• 제목/요약/키워드: Mixed Gas

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쇄석을 가스배관 채움재로 사용시 배관피복에 미치는 영향 연구 (Study on the damage effect to the Gas pipeline coating by the crashed stone backfill material)

  • 조성호;전경수;이선엽;조용범;고영태
    • 한국가스학회지
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    • 제2권1호
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    • pp.23-27
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    • 1998
  • 음극방식 시스템의 방식전류에 의한 압입구간내의 압입관과 배관의 부식거동에 관한 수학적 모델링을 경계요소법을 이용하여 수행하였다. 모델은 비선형 경계조건(Tafel 방정식)을 가진 라플라스 방정식으로 이루어져 있으며 압입관의 혼합전위를 구하기 위하여 혼합전위 이론을 응용한 반복법을 사용하였으며 그 위에 비선형 경계조건에 대한 해석을 위하여 이중 반복법을 사용하였다. 모델은 정상적인 압입구간 뿐만 아니라 압입관과 배관과의 금속간 접촉(metal touch)이나 외부환경과 압입구간 내부를 격리시키는 절연부위의 손상과 같은 결함들을 가진 비정상적인 압입구간에서의 각각의 경우에 대해서도 적용되었다. 수학적 모델링의 결과로부터 압입구간내의 전위분포나 전류분포를 계산할 수 있었다. 모델링의 타당성을 증명하기 위하여 모사실험을 수행하였으며 실험조건내에서 이론적인 결과와 실험결과는 정상적으로 잘 일치하였다.

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Flaring 가스의 $CO_2$ 분리를 위한 분리막 공정 기술개발 (Membrane Process Development for $CO_2$ Separation of Flaring Gas)

  • 김세종;김학은;조원준;하성용
    • 멤브레인
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    • 제23권5호
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    • pp.384-391
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    • 2013
  • DME 제조공정에서 발생하는 혼합가스 중, $CO_2$를 제거하기 위하여 폴리술폰 고분자를 이용하여 지지체 중공사막을 제조하고, Hyflon AD를 코팅하여 복합막을 제조하였다. 제조된 중공사막을 이용하여 Flaring 모사가스에 대한 모듈의 성능을 측정하였다. 분리막 1단 평가 결과 1.2 MPa에서 Stage cut 0.24 이상의 $CO_2$농도는 3% 이하이며, 동일조건에서 $CO_2$ 제거율 및 $CH_4$ 회수율은 각각 약 80%이다. 분리막 2단 평가결과 Product 가스의 $CO_2$ 농도를 5%로 고정하였을 때, stage cut 0.074에서 recycle 되는 $CO_2$ 농도는 공급가스와 같은 농도를 가지며, 이때 $CH_4$의 회수율은 약 99%이다.

이송식 아크플라즈마 장치에 의해 제조된 실리콘 나노분말의 특성에 대한 연구 (A Study on the Characteristics of Silicon Nanopowders Produced by Transferred Type Arc Plasma Apparatus)

  • 간우섭;박상희
    • 한국산업융합학회 논문집
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    • 제24권6_2호
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    • pp.909-917
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    • 2021
  • This study was carried out experimentally on the production and properties of silicon nanopowders characteristics using a transferred type arc plasma apparatus. To investigate the properties of silicon nanopowder, the purity of argon gas(99.999%, 99.9%) and the partial pressure ratio of nitrogen gas(0~90%) were varied. The total pressure in chamber is 400Torr and the silicon chunk amount used as raw material is 300g. The power supplied to the cathode to generate arc plasma was 9~12kW/h, and the electrode was made of tungsten and graphite with a diameter of 13mm. The particle size, impurity elements and powder evaporation rate of the silicon powder were analyzed using the XRD, FE-SEM, TEM and electronic scale. According to the purity of argon gas, the silicon evaporation rate and the particle size were similar, and impurities were generated more in the case of 99.9% purity than 99.999%. When argon gas and nitrogen gas were mixed in the chamber, the silicon evaporation rate and particle size increased as the partial pressure ratio of nitrogen gas increased. In particular, when the partial pressure ratio of nitrogen gas was 80%, the silicon evaporation rate 80g/h, and the particle size was about 80~100nm.

Ruminal microbial responses in fermentation characteristics and dry matter degradability to TDN level of total mixed ration

