• Title/Summary/Keyword: Micro reactors

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A Study on the Effect of the Composting of the Food Garbage by the Variations of Agitation cycle (교반속도 변화가 음식쓰레기의 퇴비화에 미치는 영향에 관한 연구)

  • Hu, Kwan;Shin, Dae-Yewn;Jeong, Byeong-Keon;Park, Chi-Hong
    • Journal of Environmental Health Sciences
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    • v.24 no.2
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    • pp.118-125
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    • 1998
  • This study investigates the react characteristics to suggest the condition of the utilization and disintegration of food garbage as composting by varying the supply amount of air of the fermentation reactors. With the initial temperature and agitation velocity maintained 50$\circ$C and 1 rpm, the supply amount of air gives variety to 0.5, 1, 2, 4 l/kg$\cdot$ min. In the case of the amount of air operated at the 0.5 l/kg$\cdot$ min, reaction temperature shows a rising to the maximum 66$\circ$C after the 48hr, and the oxygen used rate of the micro-organisms shows the largest level at 18.4% after the 8hr. In the case of $NH_3, H_2, H_2S$ and SO$_2$ among the react gas, the sanitary utilization shows the possibility of the microorganisms gas disintegration, with most high gas generate rate. In the case of the amount of air operated at the 1, 2 and 4 l/kg$\cdot$ min, initial react was advanced rapidly and the product of the 72 hr after shows big weight reduction. As the experimentation result, when the amount of air operated at the 1 l/kg$\cdot$ min over, the reduction by disintegration would be more effectively, for the reactor maintains the color tone and shape of the straw (bulking agent).

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Carbon-free Hydrogen Production Using Membrane Reactors (막촉매반응기를 이용한 수소생산)

  • Do, Si-Hyun;Roh, Ji Soo;Park, Ho Bum
    • Membrane Journal
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    • v.28 no.5
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    • pp.297-306
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    • 2018
  • This review focused carbon-free hydrogen productions from ammonia decomposition including inorganic membranes, catalysts and the presently studied reactor configurations. It also contains general information about hydrogen productions from hydrocarbons as hydrogen carriers. A Pd-based membrane (e.g. a porous ceramic or porous metallic support with a thin selective layer of Pd alloy) shows its efficiency to produce the high purity hydrogen. Ru-based catalysts consisted of Ru, support, and promoter are the efficient catalysts for ammonia decomposition. Packed bed membrane reactor (PBMR), Fluidized bed membrane reactor (FBMR), and membrane micro-reactor have been studied mainly for the optimization and the improvement of mass transfer limitation. Various types of reactors, which contain various combinations of hydrogen-selective membranes (i.e. Pd-based membranes) and catalysts (i.e. Ru-based catalysts) including catalytic membrane reactor, have been studied for carbon-free hydrogen production to achieve high ammonia conversion and high hydrogen flux and purity.

Analysis of High Radioactive Materials in Irradiated DUPIC SIMFUEL Using EPMA (EPMA를 이용한 DUPIC 사용후 핵연료 핵분열 생성물의 특성 분석)

  • 정양홍;유병옥;주용선;이종원;정인하;김명한
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.2
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    • pp.125-133
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    • 2004
  • Fission products of DUPIC (Direct Use of Spent PWR Fuel in CANDU Reactors) fuel, irradiated in HANARO research reactor with 61 ㎾/m of maximum linear power and 1,770 ㎿d/tU of average burn-up, was characterized by EPMA(Electron Probe Micro Analyzer). In order to find accurate characterization, the analysis results by EPMA of fresh simulated DUPIC fuel containing fission products as chemicals were compared with that of wet chemical analysis. The metallic precipitates observed at the center of the fresh simulated DUPIC fuel were about 1 $\mu\textrm{m}$ in size and their major components by EPMA were Mo-53.89 at.%, Ru-37.40 at.%, and Pd+Rh-8.71 at.%. Established procedure through the fresh simulated DUPIC fuel was applied to the irradiated DUPIC fuel. Observed size of metallic precipitates were 2∼2.5 $\mu\textrm{m}$ and their compositions were Mo-47.34 at.%, Ru-46 at.%, and Pd+Rh-6.65 at.%. What are uncommon things for this experiment, special treatment for improving the conductivity was attempted to the specimen and the conditions of exact irradiation of electron beam to small metallic precipitate were suggested.

