• Archives of Pharmacal Research
• /
• v.17 no.5
• /
• pp.389-391
• /
• 1994

• Bulletin of the Korean Chemical Society
• /
• v.30 no.12
• /
• pp.3105-3106
• /
• 2009

• Journal of the Korean Ceramic Society
• /
• v.29 no.4
• /
• pp.305-311
• /
• 1992

As compared with conventional sintering, rapid heating in microwave system could enhance sinterability and final properties of alumina with a very short sintering time. In this study microwave sintering was performed using zirconia brick as a reaction chamber which was positioned in a 2.45 GHz(700 W) multimode microwave cavity. Microwave-sintered alumina showed high density and smaller grain size than conventionally sintered alumina because the ratio of densification rate/grain growth rate was increased by rapid heating.

• Journal of Environmental Science International
• /
• v.22 no.9
• /
• pp.1097-1103
• /
• 2013

Tetrafluoromethane($CF_4$) have been widely used as etching and chemical vapor deposition gases for semiconductor manufacturing processes. $CF_4$ decomposition efficiency using microwave system was carried out as a function of the microwave power, the reaction temperature, and the quantity of $Al_2O_3$ addition. High reaction temperature and addition of $Al_2O_3$ increased the $CF_4$ removal efficiencies and the $CO_2/CF_4$ ratio. When the SA30 (SiC+30wt%$Al_2O_3$) and SA50 (SiC+50wt%$Al_2O_3$) were used, complete $CF_4$ removal was achieved at $1000^{\circ}C$. The $CF_4$ was reacted with $Al_2O_3$ and by-products such as $CO_2/CF_4$ and $AlF_3$ were produced. Significant amount of by-product such as $AlF_3$ was identified by X-ray powder diffraction analysis. It also showed that the ${\gamma}-Al_2O_3$ was transformed to ${\alpha}-Al_2O_3$ after microwave thermal reaction.

• Journal of Hydrogen and New Energy
• /
• v.28 no.5
• /
• pp.584-599
• /
• 2017

Biodiesel is renewable, eco-friendly, clean burning diesel replacement that is consisted of short chain alkyl ester. Biodiesel is derived from the transesterification of vegetables oils or animal fats with alcohol. The process has some technical problems that must be resolved to reduce the high operation cost. Eco-friendly physical technologies by using microwave have successfully improved the transesterification for biodiesel production. This paper attempts to extensively review microwave-assisted technology for biodiesel production. Additionally, different types of catalyst for biodiesel production have been summarized. It is concluded that the microwave-assisted technique improves the reaction rate significantly in comparison with conventional methods. Therefore it can be a suitable method of reducing the reaction time and can also decreases the cost of biodiesel production.

• Korean Chemical Engineering Research
• /
• v.59 no.4
• /
• pp.611-625
• /
• 2021

Mg crowns were manufactured using domestic dolomite (Ca·Mg(CO₃)₂) (20~30 mm). In order to manufacture the calcined dolomite (CaO·MgO), (a) electric furnace (950 ℃, 480 min) and (b) microwave furnace (950 ℃, 60 min) processes were used. As a result of XRD analysis, it was analyzed as (a) CaO 56.9 wt%, MgO 43.1 wt% by electric furnace process and (b) CaO 55 wt%, MgO 45 wt% by microwave furnace process. Even when the decarbonation reaction time of dolomite was shortened by 1/8 in microwave furnace process compare with electric furnace process, the calcined dolomite could be produced. The hydration reaction (ASTM C 110) is a standard for the hydration reactivity of calcined dolomite, and the calcined dolomite produced by electric furnace process showed a high hydration reactivity (max temp 79.8 ℃/1.5 minutes). Such hydration reactivity was occurred by only CaO hydration reaction and that was confirmed by XRD analysis. The calcined dolomite produced by microwave furnace process showed low hydration reactivity (max temp 81.7 ℃/19.5 minutes). Such low hydration reactivity was occurred by CaO and MgO hydration reaction due to the hydration reaction of CaO thereafter occurring of the hydration reaction of MgO, and that was confirmed by XRD analysis. The prepared Mg crown were 58.8 g and 74.6 g by electric furnace and microwave furnace processes, respectively, under the reaction conditions of 1,230 ℃, 60 min, 5 × 10^-2 torr by silicothermic reduction.