  • Lee, Seung-Uk;Jo, Jin-Ho;Park, Sung-Kwon;Choi, Chang-Weon;Jeong, Jun;Chung, Ki-Young;Chang, Sun-Sik;Li, Xiang Zi;Choi, Seong-Ho
    • 농업과학연구
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    • 제43권1호
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    • pp.80-86
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    • 2016
  • An in vitro trial was conducted to examine the effects of total mixed rations (TMR) on fermentation characteristics and effective degradability (ED) by rumen microbes. Three TMR diets were growing period TMR (GR-TMR, 67% TDN), early fattening period TMR (EF-TMR, 75.4% TDN) and late fattening TMR (LF-TMR, 80% TDN). Three TMR diets (3 g of TMRs in each incubation bottles) was added to the mixed culture solution of stained rumen fluid with artificial saliva (1:1, v/v) and incubated anaerobically for 48 hours at $39^{\circ}C$. The pH in all incubation solutions tended to decrease up to 48h, but the opposite results were found in concentration of total gas production, ammonia-N and total VFA in all incubations.The total gas production (p<0.05) in LF-TMR was highest compared with those of other diets. Also, concentration of total VFA was tended to increase in LF-TMR compared with other TMR diets in all incubations. The EDDM in both EF-TMR and LF-TMR was tended to high compared with GR-TMR (p=0.100). In this in vitro trials, concentration of propionate in all incubation solution was not affected by increased concentration of TDN. The results of the present in vitro study indicate that TMR may provide more favorable condition for nutrient digestion both in the rumen.

Substitution effects of rice for corn grain in total mixed ration on rumen fermentation characteristics and microbial community in vitro

  • Yoo, Daekyum;Hamid, Muhammad Mahboob Ali;Kim, Hanbeen;Moon, Joonbeom;Song, Jaeyong;Lee, Seyoung;Seo, Jakyeom
    • Journal of Animal Science and Technology
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    • 제62권5호
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    • pp.638-647
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    • 2020
  • This study determined the substitution effects of rice for corn as the main grain source in a total mixed ration (TMR). In vitro rumen fermentation characteristics and microbes were assessed using two experimental diets. Diets included 33% dry matter (DM) of either corn (Corn TMR) or rice grains (Rice TMR). In a 48-h in vitro incubation, DM digestibility (IVDMD), neutral detergent fiber degradability (IVNDFD), crude protein digestibility (IVCPD), volatile fatty acids (VFAs), pH and ammonia nitrogen (NH3-N) were estimated. Gas production has been calculated at 3, 6, 12, 24 and 48 h. Our results indicate that the gas production, VFAs, IVDMD, and IVNDFD of Rice TMR were higher than those of Corn TMR (p < 0.05). Ruminal pH and total fungi were significantly higher in Corn TMR (p < 0.05) than in Rice TMR; however, NH3-N and IVCPD were not affected by treatment type. In conclusion, substituting rice for corn at 33% DM in TMR appears to have no negative effects on in vitro rumen fermentation characteristics. Therefore, rice grains are an appropriate alternative energy source in early fattening stage diets of beef cattle.

AICoPd (1/1/0.05) 및 AICoFe (1/1/2)의 혼합금속산화물 촉매에 의한 NO, $N_2O$$O_2$의 흡탈착 특성 연구 (Adsorption-Desorption Characteristics of NO, $N_2O$ and $O_2$ over Mixed Oxide Catalysts of AlCoPd (1/1/0.05) and AlCoFe (1/1/2))

  • 한아름;황영애;장길상
    • 청정기술
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    • 제17권2호
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    • pp.142-149
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    • 2011
  • 혼합금속산화물인 AlCoPd (1/1/0.05) 및 AlCoFe (1/1/2) 촉매의 Lean $NO_x$ Trap (LNT) 적용을 위하여 NO 및 $N_2O$에 대한 흡착 및 탈착 특성을 살펴보았다. 이들은 NO 및 $N_2O$에 대해 산화 과정 없이도 NO를 잘 흡착하는 성능을 나타냈다. 산소가 공존하는 복합 성분의 흡착에서는 흡착량이 많이 떨어졌지만 NO의 경우 산소대비 높은 선택성과 흡착능을 유지한 반면 $N_2O$의 선택성과 흡착능은 급격히 떨어지는 양상을 나타냈다. 또한 TPD로 살펴본 탈착 특성에서는 고온 영역에서 NO 및 $N_2O$성분이 분해되며 생성된 산소 성분 등이 높은 온도에서도 촉매에 강하게 결합되어 있는 것으로 파악되었다.

확대촬영법 및 Mie 산란광법을 이용한 다성분연료의 분무구조에 관한 실험적 해명 (An Experimental Analysis on the Spray Structure of Multi-component Fuels Using Magnification Photograph and Mie Scattering Images)

  • 명광재;윤준규
    • Journal of Advanced Marine Engineering and Technology
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    • 제32권5호
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    • pp.707-716
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    • 2008
  • The objective of this study was to analyze the effect of mixed fuel composition and mass fraction on spray inner structure in evaporating transient spray under the variant ambient conditions. Spray structure and spatial distribution of liquid phase concentration were investigated using a thin laser sheet illumination technique on the three component mixed fuels. A pulsed Nd:YAG laser was used as a light source. The experiments were conducted in a constant volume vessel with optical access. Fuel was injected into the vessel with electronically controlled common rail injector. Used fuel contains i-octane($C_8H_{18}$), n-dodecane($C_{12}H_{26}$) and n-hexadecane($C_{16}H_{34}$) that were selected as low-, middle- and high-boiling point fuel, respectively. Experimental conditions are 42 MPa, 72 MPa and 112 MPa in injection pressure, $5\;kg/m^3$, $15kg/m^3$ and $30kg/m^3$ in ambient gas density, 300 K, 500 K, 600 K and 700 K in ambient gas temperature, 300 K and 368 K in fuel temperature and different fuel mass fraction. Experimental results indicated that the multi-component fuels made two phase region mixed vapor and liquid so that it would are helpful to improve combustion, for the fuels of high boiling point component could accelerate evaporation very much according as low boiling point fuel was added to high boiling point fuel.

