• 한국재료학회지
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• 제22권2호
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• pp.66-70
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• 2012

Ti-Ni alloys are widely used in numerous biomedical applications (e.g., orthodontics, cardiovascular science, orthopaedics) due to their distinctive thermomechanical and mechanical properties, such as the shape memory effect, superelasticity and low elastic modulus. In order to increase the biocompatibility of Ti-Ni alloys, many surface modification techniques, such as the sol-gel technique, plasma immersion ion implantation (PIII), laser surface melting, plasma spraying, and chemical vapor deposition, have been employed. In this study, a Ti-49.5Ni (at%) alloy was electrochemically etched in 1M $H_2SO_4$+ X (1.5, 2.0, 2.5) wt% HF electrolytes to modify the surface morphology. The morphology, element distribution, crystal structure, roughness and energy of the surface were investigated by scanning electron microscopy (SEM), energy-dispersive Xray spectrometry (EDS), X-ray diffractometry (XRD), atomic force microscopy (AFM) and contact angle analysis. Micro-sized pores were formed on the Ti-49.5Ni (at%) alloy surface by electrochemical etching with 1M $H_2SO_4$+ X (1.5, 2.0, 2.5) wt% HF. The volume fractions of the pores were increased by increasing the concentration of the HF electrolytes. Depending on the HF concentration, different pore sizes, heights, surface roughness levels, and surface energy levels were obtained. To investigate the osteoblast adhesion of the electrochemically etched Ti-49.5Ni (at%) alloy, a MTT test was performed. The degree of osteoblast adhesion was increased at a high concentration of HF-treated surface structures.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 추계학술대회 논문집
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• pp.99-99
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• 2009

Two different micro-flows during the evaporation of ink droplets were achieved by engineering both surface tension gradient and compositional gradient across the ink droplet: (1) Coffee-ring generating flow resulting from the outward flow inside the ink droplet & (2) Marangoni flow leading to the circulation flow inside the ink droplet. The surface tension gradient and the compositional gradient in the ink droplets were tailored by mixing two different solvents with difference surface tension and boiling point. In order to create the coffee-ring generating flow (outward flow), a single-solvent system using N,N-dimethylformamide with nano-sized spherical alumina particles was formulated, Marangoni flow (circulation flow) was created in the ink droplets by combining N,N-dimethylformamide and fotmamide with the spherical alumina powders as a co-solvent ink system. We have investigated the effect of these two different flows on the formation of ceramic films by inkjet printing method, The packing density of the ceramic films printed with two different ink systems (single- and co-solvent systems) and their surface roughness were characterized. The dielectric properties of these inkjet-printed ceramic films such as dielectric constant and dissipation factor were also studied in order to evaluate the feasibility of their application to the electronic ceramic package substrate.

• 한국입자에어로졸학회지
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• 제13권1호
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• pp.11-16
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• 2017

Indoor air quality is of increasing concern because it is closely related human health. An air handling unit (AHU) can be used to control the indoor air quality related to particulate matters and $CO_2$ as well as air conditioning such as temperature and humidity of indoor air. An electrostatic precipitator has a high collection efficiency and low pressure drop, however, ozone can possibly generate from its chargers, which is one of drawbacks to apply it for indoor air control. Here we compared four charging electrodes such as a $50{\mu}m$ tungsten wire, a $100{\mu}m$ tungsten wire, a $16{\mu}m$-thickness Al foil and a carbon fabric comprised of $5-10{\mu}m$ fibers. The carbon fabric electrode showed a superior particle collection efficiency and a lower ozone generation at a given power consumption compared to tungsten wires of 50, $100{\mu}m$ and an Al foil electrode. This low ozone generating, micro-sized electrode can be applied to the electrostatic precipitator in AHU for indoor air control.

• 지질공학
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• 제29권4호
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• pp.383-391
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• 2019

Bio-grouting based on microbial-induced calcite precipitation (MICP) is recently emerging as a novel and environmentally friendly technique for improvement of coarse-grained ground. To date, the mechanical behaviour of bio-grouted coarse-grained soil with different calcite contents and grain sizes still remains poorly understood. The primary objective of this study is to investigate the influence of calcite content on the mechanical properties of bio-grouted coarse-grained soil with different grain sizes. This is achieved through an integrated study of uniaxial loading experiments of bio-grouted coarse-grained soil, 3D digitization of the grains in conjunction with discrete element modelling (DEM). In the DEM model, aggregates were represented by clump logic based on the 3D morphology digitization of the typical coarse-grained aggregates while the CaCO₃ was represented by small-sized bonded particle model. The computed stress-strain relations and failure patterns of the bio-grouted coarse-grained soil were validated against the measured results. Both experimental and numerical investigation suggest that aggregate sizes and calcite content significantly influence the mechanical behaviour of bio-cemented aggregates. The strength of the bio-grouted coarse-grained soil increases linearly with calcite content, but decreases non-linearly with the increasing particle size for all calcite contents. The experimental-based DEM approach developed in this study also offers an optional avenue for the exploring of micro-mechanisms contributing to the mechanical response of bio-grouted coarse-grained soils.

