• 한국건축시공학회지
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• 제20권4호
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• pp.321-330
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• 2020

지오폴리머의 반응성은 원재료의 구성성분 및 Si/Al비, Na/Al비, 물-결합재비, 비정질 요소 등을 고려하여 명확한 메커니즘을 규명하는 것은 매우 중요하다. 따라서 원재료 및 알칼리 활성화제의 구성성분을 고려한 %Na₂O, M_s는 반응성을 결정하는 중요한 요소가 된다. 하지만 다수의 연구에서는 알칼리 활성화제의 농도와 양생 조건 등의 기본적인 요소만을 고려하는 한계점을 나타내고 있다. 따라서 본 연구에서는 %Na₂O, Ms 및 고로슬래그 미분말의 혼입량에 따른 지오폴리머 페이스트의 강도특성, 반응열, 길이변화, 미세구조 분석을 실시하였다.

• Korean Chemical Engineering Research
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• 제52권1호
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• pp.26-39
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• 2014

전자 소자의 구리 금속 배선은 전해 도금을 포함한 다마신 공정을 통해 형성한다. 본 총설에서는 배선 형성을 위한 구리 전해 도금 및 수퍼필링 메카니즘에 대해 다루고자 한다. 수퍼필링 기술은 전해 도금의 전해질에 포함된 유기 첨가제의 영향에 의한 결과이며, 이는 유기 첨가제의 표면 덮임율을 조절하여 웨이퍼 위에 형성된 패턴의 바닥 면에서의 전해 도금 속도를 선택적으로 높임으로써 가능하다. 소자의 집적도를 높이기 위해 금속 배선의 크기는 계속적으로 감소하여 현재 그 폭이 수십 nm 수준으로 줄어들었다. 이러한 배선 폭의 감소는 구리 배선의 전기적 특성 감소, 신뢰성의 저하, 그리고 수퍼필링의 어려움 등 여러 가지 문제를 야기하고 있다. 본 총설에서는 상기 기술한 문제점을 해결하기 위해 구리의 미세 구조 개선을 위한 첨가제의 개발, 펄스 및 펄스-리벌스 전해 도금의 적용, 고 신뢰성 배선 형성을 위한 구리 기반 합금의 수퍼필링, 그리고 수퍼필링 특성 향상에 관한 다양한 연구를 소개한다.

• 접착 및 계면
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• 제5권3호
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• pp.10-17
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• 2004

본 연구에서는 레이온직물에 대하여 승온속도, 안정화온도, 분위기가스, 화학적 표면처리 등 여러가지 조건에서 안정화공정을 행한 후, 직물의 열수축과 열안정성, 그리고 미세구조에 미치는 공정 조건의 영향을 조사하였다. 레이온직물의 열수축과 중량변화에 인산처리 유무와 승온속도가 가장 중요한 영향을 미쳤다. 특히, 인산처리를 한 경우가 하지 않은 경우보다 레이온직물의 두께변화는 약 80%, 길이변화는 약 20%, 그리고 중량변화는 약 26%가 줄어드는 열수축 억제 효과를 보여주었다. 안정화 된 레이온직물의 열안정성에는 안정화온도와 인산처리 그리고 분위기가스와 승온속도 등 주어진 안정화공정 조건 모두가 영향을 주었다. 또한 안정화섬유의 표면 상태 및 섬유직경 변화도 공정 전에 행한 인산처리의 유무에 의존하였다.

