• Title/Summary/Keyword: Micro-Structure

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Analysis of Mechanical Properties and Micro structure of Fly Ash Based Alkali-activated Mortar (플라이애쉬 기반(基盤) 알칼리 활성(活性) 모르타르의 역학적(力學的) 특성(特性) 및 미세구조(微細構造) 분석(分析))

  • Ryu, Gum-Sung;Koh, Kyung-Taek;Chung, Young-Soo
    • Resources Recycling
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    • v.21 no.3
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    • pp.28-38
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    • 2012
  • The purpose of this paper is to develop the alkali-activated concrete which uses 100% fly ash as a binder without any cement. The compressive strength of the mortar was examined depending on the chemical change in alkali-activator through SEM and SEM/EDS observations and the XRD analysis. It was found from the test that the higher molar concentration induced the greater effect on the initial strength, and that $Si^{4+}$ and $Al^{3+}$ were eluted relative to the compressive strength of mortar. In addition, it was confirmed that Al and Si were determined to be most influential ingredients on the microstructural development of the mortar, and that the different ingredient of the activator was almost no change in solidity from the XRD analysis.

Micro Structure and Surface Characteristics of NiCr Thin films Prepared by DC Magnetron Sputter according to Annealing Conditions (DC 마그네트론 스퍼터링 NiCr 박막의 열처리 조건에 따른 미세구조 및 표면특성)

  • Kwon, Yong;Kim, Nam-Hoon;Choi, Dong-You;Lee, Woo-Sun;Seo, Yong-Jin;Park, Jin-Seong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.6
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    • pp.554-559
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    • 2005
  • Ni/Cr thin film is very interesting material as thin film resistors, filaments, and humidity sensors because their relatively large resistivity, more resistant to oxidation and a low temperature coefficient of resistance (TCR). These interesting properties of Ni/Cr thin films are dependent upon the preparation conditions including the deposition environment and subsequent annealing treatments. Ni/Cr thin films of 250 nm were deposited by DC magnetron sputtering on $Al_2O_3/Si$ substrate with 2-inch Ni/Cr (80/20) alloy target at room temperature for 45 minutes. Annealing treatments were performed at $400^{\circ}C,\;500^{\circ}C,\;and\;600^{\circ}C$ for 6 hours in air or $H_2$ ambient, respectively. The clear crystal boundaries without crystal growth and the densification were accomplished when the pores were disappeared in air ambient. Most of surface was oxidic including NiO, $Ni_2O_3$ and $Cr_xO_y$(x=1,2, y=2,3) after annealing in air ambient. The crystal growth in $H_2$ ambient was formed and stabilized by combination with each other due to the suppression of oxidized substance on film surface. Most oxidic Ni was restored when the oxidic Cr was present due to its stability in high-temperature $H_2$ ambient.

Effects of Gas Flow Ratio on the Properties of Tool Steel Treated by a Direct Current Flasma Nitriding Process

  • Jang H. K.;Whang C. N.;Kim S. G.;Yu B. G.
    • Journal of the Korean institute of surface engineering
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    • v.38 no.5
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    • pp.202-206
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    • 2005
  • Nitriding treatments were conducted on tool steel (SKD 61) at a temperature of $500^{\circ}C$ for 5 hr using high vacuum direct current (DC) plasma, with ammonia and argon as source gases. The structural and compositional changes produced in the nitrided layers by applying different ratios of Ar to $NH_{3}\;(n_{Ar}/n_{NH3}) were investigated using glancing x-ray diffraction (GXRD), optical microscopy, atomic force microscopy (AFM), micro-Vickers hardness testing, and pin-on-disc type tribometer. Nitriding case depths of around of $50{\mu}m$ were produced, varying slightly with different ratios of $n_{Ar}/n_{NH3}. It was found that the specimen surface hardness was 1150 Hv with $n_{Ar}/n_{NH3}=1, increasing to a maximum value of 1500 Hv with $n_{Ar}/n_{NH3}=5. With a further increase in ratio to $n_{Ar}/n_{NH3}=10, the surface hardness of the specimen reduced slightly to a value of 1370 Hv. These phenomena were caused by changes of the crystallographic structure of the nitride layers, i.e the $\gamma'-Fe_{4}N$ phase only was observed in the sample treated with $n_{Ar}/n_{NH3}$=1, and the intensity of the $\gamma'-Fe_{4}N$ phase were reduced but new phase of $\varepsilon'-Fe_{3}N$, which was known as a high hardness, with increasing $n_{Ar}/n_{NH3}. Also, the relative weight loss of counterface of the pin-on-disc with unnitrided steel was 0.2. And that of nitrided steel at a gas mixture ($n_{Ar}/n_{NH3}) of 1, 5, 7, and 10 was 0.4, 0.7, 0.6, and 0.5 mg, respectively. This means that the wear resistance of the nitrided samples could be increased by a factor of 2 at least than that of unnitrided steel.

