• Title/Summary/Keyword: Minor elements

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Content of Heavy Metals in Coal Fly Ash from the Samcheonpo and the Seocheon Power Plant (삼천포와 서천 화력발전소에서 발생하는 석탄회중의 중금속 함량에 관한 연구)

  • Yoon, Chung-Han;Oh, Keun-Chang;Kim, Yong-Woong;Shin, Bang-Sup
    • Economic and Environmental Geology
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    • v.28 no.2
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    • pp.147-154
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    • 1995
  • Coal fly ashes collected from the Samcheonpo and the Seocheon Power Plants were analyzed for major and minor components and heavy metals such as As, Cd, Co, Cr, Cu, Ga, Hg, Mo, Ni, Pb, Sb, V and Zn in order to suggest basic data to apply coal fly ash as fertilizer or soil ameliorator. The specific gravity of the samples was less than 2.0, and amounts of organic matter range from 5.0% to 12.3%. The identified minerals by XRD were mainly quartz, mullite and pyrite in anthracite coal, and mainly quartz and mullite in bituminous coal. Generally, the contents of heavy metal elements analyzed were lower less than those of soil, though higher in some samples. Element couples of some elements( e.g., As-Mo, Zn ; Mo-As, Sb, V, Zn ; Sb-Zn ) show positive correlations with each other, but the high correlations of toxic elements such as As, Pb, Cd and Hg indicate to give attention to apply coal fly ash as fertilizer or soil ameliorator.

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Chemical Analysis of Fly Ashes from Municipal Solid Waste Incinerators (생활폐기물 처리시설 배출 비산재의 조성분석)

  • Jang, Seong-Ki;Choi, Duk-Il;Lim, Chang-Ho;Lee, Jin-Sook
    • Analytical Science and Technology
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    • v.13 no.2
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    • pp.215-221
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    • 2000
  • Analysis of fly ashes from the MSW incinerators was carried out using XRF, ICP-MS and ICP-AES. It was found that the major elements of fly ash were Ca, K, Na, Si, Al, S, Cl and O by the XRF analysis. The XRD spectra showed that the fly ashes were mainly consisted with the chlorides, hydroxides, carbonates and also oxides of former elements. For the determination of minor elements such as Zn, Pb, Cu, Cr, and Cd, we used ICP-AES and ICP-MS after microwave digestion and the results were compared with the result of XRF.

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Metal Fuel Development and Verification for Prototype Generation IV Sodium-Cooled Fast Reactor

  • Lee, Chan Bock;Cheon, Jin Sik;Kim, Sung Ho;Park, Jeong-Yong;Joo, Hyung-Kook
    • Nuclear Engineering and Technology
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    • v.48 no.5
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    • pp.1096-1108
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    • 2016
  • Metal fuel is being developed for the prototype generation-IV sodium-cooled fast reactor (PGSFR) to be built by 2028. U-Zr fuel is a driver for the initial core of the PGSFR, and U-transuranics (TRU)-Zr fuel will gradually replace U-Zr fuel through its qualification in the PGSFR. Based on the vast worldwide experiences of U-Zr fuel, work on U-Zr fuel is focused on fuel design, fabrication of fuel components, and fuel verification tests. U-TRU-Zr fuel uses TRU recovered through pyroelectrochemical processing of spent PWR (pressurized water reactor) fuels, which contains highly radioactive minor actinides and chemically active lanthanide or rare earth elements as carryover impurities. An advanced fuel slug casting system, which can prevent vaporization of volatile elements through a control of the atmospheric pressure of the casting chamber and also deal with chemically active lanthanide elements using protective coatings in the casting crucible, was developed. Fuel cladding of the ferritic-martensitic steel FC92, which has higher mechanical strength at a high temperature than conventional HT9 cladding, was developed and fabricated, and is being irradiated in the fast reactor.

Analysis of Trace Elements in Mud Flat with Neutron Activation Analysis (NAA) and Atomic Spectroscopy (중성자 방사화 분석법과 원자 분광법을 이용한 갯벌 시료 중 미량원소 분석법에 관한 연구)

  • Nam, Sang-Ho;Kim, Min-Jae;Chung, Yong-Sam;Kim, Sun-Ha
    • Analytical Science and Technology
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    • v.15 no.6
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    • pp.521-528
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    • 2002
  • Neutron Activation Analysis (NAA) and Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES) have been applied for the determination of inorganic elements in mud flat of south seaside in Korea. The analytical results of Al, Ca, Fe, Mg, K and Na by NAA were compared with those by ICP-AES. The results show that NAA is superior to ICP-AES for the determination of minor elements in sediment. Accordingly, NAA will play an important role in the analysis of environment samples such as mud flat and sediment having complex matrix.