• Journal of Welding and Joining
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• 제20권6호
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• pp.754-761
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• 2002

It has been reported that the creep characteristics on weldment which is composed of weld metal(W.M), fusion line(F.L), heat-affected zone(HAZ), and base meta(B.M) could be unpredictably changed in severe service conditions such as high temperature and high pressure. However, the studies done on creep damage in power plant components have been mostly conducted on B.M and not the creep properties of the localized microstructures in weldment have been thoroughly investigated yet. In this paper, it is investigated the creep characteristics for three microstructures like coarse-grain HAZ(CGHAZ), W.M, and B.M in X20CrMoV121 steel weldment by the small punch-creep-(SP-Creep) test using miniaturized specimen($10{\times}10{\times}0.5mm$). The W.M microstructure possesses the higher creep resistance and shows lower creep strain rate than the B.M and CGHAZ. In the lower creep load the highest creep strain rate is exhibited in CGHAZ, whereas in the higher creep load the B.M represents the high creep strain rate. The power law correlation for all microstructures exists between creep rate and creep load at $600^{\circ}C$. The values of creep load index (n) based on creep strain rate for B.M, CGHAZ, and W.M are 7.54, 4.23, and 5.06, respectively and CGHAZ which shows coarse grains owing to high welding heat has the lowest creep loade index. In all creep loads, the creep life for W.M shows the highest value.

• Journal of Welding and Joining
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• 제15권6호
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• pp.96-104
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• 1997

The present study was aimed to correlate the microstructure and the hardness as well as the wear resistance of the metal-ceramic particulated composite layer on the pure Al plate. The composite layers were constructed by the addition of TiC particles on the surface of Al-Cu alloyed layers by PTA overlaying process. Initially, the Al-Cu alloyed layers were achieved by the deposition of Al-(25 ~ 48%) Cu alloys on the pure Al plate by TIG process. It was revealed that TiC particles were uniformly dispersed without any reaction with matrix in the composite layer. The volume fraction of TiC particles (TiC V F) increased from 12% to 55% with increasing the number of pass of composite layer. Hardnesses of (Al-48%Cu + TiC (3&4layers)) composite layer were Hv450 and Hv560, respectively, due to the increase of TiC V/F. Hardnesses of (Al-Cu + TiC) composite layers decreased gradually with insreasing temperature from 100$^{\circ}$C to 400$^{\circ}$C, and hardnesses at 400$^{\circ}$C were then reached to 1/5 - 1/10 of room temperature hardness depending on the construction of composite layers. The Specific wear of (Al + Tic) layer and Al-48%Cu alloyed layer decreased to 1/10 of the of pure Al, while the specific wear of (Al-48%Cu + TiC (4 layers)) composite layer exhibited 1/15 of that of steel such as SS400 and STS304.

• 한국재료학회지
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• 제21권10호
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• pp.556-562
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• 2011

We carried out this study to evaluate the grain refining in and the mechanical properties of alloys that undergo severe plastic deformation (SPD). Conventional rolling (CR) and cross-roll rolling (CRR) as SPD methods were used with Ni-20Cr alloy as the experimental material. The materials were cold rolled to a thickness reduction of 90% and subsequently annealed at $700^{\circ}C$ for 30 min to obtain a fully recrystallized microstructure. For the annealed materials after the cold rolling, electron back-scattered diffraction (EBSD) analysis was carried out to investigate the grain boundary characteristic distributions (GBCDs). The CRR process was more effective when used to develop the grain refinement relative to the CR process; as a result, the grain size was refined from $70{\mu}m$ in the initial material to $4.2{\mu}m$ (CR) and $2.4{\mu}m$ (CRR). These grain refinements have a direct effect on improving the mechanical properties; in this case, the microhardness, yield and tensile strength showed significant increases compared to the initial material. In particular, the CRR-processed material showed more effective values relative to the CR-processed materials. The different texture distributions in the CR (001//ND) and CRR (111//ND) were likely the cause of the increase in the mechanical properties. These findings suggest that CRR can result in materials with a smaller grain size, improved texture development and improved mechanical properties after recrystallization by a subsequent annealing process.

