• Title/Summary/Keyword: Mineral Oil

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Exposures to Oil Mist by Metal Machining Shop Workers and Analysis of Some Oils (일부 절삭유 제조 및 취급 사업장의 오일 미스트의 노출농도 및 성분에 관한 연구)

  • 정동인;변상훈;박승현;오세민;문영한
    • Journal of environmental and Sanitary engineering
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    • v.13 no.3
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    • pp.121-127
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    • 1998
  • This study investigated exposures to oil mist obtained from an cutting oil manufacture shop and 5 machining shops and also analysis of some oils. The results were that geometric average concentrations of oil mist were $0.29 mg/m^3$, which was less than current $TLV(5mg/m^3$) in Korea. The proper case of either type of system will ensure that atmospheric concentrations of oil mist in machine shops will be within the TLV. It should be remembered, however, that this TLV was established before there was any suggestion that in the inhalable of oil mist might rarely be carcinogenic, and so it seems prudent to keep atmospheric content as low as possible. The analysis of insoluble cutting oils with GC-MSD showed that considerable suspected PAHs were contained. But soluble cutting oil(KSM-W2) didn't almost contain PAHs.

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Chemical reconstruction of Castor Oil --Research of Environmentally Friendly Lubricants

  • Tao, De-Hua;Ye, Bin
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.339-340
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    • 2002
  • Natural castor oil was chemically reconstructed to extend the carbon chains by means of iso-reaction so as to improve the rheological behavior, by way of increasing the viscosity index and decreasing the pour point. The rheological and tribological characteristics of the reconstructed castor oil were comparatively investigated with those of the natural castor oil and several other vegetable oils and a mineral oil. The friction and wear test results on a four-ball machine indicate that the chemically reconstructed castor oil has considerably improved rheological and tribological properties as compared with the natural castor oil. It shows a greatly increase viscosity index and largely decreased pour point, which makes it applicable to low temperature lubrication. The chemically reconstructed castor oil even shows better tribological behavior than pentaerythritol ester or di-iso-capryl sebacate. However, it is still needed to increase the oxidation stability of the reconstructed castor oil.

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Grease Life and Degradation Characteristics in Rolling Bearing Lubrication (특성별 그리이스의 수명과 열화특성 연구)

  • 김상근;박창남;한종대
    • Tribology and Lubricants
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    • v.19 no.5
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    • pp.280-284
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    • 2003
  • High performance characteristics are required for rolling bearings and the various functions of bearing are greatly influenced by grease. Recently, higher performance is being demanded of rolling bearing greases for bearing lubrication. Four special greases with different composition such as lithium soap/ester oil, urea/ester oil, urea/ether oil and PTFE/fluorine oil were synthesized to compare the performance of these greases with that of the conventional lithium soap/mineral oil grease. The grease properties were investigated using a series of typical grease testing methods and grease life test. After the life test, the greases were charaterized by FTIR analysis and a microscope. And the iron amount in the greases was analyzed by AAS after ashing. The composition and manufacturing process determined the grease performance. The grease with a base oil of synthetic oil showed higher performance and the urea/ester oil and PTFE/fluorine oil showed about three times longer life as compared with conventional lithium grease.

Grease Life and Degradation Characteristics in Rolling Bearing Lubrication (특성별 그리이스의 수명과 열화특성 연구)

  • 김상근;박창남;한종대
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2001.11a
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    • pp.179-185
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    • 2001
  • High performance characteristics are required for rolling bearings and the various functions of bearing are greatly influenced by grease. Recently, higher performance is being demanded of rolling bearing greases for bearing lubrication. Four special greases with different composition such as lithium soap/ester oil, urea/ester oil, urea/ether oil and PTFE/fluorine oil were synthesized to compare the performance of these greases with that of the conventional lithium soap/mineral oil grease. The grease properties were investigated using a series of typical grease testing methods and grease life test. After the life test, the greases were charaterized by FTIR analysis and a microscope. And the iron amount in the greases was analyzed by AAS after ashing. The composition and manufacturing process determined the grease performance. The grease with a base oil of synthetic oil showed higher performance and the urea/ester oil and PTFE/fluorine oil showed about three times longer life as compared with conventional lithium grease.

