc Furnace Dust as Admixture)

  • 김장호;김석호;김성훈;김동완
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 2001년도 가을 학술발표회 논문집
    • /
    • pp.669-674
    • /
    • 2001
  • Electric Arc Furnace Dust (EAF Dust) Is residual dust produced during the manufacturing of metal products from heavily heated electric arc furnace. Many researches have focused on recycling and reusing EAF Dust for industrial and construction purposes. However, most of these researches were aimed at obtaining useful heavy metal powders by treating toxic metallic materials in EAF Dust. Also, few researches dealt with using EAF Dust as admixture in concrete mixture (i.e., slag dust). In this study, EAF Dust is used as admixture in concrete mixture content considering economical feasibility and construction applicability. The concrete specimens mixed with EAF Dust is then tested in compression and tension to study its strength and ductility as well as its failure mechanism. The compression and tension (by split cylinder test) test results are compared to the results from the specimens without EAF Dust to understand the chemical stability and mechanical characteristic of concrete specimens with EAF Dust. For the experiment, 6 types of admixture added concrete were studied: ⑴Combination of EAF Dust and blast-furnace slag in 1 to 1 ratio, ⑵Combination of EAF Dust and blast-furnace slag in 1 to 2 ratio, ⑶EAF Dust only, ⑷blast-furnace slag only, ⑸fly ash only, and ⑹no admixture. The experimental results show that the strength of EAF Dust added specimen has lower early age strength but higher 28 day strength when compared to other specimens. Also, the Elastic Modulus of EAF Dust is higher(28 days) than other specimens. The study results prove that EAF Dust can be used as an effective admixture in concrete for specific usages.

  • PDF

가변색온도 가로등 구현을 위한 혼색LED의 조명특성 (A Light Characteristics of Mixed-Color LED for the Variable Color Temperature Street Light)

  • 정병호;이강연;최연옥;김대곤;김남오;민완기
    • 전기학회논문지P
    • /
    • 제58권2호
    • /
    • pp.142-147
    • /
    • 2009
  • Conventional HP(high pressure) sodium or Metal-halide lamps have a life span of around one year requiring at least annual replacement and maintenance. High Power LED lights require no regular maintenance further increasing savings on replacement bulbs, access equipment and labour costs. New installations benefit from a substantial reduction in the cost of expensive heavy duty cable required for sodium lighting. Especially, LED light can achieve variable color temperature, high functional performance in the field of street light. There are two main method to achieve variable color temperature function of the street light. one method is using RGB multi-chip LED, the other is using Orange-White LED method. In this paper, it was compare RGB Multi-chip LED with white-orange LED for there characteristics performance.

Removal of Cochlodinium polykrikoides using a novel material produced from sediment - A field study

  • Song, Young-Chae;Sivakumar, S.;Ko, Sung-Chung;Hwang, Eung-Ju;Jo, Q-Tae
    • 한국항해항만학회:학술대회논문집
    • /
    • 한국항해항만학회 2007년도 추계학술대회 및 제23회 정기총회
    • /
    • pp.200-201
    • /
    • 2007
  • The present study was conducted in three fields at Namhae to examine the removal efficiency of organic free, heavy metal immobilized sediment on Cochlodinium polykrikoidesand and on sea water quality. The present study results concluded that removal efficiency was depends on the initial number of red tide cells. There was no drastic change in the sea water quality after sediment spray. For the comparison of effectiveness of betonite, zeolite and lime were mixed with sediment did not show any marked difference in removal. Finally, the present study evaluated 50g/$m^{2}$ sediment is sufficient to remove 100% cells density, even though various environmental factors are interfering the mechanism.

  • PDF

빈배합 시멘트 혼합점토의 압밀 특성 (Consolidation Behavior of Poor Mixed Soil-Cement)

  • 이종민;권영철;이흥길;이봉직
    • 한국지반환경공학회 논문집
    • /
    • 제11권4호
    • /
    • pp.25-31
    • /
    • 2010
  • 4대강 사업이나 항만의 지속적인 건설 및 관리 등으로 인해 준설점토의 발생량은 꾸준히 증가할 것이다. 이러한 준설점토를 매립재료 등으로 유효하게 재활용하기 위해 지반공학 관련 기술자들은 많은 노력을 기울여 왔다. 그러나 준설점토가 일반적으로 매우 높은 초기 함수비를 갖고 있으며 동시에 강도 역시 매우 낮은 점을 생각하면 준설된 점토의 처리를 위한 장비의 주행성 확보나 혹은 압밀을 위해 많은 시간이 필요하다는 등의 다양한 문제에 직면하게 된다. 최근까지 경제성과 효과면에서 탁월한 시멘트를 이용한 준설점토의 처리 등에 많은 연구 성과가 발표되고 혹은 현장에서 효과적인 처리공법으로 사용되고 있지만, 시멘트 자체가 지반 내에서 6가크롬이나 수은 등의 중금속을 유출하는 경우 환경 부하의 증가 뿐만 아니라 지하수를 통한 오염 확산 등에서 우려되는 점이 없지 않다. 따라서 가급적 시멘트 혼합비를 낮출 수 있는 방안에 대한 검토가 이루어져야 한다는 것이 저자들의 판단이며 이를 위해 빈배합 시멘트 혼합점토의 거동에 대해 연구를 수행하였다. 본 논문에서는 특히 압밀 특성에 초점을 맞추어 분석하였으며 연구 결과 압밀 침하량의 억제와 압밀속도의 증가가 동시에 나타나는 시멘트 고화제 혼합비 시작점은 4%~6% 정도인 것을 확인하였다.