• 한국전산구조공학회논문집
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• 제13권1호
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• pp.51-61
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• 2000

본 논문은 구조물의 미시적 측면에서 유효평균탄성계수를 결정하기 위한 균질화기법인 점근적 방법을 적용하였고, 탄성값을 조사하기 위하여 유한요소법으로 정식화하였다. 수치 예로서 물성치가 각기 다른 등방성 재료를 적층한 부재의 임의 단면에서 단위요소를 해석영역으로 설정하고 산출된 탄성계수를 기존의 해석방법으로부터 산출된 값과 비교하였다. 균질화기법으로 산출된 탄성계수는 과소평가되어 나타나며, 이는 해석영역을 유한요소 정식화하는 과정에서 수정항만큼 차이가 난다는 것을 증명하였다. 기존 해석방법으로는 복합재료의 탄성계수가 단순히 재료의 산술적 평균값으로 계산되는 것과는 달리, 미시적으로 복합재 단위요소의 반복성을 고려함으로써 제안된 해석방법이 보다 유용하다는 것을 보여 주었다.

• 한국재료학회지
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• 제24권3호
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• pp.129-134
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• 2014

Pure $MgH_2$ was milled under a hydrogen atmosphere (reactive mechanical grinding, RMG). The hydrogen storage properties of the prepared samples were studied at a relatively low temperature of 423 K and were compared with those of pure Mg. The hydriding rate of the Mg was extremely low (0.0008 wt% H/min at n = 4), and the $MgH_2$ after RMG had higher hydriding rates than that of Mg at 423 K under 12 bar $H_2$. The initial hydriding rate of $MgH_2$ after RMG at 423 K under 12 bar $H_2$ was the highest (0.08 wt% H/min) at n = 2. At n = 2, the $MgH_2$ after RMG absorbed 0.39 wt% H for 5 min, and 1.21 wt% H for 60 min at 423K under 12 bar $H_2$. At 573 K under 12 bar $H_2$, the $MgH_2$ after RMG absorbed 4.86 wt% H for 5 min, and 5.52 wt% H for 60 min at n = 2. At 573 K and 423 K under 1.0 bar $H_2$, the $MgH_2$ after RMG and the Mg did not release hydrogen. The decrease in particle size and creation of defects by reactive mechanical grinding are believed to have led to the increase in the hydriding rate of the $MgH_2$ after RMG at a relatively low temperature of 423 K.

• 한국분말재료학회지
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• 제15권6호
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• pp.482-488
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• 2008

The indentation technique has been one of the most commonly used techniques for the measurement of the mechanical properties of materials due to its experimental ease and speed. Recently, the scope of indentation has been enlarged down to the nanometer range through the development of instrumentations capable of continuously measuring load and displacement. In addition to testing hardness, the elastic modulus of submicron area could be measured from an indentation load-displacement (P-h) curve. In this study, the hardness values of the constituent phases in Ti($C_{0.7}N_{0.3}$)-NbC-Ni cermets were evaluated by nanoindentation. SEM observation of the indented surface was indispensable in order to separate the hardness of each constituent phase since the Ti($C_{0.7}N_{0.3}$)-based cermets have relatively inhomogeneous microstructure. The measured values of hardness using nanoindentation were ${\sim}20$ GPa for hard phase and ${\sim}10$ GPa for binder phase. The effect of NbC addition on hardness was not obvious in this work.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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• pp.297-297
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• 2008

Buffer layers play an important role in the development of high critical current density coated conductor. $LaMnO_3$, $SrTiO_3$ and $BaZrO_3$ buffer layers were compatible with MgO surfaces and also provide a good template for growing high current density REBCO(RE=Rare earth) films. Systematic studies on the influences of pulsed laser deposition parameters (deposition temperature, deposition pressure, processing gas, laser energy density, etc.) on microstructure and texture properties of $LaMnO_3$, $SrTiO_3$ and $BaZrO_3$ films as buffer layer deposited on ion-beam assisted deposition MgO (IBAD_MgO) template by pulse laser deposition method, were carried out. These results will be presented together with the discussion on the possible use of this material in HTS coated conductor as buffer.