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Removal of Anionic Dyes and Heavy Metal Ions Using Silica Nanospheres or Porous Silica Micro-particles Modified with Various Coupling Agents (다양한 커플링제로 표면 개질된 실리카들을 활용한 음이온성 염료 및 중금속의 제거)

  • Sung, Sohyeon;Lee, Minjun;Cho, Young-Sang
    • Korean Chemical Engineering Research
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    • v.59 no.4
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    • pp.596-610
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    • 2021
  • For application in adsorption process, we synthesized silica nanospheres by Stober method, and silica particles with wrinkled surface as well as macroporous silica particles were also fabricated by utilizing emulsion droplet as micro-reactors, followed by modification of the particle surface using suitable coupling agents containing amine groups. These particles exhibited improved adsorption capacity for heavy metal ions and anionic dyes, which were difficult to be removed by conventional silica particles without surface modification. Anionic dye, methyl orange could be removed almost completely by adsorption using porous silica particles modified using APTES. The adsorption efficiency of heavy metal like copper ions was close to 100%, when porous silica was used as adsorbent particles modified with AAPTS.

Removal of Sediments below Breeding Ground Using Supersonics and Micro-Air Flotation (초음파 및 마이크로공기부양법을 이용한 양식장 퇴적물 제거 특성)

  • Kim, Seog-Ku;Ahn, Jae-Hwan;Yun, Sang-Leen;Kang, Sung-Won;Lee, Jungwoo;Lee, Jea-Keun;Lim, Jun-Heok;Kim, Dong-Soo;Lee, Tae-Yoon
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.10
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    • pp.737-742
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    • 2013
  • The purpose of this study was to remove sediments obtained from breeding ground using supersonics and micro-air flotation method. Sediments from Tongyong breeding grounds showed no contaminations of heavy metals but had great amount of organics. Thus, efficient removal of sediments was required to preserve water quality near breeding ground. Supersonics treatment for sediments was determined to be essential because higher removal efficiency of sediments was obtained when supersonics treatment was used. In addition, application of coagulants increased removal efficiency because its usage increased particle size of sediments, which enabled easy trapping of sediments particle into micro-air bubbles. Removal efficiency of sediments slightly decreased from 95.8% (1 g/L) to 83.9% (8 g/L) at the tests for different amount of sediments, but most of tiny particles were removed from water where sand size particles were left in the bottom of reactors.

Improvement of LBW quality of Zircaloy-4 Spacer Grids for PWR Fuel Assembly (경수로 원전연료용 지르칼로이-4 지지격자 레이저용접품질 개선)

  • Kim, Soo-Sung;Song, Kee-Nam;Han, Hyoung-Jun
    • Journal of Welding and Joining
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    • v.24 no.5
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    • pp.22-28
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    • 2006
  • A spacer grid assembly, which is an interconnected array of slotted grid straps and is welded at the intersections to form an egg crate structure, is one of the main structural components of the nuclear fuel assembly for Pressurized Water Reactors (PWRs). The weld quality of spacer grids in PWRs fuel is extremely important for the fuel assembly performance in the nuclear renter. The spacer grid welds are currently evaluated mainly by the metallographic examination although it reveals only cross-points which are welded by the laser beam. This experiment is also to compare the weldability of Zircaloy-4 spacer grids using by the GTA and LB. The effect of node geometries of spacer grids for the GTAW and LBW has been studied and optimum conditions of spacer grid welding have been found. Microstructures and micro-hardness of the GTA and LB welded zones have been also compared.