폐수처리제(廢水處理劑)로서의 Zeolite의 이용(利用) (Utilization of Zeolite in Waste Water Treatment.)

  • 이전식;이정재;최정
    • 한국환경농학회지
    • /
    • 제6권2호
    • /
    • pp.46-52
    • /
    • 1987
  • 폐수중(廢水中) 중금속(重金屬)의 제거제(除去劑)로서 천연(天然) Zeolite의 이용(利用) 가능성(可能性)을 조사(調査)하기 위하여 활성탄(活性炭)을 대조(對照)로 하여 흡착실험(吸着實驗) 및 Column 투과실험(透過實驗)을 한 결과(結果)는 다음과 같았다. Freundlich 흡착상수(吸着常數) ${\frac{1}{n}$값이 $0.12{\sim}0.45$, K값 $18.77{\sim}59.48$인 것으로 보아 천연(天然) Zeolite는 활성탄(活性炭)보다 더 효과적(效果的)인 중금속(重金屬) 흡착제(吸着劑)였다. 동일(同一)한 입경(粒徑), 동일(同一)한 투과정도(透過程度)에 있어서 천연(天然) Zeolite는 활성탄(活性炭)보다 더 많은 양(量)의 중금속(重金屬)을 흡착(吸着)하였다. 입자(粒子)가 작을수록 흡착량(吸着量)은 증가(增加)하는 경향(傾向)이었으며 폐수중(廢水中) 중금속(重金屬) 흡착제吸(着劑)로서의 최적입경(最適粒徑)은 $0.5{\sim}2.0mm$ 화분(畵分)이었다. 중김속용액(重金屬溶液)의 Column 투과속도(透過速度)가 느릴수록 또 혼합용액(混合溶液)에서 보다 단일용액(單一溶液)에서 더 많은 량(量)의 중금속(重金屬)이 흡착(吸着)되었다. 혼합용액내(混合溶液內)에서 중금속(重金屬)의 흡착량(吸着量)은 Cu>Zn>Cd의 순(順)이었다.

  • PDF

포화된 사질토의 전기전도도에 중금속과 염분 농도가 미치는 영향 (Effects of Heavy Metal and Salinity on Electrical Conductivity in Fully Saturated Sand)

  • 이동수;홍영호;홍원택;채광석;이종섭
    • 한국지반환경공학회 논문집
    • /
    • 제18권10호
    • /
    • pp.23-34
    • /
    • 2017
  • 포화된 흙의 전기적인 특성은 흙 주위에 있는 간극수의 전기전도도에 크게 의존하므로, 흙의 전기전도도 변화를 이용하여 지반속으로의 오염물 침투를 감지하는데 널리 활용되고 있다. 본 연구의 목적은 포화시료에 대해 염분비와 납의 농도 변화에 따른 흙의 전기적 특성 변화를 조사하는 것이다. 전기저항과 시간영역반사법 신호측정을 위한 센서를 매설한 원통형 셀 내부에 담수 및 염분 농도 1%, 2% 그리고 3%의 염수용액을 0~10mg/L 사이의 6가지 납 표준용액과 혼합하여 수용액을 준비하였다. 이후 수용액 속에 건조시킨 모래시료를 수중강사법을 이용하여 조성하였다. 조성된 포화시료에 대해 셀 내부에 설치된 센서들로부터 전기저항과 시간영역반사법 신호를 측정하고 이 결과로부터 전기전도도를 산정하였다. 실험 결과, 주파수 1kHz에서 측정된 전기저항으로 부터 산정한 전기전도도는 납의 농도가 증가함에 따라 연속적으로 증가하는 것으로 나타났으므로 전기저항으로부터 산정한 전기전도도가 오염정도를 파악하기 위해 사용될 수 있는 것으로 나타났다. 또한 시간영역반사법으로부터 산정한 전기전도도의 경우 저농도에서의 납의 농도 변화에도 전기전도도가 변화하지만, 납의 농도가 증가함에 따라 변화 정도는 점차 감소하는 것으로 나타났다. 즉, 시간영역반사법은 중금속 누출여부를 조사하는데 적합한 것으로 평가되었다. 본 연구는 전기저항과 시간영역반사법의 상호보완적인 특성을 활용한다면 해안 및 해양환경에서도 중금속의 누출 및 오염을 감지할 수 있음을 보여준다.