Studies on the Development of TiAIN/CrN Multi-layered Thin Films by Unbalanced Magnetron Sputtering Process (비대칭 스퍼터링에 의한 TiAIN/CrN 나노 다층 박막의 합성 및 특성 분석에 관한 연구)

  • Kim, Gwang-Seok;Kim, Bom-Sok;Lee, Sang-Yul
    • Journal of the Korean institute of surface engineering
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    • v.38 no.6
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    • pp.207-211
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    • 2005
  • In this work a multi-layered nanostructured TiAIN/CrN superlattice coatings was synthesized using closed-field unbalanced magnetron sputtering method and the relationships between their superlattice period (1), micro-structure, hardness and elastic modulus were investigated. In addition, wear test at $500^{\circ}C$ and oxidation resistance test at $900^{\circ}C$ were performed to investigate high temperature properties of these thin films. The coatings were characterized in terms of microstructure and mechanical properties by transmission electron microscopy (TEM) and nano-indentation test. Results from TEM analysis showed that superlattice periods was inversely proportional to the jig rotation speed. The maximum hardness and elastic modulus of 37 GPa and 375 GPa were observed at superalttice period of 6.1 nm and 4.4 nm, respectively. An higher value of microhardness from TiAIN/CrN thin films than either TiAIN (30 GPa) or CrN (26 GPa) was noted while the elastic modulus was approximately an average of TiAIN and CrN films. These enhancement effects in superlattice films could be attributed to the resistance to dislocation glide across interface between the CrN and TiAIN layers. Much improved plastic deformation resistance ($H^3/E^2$) of 0.36 from TiAIN/CrN coatings was observed, compared with 0.15 and 0.16 from TiAIN and CrN, respectively. Also the wear resistance at $500^{\circ}C$ was largely increased than those of single TiAIN and CrN coatings and TiAIN/CrN coatings showed much reduced weight gain after exposure at $900^{\circ}C$ for 20 hours.

Structure of Mesoscale Heavy Precipitation Systems Originated from the Changma Front (장마전선 상에서 발생한 중규모 호우계 구조에 대한 연구)

  • Park, Chang-Geun;Lee, Tae-Young
    • Atmosphere
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    • v.18 no.4
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    • pp.317-338
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    • 2008
  • Analyses of observational data and numerical simulations were performed to understand the mechanism of MCSs (Mesoscale Convective Systems) occurred on 13-14 July 2004 over Jindo area of the Korean Peninsula. Observations indicated that synoptic environment was favorable for the occurrence of heavy rainfall. This heavy rainfall appeared to have been enhanced by convergence around the Changma front and synoptic scale lifting. From the analyses of storm environment using Haenam upper-air observation data, it was confirmed that strong convective instability was present around the Jindo area. Instability indices such as K-index, SSI-index showed favorable condition for strong convection. In addition, warm advection in the lower troposphere and cold advection in the middle troposphere were detected from wind profiler data. The size of storm, that produced heavy rainfall over Jindo area, was smaller than $50{\times}50km^2$ according to radar observation. The storm developed more than 10 km in height, but high reflectivity (rain rate 30 mm/hr) was limited under 6 km. It can be judged that convection cells, which form cloud clusters, occurred on the inflow area of the Changma front. In numerical simulation, high CAPE (Convective Available Potential Energy) was found in the southwest of the Korean Peninsula. However, heavy rainfall was restricted to the Jindo area with high CIN (Convective INhibition) and high CAPE. From the observations of vertical drop size distribution from MRR (Micro Rain Radar) and the analyses of numerically simulated hydrometeors such as graupel etc., it can be inferred that melted graupels enhanced collision and coalescence process of heavy precipitation systems.

Refinement Behavior of Coarse Magnesium Powder by High Energy Ball Milling (HEBM) (고에너지 밀링공정을 이용한 조대 마그네슘 분말의 미세화 거동)

  • Song, Joon-Woo;Kim, Hyo-Seob;Kim, Hong-Moule;Kim, Taek-Soo;Hong, Soon-Jik
    • Journal of Powder Materials
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    • v.17 no.4
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    • pp.302-311
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    • 2010
  • In this research, the refinement behavior of the coarse magnesium powders fabricated by gas atomization was investigated as a function of milling time using a short duration high-energy ball milling equipment, which produces fine powders by means of an ultra high-energy within a short duration. The microstructure, hardness, and formability of the powders were investigated as a function of milling time using X-ray diffraction, scanning electron microscopy, Vickers micro-hardness tester and magnetic pulsed compaction. The particle morphology of Mg powders changed from spherical particles of feed metals to irregular oval particles, then platetype particles, with increasing milling time. Due to having HCP structure, deformation occurs due to the existence of the easily breakable C-axis perpendicular to the base, resulting in producing plate-type powders. With increasing milling time, the particle size increased until 5 minutes, then decreased gradually reaching a uniform size of about 50 micrometer after 20 minutes. The relative density of the initial power was 98% before milling, and mechanically milled powder was 92~94% with increase milling time (1~5 min) then it increased to 99% after milling for 20 minutes because of the change in particle shapes.