Treatment of Industrial Wastewater with High Concentration of Hydrocarbons Using Membrane Reactors

  • Bienati, B.;Bottino, A.;Comite, A.;Ferrari, F.;Firpo, R.;Capannelli, G.
    • Membrane Journal
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    • v.17 no.2
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    • pp.112-117
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    • 2007
  • The application of membrane bioreactors for the depuration of wastewater coming from the washing of mineral oil storage tanks is described. Microfiltration hollow-fibre membranes were used in the submerged configuration. Filtration tests were carried out with a biomass concentration of about 15 g/L in order to assess the critical flux of the hollow fibre membrane used. Then particular care was taken in carrying out the performance runs in the sub-critical flux region. The reactor performance was very high, with removal efficiencies ranging between 93% and 97% also when the concentration of hydrocarbon was very high. Some kinetic parameters for the COD and the hydrocarbon removal were estimated.

Transmission Electron Microscopy Characterization of Early Pre-Transition Oxides Formed on ZIRLOTM

  • Bae, Hoyeon;Kim, Taeho;Kim, Ji Hyun;Bahn, Chi Bum
    • Corrosion Science and Technology
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    • v.14 no.6
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    • pp.301-312
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    • 2015
  • Corrosion of zirconium fuel cladding is known to limit the lifetime and reloading cycles of fuel in nuclear reactors. Oxide layers formed on ZIRLO4^{TM}$ cladding samples, after immersion for 300-hour and 50-day in a simulated primary water chemistry condition ($360^{\circ}C$ and 20 MPa), were analyzed by using the scanning transmission electron microscopy (STEM), in-situ transmission electron microscopy (in-situ TEM) with the focused ion beam (FIB) technique, and X-ray diffraction (XRD). Both samples (immersion for 300 hours and 50 days) revealed the presence of the ZrO sub-oxide phase at the metal/oxide interface and columnar grains developed perpendicularly to the metal/oxide interface. Voids and micro-cracks were also detected near the water/oxide interface, while relatively large lateral cracks were found just above the less advanced metal/oxide interface. Equiaxed grains were mainly observed near the water/oxide interface.

Effect of Scale and Fuel Type on Heat-recirculating Swiss-roll Combustor Performance for Fuel Cell Reformer Applications (연료전지 개질기로 활용을 위한 스위스 롤 연소기의 크기와 연료의 종류에 따른 특성연구)

  • Kim, Youn-Ho;Huh, Hwan-Il;Ronney, Paul D.
    • Journal of the Korean Society of Propulsion Engineers
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    • v.15 no.1
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    • pp.11-18
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    • 2011
  • The geometrically similar swiss roll reactors of different physical sizes were tested with the aim of independently determining the effects of Re and Da. It is found that the difference between catalytic and non-catalytic combustions extinction limits are narrowed as scale decreases. In addition to assess the importance of fuel chemistry, different families of fuels including alkanes and ethers were tested. From these results the effect of scale and fuel type on microscale reactor performance and implications for practical micro combustion devices are discussed.

Experiment of CO Cleaning Process in DME Autothermal Reformate Gas for PEMFC Application (고분자 전해질 연료전지 적용을 위한 DME 자열개질가스 내 CO제거 공정 특성 연구)

  • Choi, Seung-Hyeon;Bae, Joong-Myeon
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.4
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    • pp.474-480
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    • 2011
  • Hydrocarbon is required to be converted to pure hydrogen without carbon monooxide (CO) for polymer exchange membran fuel cell (PEMFC) applications. In this paper, CO cleaning processes as the downstream of Dimethyl ehter (DME) autothermal reforming process were performed in micro-reactors. Our study suggested two kinds of water gas shift (WGS) reaction process: High Temperature shift (HTS) - Low Temperature shift (LTS), Middle temperature shift (MTS). Firstly, using perovskite catalyst for MTS was decreased effieiciency since methanation. Using HTS-LTS the CO concentration was decreased about 2% ($N_2$ & $H_2O$ free) with the reaction temperature of $420^{\circ}C$ and $235^{\circ}C$ for HTS and LTS, respectively. As the final stage of CO cleaning process, preferential oxidation (PROX) was applied. The amount of additional oxygen need 2 times of stoichiometric at $65^{\circ}C$. The total conversion reforming efficiency of 75% was gained.