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Apparatus for Monitoring Oil Oxidation Using a Plurality of UV Fluorescence Light-reflecting Members (복수 경로를 지닌 자외선 형광측정기를 이용한 오일 산화도 측정장치)

  • Kong, H.;Han, H.G.;Markava, L.V.
    • Tribology and Lubricants
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    • v.26 no.3
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    • pp.167-174
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    • 2010
  • An apparatus for measuring oil oxidation was developed, which is capable of being mounted to mechanical devices for detecting power of fluorescent light reflected from oil in real time as an indication of the oil oxidation. This device has an advantage over conventional fluorescence spectrometers where the thin film is required for the measurement. Clean and used oil samples (mineral and synthetic oils) were tested by the developed apparatus that calculates a fluorescence quantum yield and a light absorption coefficient of the oil based upon the signals from the two light-receiving members and evaluates the degree of oil oxidation of test oils based on the fluorescence quantum yield. Results generally show that the developed device is able to effectively evaluate oil oxidation characteristics on-site in the field.

Stratigraphy and Petroleum Geochemical Characteristics of Jiaolai Basin in Shandong Province of China (중국 교래분지의 층서와 석유지화학적 특성)

  • Cheong, Tae-Jin;Oh, Jae-Ho;Lee, Young-Joo;Kim, Ji-Hoon
    • The Korean Journal of Petroleum Geology
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    • v.12 no.1
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    • pp.1-8
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    • 2006
  • Jiaolai Basin is the Cretaceous continental sedimentary basin developed in Shandong Province of China. It is interpreted as a pull-apart basin which is filled with fluvio-lacustrine sediments and volcanic rocks. The sedimentary strata are divided into three formations: Laiyang Formation, Qingshan Formation and Wangshi Formation in ascending order. Laiyang Formation of the early Cretaceous consists of conglomerate, sandstone and shale, which are grey, black or red in color, respectively. Qingshan Formation of early Cretaceous includes various kinds of volcanic rocks. Late Cretaceous Wangshi Formation consists of red conglomerate, sandstone and shale. Various types of oil shows are observed on many outcrops in the basin such as asphalt filing fissures, oil smelling, rocks wetted with oil. However, commercial oil discovery was not made. Laiyang Formation is the richest in terms of organic matter contents. Some grey or black shales of Laiyang Formation contain more than 1% of organic matter. Kerogens of some layers mainly consist of amorphous organic matter or pollen. Thermal maturity of the organic matter reached main oil generation zone and hydrocarbon genetic potential is fairly good. According to such geochemical data, some layers of Laiyang Formation can act as hydrocarbon source rocks.

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Development of an Environmental Friend Pellet Coating Oil for Replacement of Antibiotics for Ruminant Aninmal (천연물질을 이용한 반추동물 항생제 대체용 친환경 펠렛코팅오일의 개발)