국내 무연탄과 미분을 성형한 무연탄의 순환유동층 연소 (Circulating Fluidized Bed Combustion of Korean Anthracite and Fabricated Anthracite Fines)

  • 선도원;배달희;오창섭;김헌창
    • 공업화학
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    • 제21권5호
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    • pp.553-558
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    • 2010
  • 순환유동층에서 나타나는 국내 무연탄의 낮은 연소성을 극복하고 비산재로 배출되는 미연분의 손실을 극복하기 위하여 분탄과 비산회를 혼합하여 성형한 성형탄과 무연탄의 혼소를 0.1 MW급 순환유동층에서 수행하였다. 비교 시험에서 원탄 연소는 다량의 미분의 비산과 연소로 상부에서의 과열을 일으켰으나 조립탄 연소의 경우 미분을 제거하였으므로 일정한 온도에서 연소되었고 운전이 가장 안정적이었다. 조립탄과 원탄이 혼합된 석탄은 다소 운전이 불안하였으나 원탄만을 연소시킬 때보다는 안정적 연소가 가능하였다. 조립탄에 성형탄을 혼합한 경우 조립탄 연소의 경우와 같이 원활한 운전이 가능하였다. 본 연구는 상용 순환유동층 보일러에서 성형탄 혼소가 국내 무연탄의 연소성 개선에 도움이 됨을 보여 주었다.

깔짚에서 발생되는 가스와 휘발성지방산에 대한 황산알루미늄과 비교 시 혼합 홍삼박제제의 평가: 축산환경 경영관점에서 (Evaluation of Mixed Korean Red Ginseng Marc with Aluminum Sulfate on Gas Concentration and VFA in Poultry Litter in Comparison with Aluminum Sulfate: In Terms of Livestock and Environment Managements)

  • 최인학
    • 한국환경과학회지
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    • 제24권4호
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    • pp.549-554
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    • 2015
  • This study was conducted to determine the effects of mixed Korean red ginseng marc with aluminum sulfate on gas concentration and volatile fatty acid (VFA) in poultry litter during 4 weeks in terms of livestock and environment managements. A total of 240 broiler chicks were randomly allocated to four treatments in four replications and 15 birds per replicate. The four treatments was mixed to rice hull under each pen at 0, 10 g or 20 g red ginseng marc + 90g aluminum sulfate, and 100g aluminum sulfate per kg poultry litter (rice hulls). Carbon dioxide, methane, acetic acid, and propionic acids were measured weekly. The results that could be available include: First, during the experimental period, carbon dioxide emissions were not remarkably different among treatments. Second, no differences were observed among treatments in methane emissions at 2 weeks through 4 weeks, but at 1 week, the reduction in methane emissions was in following order: 100 g aluminum sulfate > 20 g red ginseng marc + 90 g aluminum sulfate > 10 g red ginseng marc + 90 g aluminum sulfate > control. Third, in spite of statistically differences, treatment with 10 g or 20 g red ginseng marc + 90g aluminum sulfate, and 100g aluminum sulfate reduced acetic acid and propionic acid as a function of time, except acetic acid in aluminum sulfate treatment at 2 and 4 weeks. In conclusion, the results indicated that like aluminum sulfate, using 10 g or 20 g red ginseng marc with aluminum sulfate was effective in decreasing methane and propionic acid released from poultry litter.

DME-LPG 순차 혼합시 저장탱크 내의 혼합특성 (Mixing Characteristics of Sequential Blending with DME and LPG in Mixing Drum)

  • 천석훈;김차환;신동우;김래현;이현찬;백영순
    • Korean Chemical Engineering Research
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    • 제50권3호
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    • pp.464-470
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    • 2012
  • DME 및 LPG 혼합연료에 대한 혼합도 분석 실험을 수행하였다. DME 20 wt%와 LPG(주성분 프로판) 80 wt%를 탱크에 순차적으로 주입하여 시간 경과에 따라 탱크의 각 측정부에서의 농도를 측정하였다. 먼저 DME가 주입되고 그 후에 프로판이 주입되면서 DME의 일부는 혼합이 되나 일부는 혼합이 되지 않고 밀도차에 의해서 탱크 하부로 가라앉게 되는 층상화 현상이 발생하였다. 1일 경과 시 약 0.2~0.3 wt%의 증가비율로 두 연료가 혼합되어 완전히 균일하게 되기까지 약 500시간 이상이 소요되었다. 또한 재순환 펌프를 가동하여 탱크 내 연료를 순환 시킨 후 혼합 연료의 성분을 측정한 실험에서는 DME와 프로판이 균일하게 혼합됨을 확인하였다.