Social Capital in Mangrove Management: A Case Study in Lampung Province, Indonesia

  • Qurniati, Rommy;Hidayat, Wahyu;Kaskoyo, Hari;Firdasari, Firdasari;Inoue, Makoto
    • Journal of Forest and Environmental Science
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    • v.33 no.1
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    • pp.8-21
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    • 2017
  • The objective of this study is to identify the individual characteristics and the elements of social capital hence a suitable design of social capital reinforcement can be proposed to promote a sustainable community-based mangrove management. The research conducted in three villages that were selected based on mangrove ecological differences in Lampung Province, Indonesia. Qualitative data was collected through field observation and in-depth interviews with key informants. The results showed that the population in the three villages dominated on productive ages, worked as farmers, and less educated (only a half of the population had fulfilled the basic education standard of Indonesia). The study results also indicated that the social capital in the communities showed minimum condition of interpersonal attachment and cooperation. This condition was derived from the attitude of the people who only took personal benefit without concerning to others' welfare. Many programs conducted by government to ensure the conservation of mangroves were project-oriented with minor participation of community. The minor participation might also contributed to the minimum of social capital in the community. To improve social capital, the communities should strengthen mutual trust based on mutual benefit to increase members' participation in mangrove activity.

Microstructural Change and Magnetic Properties of Nanocrystalline Fe-Si-B-Nb-Cu Based Alloys Containing Minor Elements

  • Nam, Seul-Ki;Moon, Sun-Gyu;Sohn, Keun Yong;Park, Won-Wook
    • Journal of Magnetics
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    • v.19 no.4
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    • pp.327-332
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    • 2014
  • The effect of minor element additions (Ca, Al) on microstructural change and magnetic properties of Fe-Nb-Cu-Si-B alloy has been investigated, in this paper. The Fe-Si-B-Nb-Cu(-Ca-Al) alloys were prepared by arc melting in argon gas atmosphere. The alloy ribbons were fabricated by melt-spinning, and heat-treated under a nitrogen atmosphere at $520-570^{\circ}C$ for 1 h. The soft magnetic properties of the ribbon core were analyzed using the AC B-H meter. A differential scanning calorimetry (DSC) was used to examine the crystallization behavior of the amorphous alloy ribbon. The microstructure was observed by X-ray diffraction (XRD), transmission electron microscope (TEM) and scanning electron microscope (SEM). The addition of Ca increased the electrical resistivity to reduce the eddy current loss. And the addition of Al decreased the intrinsic magnetocrystalline anisotropy $K_1$ resulting in the increased permeability. The reduction in the size of the ${\alpha}$-Fe precipitates was observed in the alloys containing of Ca and Al. Based on the results, it can be concluded that the additions of Ca and Al notably improved the soft magnetic properties such as permeability, coercivity and core loss in the Fe-Nb-Cu-Si-B base nanocrystalline alloys.

Non-contact Measurement and Analysis of Surface Hardness on Welding Steel using Laser-induced Breakdown Spectroscopy (레이저 유도 플라즈마 분광 기법을 이용한 용접 연강에서의 비접촉 강도 측정과 해석)

  • Kim, Joohan;Ko, Chansol
    • Journal of the Korean Society for Precision Engineering
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    • v.31 no.2
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    • pp.141-148
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    • 2014
  • In this work, effects of plasma on different hardness of welding steel using laser-induced breakdown spectroscopy were investigated. The ratios of ionic to atomic spectrum peaks were related to its material hardness. The major spectrum peak (Fe) and minor spectrum peak (Mn) were considered as monitoring elements. The stronger repulse plasma was generated, the harder material it was. The ratios of ionic to atomic spectrum peaks increased with respect to the material hardness as well. The correlation of minor spectrum peaks was stronger than that of major spectrum peaks. However, the major spectrum peaks indicated a similar trend, which could be used to estimate the hardness, too. Based on this result, the method could be used as a non-contact remote measurement of material properties.