• Korean Chemical Engineering Research
• /
• v.56 no.2
• /
• pp.275-280
• /
• 2018

Methyl ester derived from coconut oil is very interesting to study since it contains free-fatty acid with chemical structure of medium carbon chain ($C_{12}-C_{14}$), so the methyl ester obtained from its part can be a biodiesel and another partially into biokerosene. The use of heterogeneous catalysts in the production of methyl ester requires severe conditions (high pressure and high temperature), while at low temperature and atmospheric conditions, yield of methyl ester is relatively very low. By using microwave irradiation trans-esterification reaction with heterogeneous catalysts, it is expected to be much faster and can give higher yields. Therefore, we studied the production of methyl ester from coconut oil using CaO catalyst assisted by microwave. Our aim was to find a kinetic model of methyl ester production through a transesterification process from coconut oil assisted by microwave using heterogeneous CaO catalyst. The experimental apparatus consisted of a batch reactor placed in a microwave oven equipped with a condenser, stirrer and temperature controllers. Batch process was conducted at atmospheric pressure with a variation of CaO catalyst concentration (0.5; 1.0; 1.5; 2.0, 2.5%) and microwave power (100, 264 and 400 W). In general, the production process of methyl esters by heterogeneous catalyst will obtain three layers, wherein the first layer is the product of methyl ester, the second layer is glycerol and the third layer is the catalyst. The experimental results show that the yield of methyl ester increases along with the increase of microwave power, catalyst concentration and reaction time. Kinetic model of methyl ester production can be represented by the following equation: $-r_{TG}=1.7{\cdot}10^6{_e}{\frac{-43.86}{RT}}C_{TG}$.

• Bulletin of the Korean Chemical Society
• /
• v.23 no.5
• /
• pp.667-668
• /
• 2002

• Bulletin of the Korean Chemical Society
• /
• v.34 no.10
• /
• pp.2871-2876
• /
• 2013

We present an efficient and new preparative method for the symmetric ${\beta}$-diketimines assisted by microwave. A series of N,N'-symmetrically alkyl substituted ${\beta}$-diketimines have been synthesized from the reaction of O-acylation with dimethylsulfate. Higher reproducibility and yield, lower cost and much improved green nature originated from no solvent condition and higher energy efficiency due to faster reaction time are major merits of this new method. In addition to these merits, almost every kind of ${\beta}$-diketimines including alkyl-substituted ${\beta}$-diketimines little reported yet has been successfully prepared. Much wider applications of these compounds in various fields are expected.

• Applied Chemistry for Engineering
• /
• v.18 no.4
• /
• pp.344-349
• /
• 2007

NaY zeolites synthesized by microwave heating were compared with those obtained by conventional heating. When the same temperature increasing rates were adopted in both heating methods, the microwave heating shortened the induction period and enhanced the rate of crystallization of NaY zeolites compared with the conventional heating. Irrespective of microwave radiation, the fast temperature increasing rate also shortened the induction time and enhanced the crystallization of NaY zeolites. The crystal sizes of NaY zeolites were large under the fast temperature raise of the reaction mixture and became larger by microwave radiation. At the same time, the fast temperature increasing rate has reduced the energy consumption due to the fast completion of reaction during the synthesis of NaY zeolite. The energy consumption in the conventional ethylene glycol bath was lower than that in the microwave oven with the same temperature increasing rate in this study, which means that the energy efficiency is not always high in microwave heating. If the temperature increasing rate is carefully controlled, however, NaY zeolite can be produced with high energy efficiency in the microwave oven.