Rapid and Accurate Measurement of Diffusion Length of Minority Carriers of CIGS Solar Cells (CIGS 태양전지의 소수캐리어 확산 거리에 대한 새로운 측정 방안 연구)

  • Lee, Don Hwan;Kim, Young Su;Mo, Chan Bin;Nam, Jung Gyu;Lee, Dong Ho;Park, Sung Chan;Kim, Byoung June;Kim, Dong Seop
    • Current Photovoltaic Research
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    • v.2 no.2
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    • pp.59-62
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    • 2014
  • Minority carrier diffusion length is one of the most important parameters of solar cells, especially for short circuit current density (Jsc). In this report, we proposed the calculating method of the minority carrier diffusion length ($L_n$) in CIGS solar cells through biased quantum efficiency (QE). To verify this method's reliability, we chose two CIGS samples which have different grain size and calculated $L_n$ for each sample. First of all, we calculated out that $L_n$ was 56nm and 97nm for small and large grain sized-cell through this method, respectively. Second, we found out the large grain sized-cell has about 7 times lower defect density than the small grain sized-cell using drive level capacitance profiling (DLCP) method. Consequently, we confirmed that $L_n$ was mainly affected by the micro-structure and defect density of CIGS layer, and could explain the cause of Jsc difference between two samples having same band gap.

Three-Dimensional Numerical Simulation of Mold-Filing and Void Formation During Vacuum-Assisted Resin Transfer Molding (VARTM 공정에서의 금형 충전 및 기공 형성에 관한 3차원 수치해석)

  • 강문구;배준호;이우일
    • Composites Research
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    • v.17 no.3
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    • pp.1-7
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    • 2004
  • In the vacuum assisted RTM (VARTM) process that has become the center of attention for manufacturing massive composite structures, a good evacuation of air in the fiber preform is recognized as the prime factor. The microvoids, or the dry spots, are formed as a result of improper gate/vent locations and the mold geometry. The non-uniform resin velocity at the flow front leads to the formation of microvoids in the fibers, whereas the air in the microvoids can migrate along with the resin flow during mold filling. The residual air in the internal voids of a composite structure may cause a degradation of the mechanical properties as well as the structural failure. In this study, a unified macro- and micro analysis methods were developed to investigate the formation and transport of air in resin during VARTM process. A numerical simulation program was developed to analyze the three-dimensional flow pattern as well as the macro- and microscopic distribution of air in a composite part fabricated by VARTM process.

Multi-wavelength Study of Blazars Using Variability as a Tool

  • Baliyan, Kiran S.;Kaur, Navpreet;Chandra, Sunil;Sameer, Sameer;Ganesh, Shashikiran
    • Journal of Astronomy and Space Sciences
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    • v.33 no.3
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    • pp.177-183
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    • 2016
  • Active galactic nuclei (AGN) are too compact to be resolved by any existing optical telescope facility, making it difficult to understand their structure and the emission processes responsible for their huge energy output. However, variability, one of their characteristic properties, provides a tool to probe the inner regions of AGN. Blazars are the best candidates for such a study, and hence a considerable amount of effort is being made to investigate variability in these sources across the electromagnetic spectrum. Here, using the Mt. Abu infrared observatory (MIRO) blazar monitoring program, we present intra-night, inter-night, and long term aspects of the variability in S5 0716+71, 3C66A, and OJ 287. These stars show significant variability on short (a few tens of mins, to a few hours, to a few days) to long term (months to years) timescales. Based on the light travel time argument, the shortest variability timescales (micro-variability) provide upper limits to the size of the emission region. While S5 0716 shows a very high duty cycle of variability (> 80 %), 3C66A shows a much lower intra day variability (IDV) duty cycle (< 20 %). All three show rapid variations within 2.5 to 3.5 hr, which, perhaps, are generated near the vicinity of black holes. Assuming this, estimates of the masses of the black holes are made at ~109, 8×108, and 2.7×109 M for S5 0716+71, 3C66A, and OJ 287, respectively. Multi-wavelength light-curves for the blazar PKS 1510-089 are discussed to infer the emission processes responsible for the recent flaring episodes in this source.

Experimental Study of a Recuperator with Offset Strip Fins (오프셋 스트립 휜을 가지는 리큐퍼레이터에 대한 실험적 연구)

  • Kim, Taehoon;Do, Kyu Hyung;Han, Yong-Shik;Choi, Byung-Il;Kim, Myungbae
    • Journal of Energy Engineering
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    • v.24 no.2
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    • pp.72-78
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    • 2015
  • In the present study, a recuperator to improve the thermal efficiency of a micro gas turbine is considered. The counter flow plate-fin heat exchanger with offset strip fins is chosen as the type of the recuperator. From the optimization study as varying design parameters of the recuperator determined from the ideal cycle analysis, the internal structure of the recuperator is determined. The recuperator is made from stainless steel 304. In order to evaluate performance of the recuperator, experimental investigation is performed. The effects of inlet temperature of hot-side of the recuperator on the thermal performance of the recuperator are investigated. As a result, effectiveness of the recuperator obtained from the experiments is well consistent with that obtained from the correlations.