Effect of Minor Additives on Casting Properties of AC4A Aluminum Casting Alloys (AC4A 알루미늄 합금의 주조특성에 미치는 미량 첨가원소의 영향)

  • Oh, Seung-Hwan;Kim, Heon-Joo
    • Journal of Korea Foundry Society
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    • v.37 no.5
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    • pp.148-156
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    • 2017
  • The effects of minor additives on the casting properties of AC4A aluminum alloys were investigated. Measurements of the cooling curve and microstructure observations were conducted to analyze the effects of Ti-B and Sr minor elements during the solidification process. A fine grain size and an increase in the crystallization temperature for the ${\alpha}-Al$ solution were evident after the addition of 0.1wt% Al-5%Ti-1%B additive. The modification effect of the eutectic $Mg_2Si$ phase with the addition of 0.05% Al-10%Sr additive was prominent. A fine eutectic $Mg_2Si$ phase and a decrease in the growth temperature of the eutectic $Mg_2Si$ phase were evident. Fluidity, shrinkage and solidification-cracking tests were conducted to evaluate the castability of the alloy. The combined addition of Al-5%Ti-1%B and Al-10%Sr additives showed the maximum filling length owing to the effect of the fine ${\alpha}-Al$ grains. The macro-shrinkage ratio increased, while the micro-shrinkage ratio decreased with the combined addition of Al-5%Ti-1%B and Al-10%Sr additives. The macro-shrinkage ratio was nearly identical, while the micro-shrinkage ratio increased with the addition of the Al-10%Sr additive. The tendency of the occurrence of solidification cracking decreased owing to the effect of the fine ${\alpha}-Al$ grains and the modification of the $Mg_2Si$ phase with the combined addition of Al-5%Ti-1%B and Al-10%Sr additives.

Geochemical Study on the Mobility of Dissolved Elements by Rocks-$CO_2$-rich waters Interaction in the Kangwon Province (강원도 지역 탄산수와 암석간의 반응에 의한 용존 원소들의 유동성에 관한 지구화학적 연구)

  • 최현수;고용권;윤성택;김천수
    • Economic and Environmental Geology
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    • v.35 no.6
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    • pp.533-544
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    • 2002
  • In order to investigate the relative mobility (RM) of dissolved elements during processes controlling major and trace element content, the concentrations of major, minor and trace elements were reviewed from the previous data of $CO_2$-rich waters and granites from Kangwon Province. The relative mobility of elements dissolved in $CO_2$-rich waters is calculated from $CO_2$-rich water/granite ratio with normalizing by sodium. The results show that gaseous input of magmatic volatile metals into the aquifer is negligible in this study area, being limited by cooling of the rising fluids. Granite leaching by weakly acidic, $CO_2$-charged water is the overwhelming source of metals. Poorly mobile element (Al) is preferentially retained in the solid residue of weathering, while alkalis, alkaline earth and oxo-hydroxo anion forming elements (especially As and U) are mobile and released to the aqueous system. Transition metals display an intermediate behavior and are strongly dependent on either the redox conditions (Fe and Mn) or solid surface-related processes (adsorption or precipitation) (V, Zn and Cu).

A proton induced X-ray emission (PIXE) analysis of concentration of major/trace and toxic elements in broiler gizzard and flesh of Tehsil Gujar Khan area in Pakistan

  • Nadeem, Khawar;Hussain, Javaid;Haq, Noaman Ul;Haq, A. Ul;Akram, Waheed;Ahmad, Ishaq
    • Nuclear Engineering and Technology
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    • v.51 no.8
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    • pp.2042-2049
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    • 2019
  • Ten gizzard and three flesh samples of the broiler were collected from different locations in Tehsil Gujar Khan District Rawalpindi, Pakistan. The samples were dried, crushed and ground. Pellets were prepared by pressing the powder of the samples and that of the Bovine liver 1577c reference material obtained from NIST, USA. Proton induced X-ray emission (PIXE) installed at National Center for Physics, Islamabad, Pakistan has been used as a reliable and improved technique to determine concentration of various major/trace and toxic elements e.g. S, Cl, K, Ca, Cl, Fe, Cu, Mn, Co, Zn, Ti, Cd, Ga, Cr, V and Ni, in the Gizzard and Flesh samples of the broiler. The concentrations of all the detected elements in the samples are statistically significant. The certified and measured values of the elements in the reference material were in agreement with each other within a deviation of 7%. S, Cl, K and Ca are within tolerable limits and are good for human consumption. Ti, V, Cr, Mn, Fe, Co, Ni, Cu and Zn were more than the acceptable limits of World Health Organization, WHO whereas Ga, As, Sn, Sb and Pb are not detected in most of the samples.