Economic and Environmental Geology (자원환경지질)

The Korean Society of Economic and Environmental Geology (대한자원환경지질학회)
권호 표지

Geochemical Study on the Mobility of Dissolved Elements by Rocks-$CO_2$-rich waters Interaction in the Kangwon Province

강원도 지역 탄산수와 암석간의 반응에 의한 용존 원소들의 유동성에 관한 지구화학적 연구

  • Published : 2002.12.01
Download PDF
⟨ Previous Next ⟩

Abstract

In order to investigate the relative mobility (RM) of dissolved elements during processes controlling major and trace element content, the concentrations of major, minor and trace elements were reviewed from the previous data of $CO_2$-rich waters and granites from Kangwon Province. The relative mobility of elements dissolved in $CO_2$-rich waters is calculated from $CO_2$-rich water/granite ratio with normalizing by sodium. The results show that gaseous input of magmatic volatile metals into the aquifer is negligible in this study area, being limited by cooling of the rising fluids. Granite leaching by weakly acidic, $CO_2$-charged water is the overwhelming source of metals. Poorly mobile element (Al) is preferentially retained in the solid residue of weathering, while alkalis, alkaline earth and oxo-hydroxo anion forming elements (especially As and U) are mobile and released to the aqueous system. Transition metals display an intermediate behavior and are strongly dependent on either the redox conditions (Fe and Mn) or solid surface-related processes (adsorption or precipitation) (V, Zn and Cu).

주요 및 미량원소들의 함량을 조절하는 반응들 동안 용존 원소들의 상대적인 유동성을 알아보기 기존에 발표된 강원도 지역 탄산수와 화강암에 대한 자료로부터 주·부·미량원소의 함량을 다시 살펴보았다. 탄산수내에 용존되어 있는 원소들의 상대적인 유동성은 Na으로 평균화한 탄산수-화강암간의 비로부터 계산하였다 계산결과는 탄산수 대수층내로 마그마에서 기원한 휘발성을 지닌 금속원소들의 가스에 의한 유입은 강원도 지역에서 무시할 만하며, 이런 유입은 상승하는 유체의 냉각에 의해 조절된다 이산화탄소가 유입된 약산성의 물에 의한 화강암의 용해반응이 금속원소들의 주요 공급원이다 유동성이 매우 낮은 원소 (Al)는 고체의 풍화산물 내에 우선적으로 잔류하는 반면, 알칼리 및 알칼리 토금속들과 OHA원소들 중 As과 U은 유동성이 있으며, 따라서 수용액계 내로 방출된다. 전이금속원소들은 중간정도의 유동특성을 보이는데, Fe와 Mn은 산화환원조건 또는 V, Zn과 Cu는 고체표면과 연관된 반응(흡착이나 침전)의해 주로 영향을 받는다.

