• 제목/요약/키워드: Migration coalescence

검색결과 6건 처리시간 0.019초

TiO2 나노 분말의 분산 안정성 및 침강 특성 (Stability and Sedimentation Properties of TiO2 Nanoparticles)

  • 우승희;이민구;이창규
    • 한국분말재료학회지
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    • 제13권4호
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    • pp.263-268
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    • 2006
  • In this study, the colloidal stability and sedimentation behavior of crystalline $TiO_2$ particles (300nm) in various organic solvents have been investigated by means of a backscattered light flux profile (Turbiscan). The backscattered light flux profiles revealed that the $TiO_2$ nanoparticles were readily sedimented in water, methyl alcohol, and ethyl alcohol due to a flocculation-induced particle growth, while a particle coalescence and a sedimentation of the $TiO_2$ nanoparticles were hardly observed in isopropyl alcohol. The migration velocities of the $TiO_2$ particle were measured as around 6.15/min, 12.53 m/min, 6.51m/min, and 0.18m/min for water, methyl alcohol, ethyl alcohol, and isopropyl alcohol, respectively, showing a remarkably slow migration of the $TiO_2$ particles in isopropyl alcohol.

반응 용기법을 이용한 InP/ZnS 양자점 합성과정에서 InP 코어의 성장기구 (Growth mechanism of InP and InP/ZnS synthesis using colloidal synthesis)

  • 서한욱;정다운;이빈;현승균;김범성
    • 한국분말재료학회지
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    • 제24권1호
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    • pp.6-10
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    • 2017
  • This study investigates the main growth mechanism of InP during InP/ZnS reaction of quantum dots (QDs). The size of the InP core, considering a synthesis time of 1-30 min, increased from the initial 2.56 nm to 3.97 nm. As a result of applying the proposed particle growth model, the migration mechanism, with time index 7, was found to be the main reaction. In addition, after the removal of unreacted In and P precursors from bath, further InP growth (of up to 4.19 nm (5%)), was observed when ZnS was added. The full width at half maximum (FWHM) of the synthesized InP/ZnS quantum dots was found to be relatively uniform, measuring about 59 nm. However, kinetic growth mechanism provides limited information for InP / ZnS core shell QDs, because the surface state of InP changes with reaction time. Further study is necessary, in order to clearly determine the kinetic growth mechanism of InP / ZnS core shell QDs.

Computational and Experimental Study of Grain Growth in WC-Co and WC-VC-Co Cemented Carbides

  • Shin, Soon-Gi
    • 한국재료학회지
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    • 제19권11호
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    • pp.588-595
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    • 2009
  • The knowledge of grain growth of carbide particles is very important for manufacturing micrograined cemented carbides. In the present study, continuous and discontinuous grain growth in WC-Co and WC-VC-Co cemented carbides is investigated using the Monte Carlo computer simulation technique. The Ostwald ripening process (solution/re-precipitation) and the grain boundary migration process are assumed in the simulation as the grain growth mechanism. The effects of liquid phase fraction, grain boundary energy and implanted coarse grain are examined. At higher liquid phase content, mass transfer via solid/liquid interfaces plays a major role in grain growth. Growth rate of the implanted grain was higher than that of the matrix grains through solution/re-precipitation and coalescence with neighboring grains. The results of these simulations qualitatively agree with experimental ones and suggest that distribution of liquid phase and carbide particle/carbide grain boundary energy as well as contamination by coarse grain are important factors controlling discontinuous grain growth in WC-Co and WC-VC-Co cemented carbides. The contamination by coarse grains must by avoided in the manufacturing process of fine grain cemented carbides, especially with low Co.

$Al_2O_3/Ni$ 나노복합분말의 치밀화중 분산상 Ni의 성장기구 (Growth Mechanism of Nickel Nanodispersoids during Consolidation of $Al_2O_3/Ni$ Nanocomposite Powder)

  • 김범성;이재성;오승탁;좌용호
    • 한국분말재료학회지
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    • 제7권4호
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    • pp.237-243
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    • 2000
  • The property and performance of the $Al_2O_3/Ni$ nanocomposites have been known to strongly depend on the structural feature of Ni nanodispersoids which affects considerably the structure of matrix. Such nanodispersoids undergo structural evolution in the process of consolidation. Thus, it is very important to understand the microstructural development of Ni nanodispersoids depending on the structure change of the matrix by consolidation. The present investigation has focused on the growth mechanism of Ni nanodispersoids in the initial stage of sintering. $Al_2O_3/Ni$ powder mixtures were prepared by wet ball milling and hydrogen reduction of $Al_2O_3$ and Ni oxide powders. Microstructural development and the growth mechanism of Ni dispersion during isothermal sintering were investigated depending on the porosity and structure of powder compacts. The growth mechanism of Ni was discussed based upon the reported kinetic mechanisms. It is found that the growth mechanism is closely related to the structural change of the compacts that affect material transport for coarsening. The result revealed that with decreasing porosity by consolidation the growth mechanism of Ni nanoparticles is changed from the migration-coalescence process to the interparticle transport mechanism.

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냉간가공과 베타급냉된 Zr-Sn 합금의 재결절 거동 (Recrystallization Behavior of Cold-worked and $\beta$-Quenched Zr-Zn Alloys)

  • 이명호;정용환
    • 한국재료학회지
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    • 제10권11호
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    • pp.725-731
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    • 2000
  • 냉간가공과 베타급냉된 Zr-Sn 합금의 재결정 거동을 미소경도 시험과 미세 조직 관찰 방법에 의해서 조사하였다. 베타급냉 처리된 합금의 재결정은 냉간가공된 합금의 재결정보다 늦게 일어났는데, 이는 냉간 가공에 의해 도입된 축적에너지가 더 높다는 것을 의미한다. 냉간가공재와 베타급냉재의 초기 경도는 동일하지라도 재결정거동은 아주 다르게 나타났다. TEM 조직관찰 결과를 근거로 할 때, 냉간가공재는 subgrain합체에 의해서 재결정이 일어나며 베타급냉재는 응력유기 입계이동에 의해서 재결정이 일어나는 것으로 밝혀졌다.

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Delaire 방법을 이용한 구순열의 교정 (Primary Cleft Lip Repair Using the "Delaire" Technique)

  • 김용하;이현태
    • 대한두개안면성형외과학회지
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    • 제12권2호
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    • pp.75-80
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    • 2011
  • Deformities related with cleft lip are not only limited to the cleft site but also extended to all around the nasolabial region. Facial development is composed of several complex processes as the formation, migration, coalescence and interaction of separate fields. When there is a cleft event, it means there are general problems of those processes. As a result facial elements should have displacement, deformation and functional hypotrophy. These also affect the mucocutaneous structures, which result in the typical deformities of cleft lip. Traditional surgical methods are not sufficient of the correction of functional impairments in the cleft lip. Accordingly, there are relatively high possibilities of occurring secondary deformities. The Delaire's method focuses on repair of functional impairment of the cleft. Consequently, it can maintain the initial good surgical result and avoid the unnecessary incision scar. And this method can minimize secondary nasal deformities which can reduce the risk of additional nasal correction. Therefore authors introduce this advantageous the Delaire technique cheliolplasty which it can be widely used for the cleft lip correction in Korea.