  • Choi, Bitna;Song, Wan-Sun;Choo, Byung Kil;Cho, Sangbuem;Ham, Young-Joo;Kim, Nam Hyung;Yang, Kyoung Hee;Kim, Young Jun;Lee, Hong-Gu;Choi, Nag-Jin
    • Korean Journal of Organic Agriculture
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    • v.23 no.2
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    • pp.373-390
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    • 2015
  • This study investigated the effect of coated feed using mixed oil on rumen fermentation characteristics. Two experiments were conducted based on materials that were mixed. First, cashew nut and soybean oils were mixed with white mineral oil. And second, different plant extracts were mixed with white mineral oil. At first experiment, inclusion levels of mixed oil on diet (0.03%, 0.1%, 0.5%) were applied as variables. A coated diet was fermented with rumen inoculum according to in vitro rumen fermentation and its parameters were investigated. In the result of first experiment, no negative effects on rumen pH were found. Significantly decreased dry matter digestibility was detected at 0.5% treatment (P<0.05). Total gas productions in control and 0.03% were significantly greater than those of others (P<0.05). Significantly reduced methane productions were found in all treatments compared to the control (P<0.05). Inclusion of mixed oil did not affect on ammonia production. Total volatile fatty acid production was also not influenced by coating with mixed oils. Rumen fermentation parameters were greatly changed according to introduced plant extracts at second experiment. The significantly lowest and greatest ammonia productions were found at treatments with Ixeris dentata and Plantago asiatica, respectively (P<0.05). The significantly greatest acetate and propionate productions were detected at treatments with Crucuma longa and Zizyphus vulgaris 1, respectively (P<0.05). All treatments, except Chrysanthemum idicum, Euyale ferox seed, Moringa leaf and fruit and Zizyphus vulgaris 1, showed significantly increased total volatile fatty acid production compared to the control (P<0.05). Only Paeonia lactiflora showed significantly lesser gas production than the control (P<0.05). In methane production, Ceramium, Zizyphus, Paeonia, Agrimonia, Torilis, Mugwort, Foeniculum, Euphorbia, Taraxacum, Artemisia, Momordica, Curcuma and Moringa reduced methane significantly compared to the control (P<0.05).

Study on Incineration Behavior of Heavy Oil Fly Ash for Valuable Metal Recovery (유가금속(有價金屬) 회수(回收)를 위한 중유회(重油灰)의 연소거동(燃燒擧動)에 관한 연구(硏究))

  • Choi, Young-Yeon;Nam, Chul-Woo;Kim, Byoung-Gyu
    • Resources Recycling
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    • v.18 no.1
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    • pp.22-29
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    • 2009
  • To design and construct a moving bed stoker incinerator for incineration treatment of the domestic oil fly ash, operating condition and moving bed area of incinerator were determined by performing incinerate experiment of the oil fly ash in the muffle furnace which simulates moving bed stoker incinerator in all conditions. Incineration process of the oil fly ash could be divided into 3 stages, every stage needs the appropriate operating condition for effective incineration. The optimum content of water in the heavy oil fly ash was found to be 20 wt% to prevent the ash from flying and reduce the volume. Science combustion rate of oil fly ash depends on the oxygen content, the incinerator must have a equipment to control the oxygen content in the combustion air. The optimum temperature was $750{\sim}800^{\circ}C$ in order to prevent adhesion to the stocker and evaporation of metal compounds of low melting point. Uniform combustion reaction and acceleration of combustion rate required agitation during the combustion of oil fly ash. The incineration rate was $12.53kg/m^2hr$ and the working area of moving bed incinerator was found to be $60m^2$ to incinerate 18 tons of oil fly ash per day.

The Prediction of Minimum Miscible Pressure for CO2 EOR using a Process Simulator

  • Salim, Felicia;Kim, Seojin;Saputra, Dadan D.S.M.;Bae, Wisup;Lee, Jaihyo;Kim, In-Won
    • Korean Chemical Engineering Research
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    • v.54 no.5
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    • pp.606-611
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    • 2016
  • Carbon dioxide injection is a widely known method of enhanced oil recovery (EOR). It is critical for the $CO_2$ EOR that the injected $CO_2$ to reach a condition fully miscible with oil. To reach the miscible point, a certain level of pressure is required, which is known as minimum miscibility pressure (MMP). In this study, a MMP prediction method using a process simulator is proposed. To validate the results of the simulation, those are compared to a slim tube experiment and several empirical correlations of previous literatures. Aspen HYSYS is utilized as the process simulator to create a model of $CO_2$/crude oil encounter. The results of the study show that the process simulator model is capable of predicting MMP and comparable to other published methods.