Keywords

References

  1. 지하수환경 v.6 초정지역 탄산수의 지구화학적연구 Ⅰ. 수리화학. 고용권;김천수;배대석;김건영;정형재
  2. 지하수환경 v.6 초정지역 탄산수의 지구화학적 연구 Ⅱ. 동위원소 고용권;김천수;배대석;최현수
  3. 자원환경지질 v.33 문경지역 심부지 하수의 수리화학 및 환경동위원소 연구 고용권;김천수;배대석;이동익
  4. 지하수환경 v.7 강원도 지역 탄산약수의 지화학적 연구 고용권;김천수;최현수;박맹언;배대석
  5. 자원환경지질 v.32 중원지역 탄산수의 지구화학적 진화 고용권;윤성택;김천수;최현수;김건영
  6. 자원환경지질 v.34 경상지역 신촌 탄산약수의 지화학적 및 동위원소 특성 김건영;고용권;배대석;김천수;박맹언
  7. 자원환경지질 v.33 강원도 지역 탄산수의 환경동위원소적 특성 최현수;고용권;김천수;배대석;윤성택
  8. Proc. of the 9th Internat. Symp. on Water Rock Interaction, Taupo, New Zealand, 30 March-3 April 1998 Trace element hydrogeochemistry of Mt. Etna, Sicily: insight on water-rock interaction Aiuppa, A.;Allard, P.;D'Alessandro, W.;Michel, A.;Parallo, F.;Treuil, M.;Arehart(ed.);Hulston(ed.)
  9. Geochim. Cosmochim. Acta v.64 Mobility and fluxes of major, minor and trace metals during basalt weathering and groundwater transport at Mt. Etna volcano (Sicily) Aiuppa, A.;Allard, P.;D'Alessandro, W.;Michel, A.;Parello, F.;Treuil, M.;Valenza, M. https://doi.org/10.1016/S0016-7037(00)00345-8
  10. J. Volcanol. Geotherm. Res. v.98 Trace elements in the thermal groundwaters of Vulcano Island (Sicily) Aiuppa, A.;Dongarr, G.;Capasso, G.;Allard, P.
  11. Geol. Rundsch. v.82 Sulphur dioxide, paricle and elemental emissions from Mount Etna, Italy during July 1987 Andres, R.;Kyle, P.R.;Chuan, R.L.
  12. Hydrolysis of cations Baes, C.F.;Mesmer, R.E.
  13. Global environment: Water, air and geochemical cycle Barner, E.K;Berner, R.A.
  14. J. Volcanol. Geotherm. Res. v.108 Geochemical mapping of magmatic gas-water-rock interactions in the aquifer of Mount Etna volcano Brusca, L.;Aiuppa, A. https://doi.org/10.1016/S0377-0273(00)00286-9
  15. Geophys. Res. Lett. v.5 The heavy metal chemistry of atmospheric particulate matter emitted by Mount Etna volcano Buat-M nard, P.;Arnold, M. https://doi.org/10.1029/GL005i004p00245
  16. J. Royal Society of New Zealand v.10 The chemical and mineralogical changes accompanying the laterization of basalt at Kerikeri, North Auckland Carr, R.G.;Rodgers, K.A.;Black, P.M. https://doi.org/10.1080/03036758.1980.10415331
  17. Geochim. Cosmochim. Acta v.61 The weathering of basalt and relative mobilities of the major elements at Belbex, France Chesworth, W.;Dejou, J.;Larroque, P.
  18. The geochemistry of a natural waters: surface and groundwater environments(3rd ed.) Drever, J.I.
  19. Evolution of sedimentary rocks Garrels, R.M.;Mackenzie, F.T.
  20. J. Volcanol. Geotherm. Res. v.81 Variability of alkali and heavy metal fluxes released by Mt. Etna volcano, Sicily, between 1991 and 1995 Gauthier, P.L.;Le Cloarec, M.F. https://doi.org/10.1016/S0377-0273(98)00002-X
  21. Geochim. Cosmochim. Acta v.51 Meteoric waterbasalt interactions. Ⅱ: A field study in NE Iceland Gislason, S.R.;Eugster, H.P. https://doi.org/10.1016/0016-7037(87)90162-1
  22. Am. J. Sci. v.296 Chemical weathering of basalt as deduced from the composition of precipitation, rivers and rocks in SW Iceland Gislason, S.R.;Arnorsson, S.;Armannsson, H. https://doi.org/10.2475/ajs.296.8.837
  23. Geochim. Cosmochim. Acta v.49 Adsorption of uranyl onto ferric oxyhydroxides: application of the surface complexation site-binding model Hsi, C.D.;Langmuir, D. https://doi.org/10.1016/0016-7037(85)90088-2
  24. Geochim. Cosmochim. Acta v.50 Heavy metals adsorption by sulphide minerals surfaces Jean, G.E.;Bancroft, M. https://doi.org/10.1016/0016-7037(86)90319-4
  25. Geochim. Cosmochim. Acta v.42 Uranium solution-mineral equilibria at low temperatures with application to sedimentary ore deposits Langmuir, D. https://doi.org/10.1016/0016-7037(78)90001-7
  26. Geochim. Cosmochim. Acta v.39 The interaction of metal ions at manganse dioxides-solution interface Murray, J.W. https://doi.org/10.1016/0016-7037(75)90103-9
  27. Am. J. Sci. v.292 Recent chemical weathering of basalt Nesbitt, H.W.;Wilson, R.E. https://doi.org/10.2475/ajs.292.10.740
  28. Water Res. v.16 Adsorption of arsenite and arsenate on amorphous iron hydroxide Pierce, M.L.;Moore, C.B. https://doi.org/10.1016/0043-1354(82)90143-9
  29. Geochim. Cosmochim. Acta v.53 The adsorption of thio gold(I) Complexes by amorphous As2S3 and Sb2S3 at 25 and 90 Renders, P.J.;Seward, T.M. https://doi.org/10.1016/0016-7037(89)90378-5
  30. Geochim. Cosmochim. Acta v.56 Origin, speciation and fluxes of trace-element gases at Augustine Volcano, Alaska: Insights into magma degassing and fumarolic processes Symonds, R.B.;Reed, M.K.;Rose, W.I. https://doi.org/10.1016/0016-7037(92)90087-Y
  31. Aquatic chemistry: Chemical equilibria and rates in natural waters(3rd ed.) Stumm, W.;Morgan, J.J.
  32. Geochim. Cosmochim. Acta v.53 Vanadyl in natural waters: Adsorption and hydrolysis promote oxygenation Wehrli, B.;Stumm, W. https://doi.org/10.1016/0016-7037(89)90273-1
  33. Geochim. Cosmochim. Acta v.47 Surface chemistry and dissolution kinetic of glassy rocks White, A.F. https://doi.org/10.1016/0016-7037(83)90114-X
  34. Geochim. Cosmochim. Acta v.130 Stability relations of antimony and arsenic compounds in the light of revised and extended Eh-pH diagrams Vink, B.W.