• 한국재료학회지
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• 제21권5호
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• pp.288-294
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• 2011

Simultaneous Ni and C codeposition by electrolysis was investigated with the aim of obtaining better corrosion resistivity and surface conductivity of a metallic bipolar plate for application in fuel cells and redox flow batteries. The carbon content in the Ni-C composite plate fell in a range of 9.2~26.2 at.% as the amount of carbon in the Ni Watt bath and the roughness of the composite were increased. The Ni-C composite with more than 21.6 at.% C content did not show uniformly dispersed carbon. It also displayed micro-sized defects such as cracks and crevices, which result in pitting or crevice corrosion. The corrosion resistance of the Ni-C composite in sulfuric acid is similar with that of pure Ni. Electrochemical test results such as passivation were not satisfactory; however, the Ni-C composite still displayed less than $10^{-4}$ $A/cm^2$ passivation current density. Passivation by an anodizing technique could yield better corrosion resistance in the Ni-C composite, approaching that of pure Ni plating. Surface resistivity of pure Ni after passivation was increased by about 8% compared to pure Ni. On the other hand, the surface resistivity of the Ni-C composite with 13 at.% C content was increased by only 1%. It can be confirmed that the metal plate electrodeposited Ni-C composite can be applied as a bipolar plate for fuel cells and redox flow batteries.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 춘계학술대회 논문집
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• pp.57-58
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• 2009

The dynamics of nano or micro sized-particles in liquid crystal (LC) medium under an external electric field is of theoretical and technological interest. A fullerene of 10 wt% was doped into the LC medium and its electric field induced motion was controlled by both in-plane and vertical electric fields. In the proposed device, pixel electrode I and pixel electrode II were designed consecutively on the bottom substrate and common electrode on the top of the substrate. When the electric field was applied, the fullerenes start to move in direction of applied electric field. The dark, grey and white states in the proposed device can be obtained by suitable combination of the polarity of applied electric field at pixel electrode I, pixel electrode II and common electrode. The dynamical motions of fullerene particles in LC medium suggest that fullerene can be designed for electronic-paper like displays.

• 비파괴검사학회지
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• 제28권5호
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• pp.395-400
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• 2008

비자성 및 자성 금속 시편의 표면 결함을 검출하기 위하여 교류자기장을 이용하였다. 비파괴 센서 프로브는 자성 박막 요크와 박막형 코일로 구성된 신호 검출부와 시편에 교류자기장을 인가하기 위한 단일 직선을 이용한 여기 코일로 이루어져 있다. 박막형 유도 코일 센서는 스퍼터, 전기도금, 건식 식각과 사진식각 공정을 이용하여 제작되었다. 시편에 교류자기장을 인가하기 위하여 0.7 MHz-1.8 MHz 주파수 영역에서 0.1A-1.0A의 교류전류를 여기코일에 인가하였다. 센서의 특성은 최소 0.5 mm의 깊이와 폭을 가진 인위적인 슬릿 형태 비자성체 Al과 자성체 FeC 결함 시편을 이용하여 측정하였다. 측정된 신호는 높은 감도를 갖고 결함 시편위의 슬릿결함의 위치와 일치함을 알 수 있었다. 또한 박막형 유도 코일 센서를 이용하여 마이크론 크기의 표면 결함을 가진 자성체 FeC의 시편을 비접촉 스캔하여 측정된 유도전압의 변화를 이미지화 하였으며 그 결과를 광학적 이미지와 비교하였다.

• 열처리공학회지
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• 제20권5호
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• pp.237-242
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• 2007

Friction coefficient of SM45C steel was surprisingly reduced with $H_2S$ and $C_3H_8$ gas during plasma sulf-nitriding. During the plasma sulf-nitriding, 100-700 sccm of $H_2S$ gas and 100 sccm of $C_3H_8$ gas were added and working pressure and temperature were 2 torr, $500-550^{\circ}C$, respectively. As $H_2S$ gas amount increased over 500 sccm, flake-like structures were developed on top of the nitriding layer and grain size of the nitriding layer were about 100 nm. The friction coefficient for the sample treated plasma sulf-nitriding under $N_2-H_2S$ gas was 0.4 - 0.5. The structure became more finer and amorphous-like along with $N_2-H_2S-C_3H_8$ gas and the nano-sized surface microstructures resulted in high hardness and significantly low friction coefficient of 0.2.

• 한국분말재료학회지
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• 제20권4호
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• pp.269-274
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• 2013

The present work investigated the dispersion behavior of $Y_2O_3$ particles into AISI 316L SS manufactured using laser cladding technology. The starting particles were produced by high energy ball milling in 10 min for prealloying, which has a trapping effect and homogeneous dispersion of $Y_2O_3$ particles, followed by laser cladding using $CO_2$ laser source. The phase and crystal structures of the cladded alloys were examined by XRD, and the cross section was characterized using SEM. The detailed microstructure was also studied through FE-TEM. The results clearly indicated that as the amount of $Y_2O_3$ increased, micro-sized defects consisted of coarse $Y_2O_3$ were increased. It was also revealed that homogeneously distributed spherical precipitates were amorphous silicon oxides containing yttrium. This study represents much to a new technology for the manufacture and maintenance of ODS alloys.

• 한국분말재료학회지
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• 제20권4호
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• pp.275-279
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• 2013

Fe-based oxide dispersion strengthened (ODS) powders were produced by high energy ball milling, followed by spark plasma sintering (SPS) for consolidation. The mixed powders of 84Fe-14Cr-$2Y_2O_3$ (wt%) were mechanically milled for 10 and 90 mins, and then consolidated at different temperatures ($900{\sim}1100^{\circ}C$). Mechanically-Alloyed (MAed) particles were examined by means of cross-sectional images using scanning electron microscopy (SEM). Both mechanical alloying and sintering behavior was investigated by X-ray diffraction (XRD) and high resolution transmission electron microscopy (HR-TEM). To confirm the thermal behavior of $Y_2O_3$, a replica method was applied after the SPS process. From the SEM observation, MAed powders milled for 10 min showed a lamella structure consisting of rich regions of Fe and Cr, while both regions were fully alloyed after 90 min. The results of sintering behavior clearly indicate that as the SPS temperature increased, micro-sized defects decreased and the density of consolidated ODS alloys increased. TEM images revealed that precipitates smaller than 50 nm consisted of $YCrO_3$.