• 제목/요약/키워드: Micro reactor

검색결과 178건 처리시간 0.082초

A New Detergentless Micro-Emulsion System Using Urushiol as an Enzyme Reaction System

  • Kim, John-Woo-Shik;Yoo, Young-Je
    • Journal of Microbiology and Biotechnology
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    • 제11권3호
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    • pp.369-375
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    • 2001
  • Urushiol, a natural monomeric oil, was used to prepare a detergentless micro-emulsion with water and 2-propanol The formation of micro-emulsion was verified by conductivity measurements and dynamic light scattering. The conductivity data showed phase change dynamics, a characteristics of micro-emulsions, and subsequent dynamic light scattering study further confirmed the phenomenon. Average water droplet diameter was 10 nm to 500 nm when the molar ratio of 2-propanol ranged from 0.40 to 0.44 . Earlier studies were performed on toluene and hexane, in which the insoluble substrate in water phase was added to the solvents to be reacted on by enzymes. However, in the present urushiol system, urushiol was used as both solvent and substrate in the laccase polymerization of urushiol. The laccase activity in the system was examined using polymerization of urushiol. The laccase activity in the system was examined using syringaldezine as a substrate, and the activity increased rapidly near the molar ratio of 2-propanol at 0.4, where micro-emulsion started. The activity rose until 0.46 and fell dramatically thereafter. The study of laccase activity in differing mole fractions of 2-propanol showed the existence of an ‘optimal zone’, where the activity of laccase was significantly higher. In order to analyze urushiol polymerization by laccase, a bubble column reactor using a detergentless micro-emulsion system was constructed. Comparative study using other organic solvents systems were conducted and the 2-propanol system was shown to yield the highest polymerization level. The study of laccase activity at a differing mole fraction of 2-propanol showed the existence of an ‘optimal zone’ where the activity was significantly higher. Also, 3,000 cP viscosity was achieved in actual urushi processing, using only 1/100 level of laccase present in urushi.

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Steam generator performance improvements for integral small modular reactors

  • Ilyas, Muhammad;Aydogan, Fatih
    • Nuclear Engineering and Technology
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    • 제49권8호
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    • pp.1669-1679
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    • 2017
  • Background: Steam generator (SG) is one of the significant components in the nuclear steam supply system. A variety of SGs have been designed and used in nuclear reactor systems. Every SG has advantages and disadvantages. A brief account of some of the existing SG designs is presented in this study. A high surface to volume ratio of a SG is required in small modular reactors to occupy the least space. In this paper, performance improvement for SGs of integral small modular reactor is proposed. Aims/Methods: For this purpose, cross-grooved microfins have been incorporated on the inner surface of the helical tube to enhance heat transfer. The primary objective of this work is to investigate thermal-hydraulic behavior of the proposed improvements through modeling in RELAP5-3D. Results and Conclusions: The results are compared with helical-coiled SGs being used in IRIS (International Reactor Innovative and Secure). The results show that the tube length reduces up to 11.56% keeping thermal and hydraulic conditions fixed. In the case of fixed size, the steam outlet temperature increases from 590.1 K to 597.0 K and the capability of power transfer from primary to secondary also increases. However, these advantages are associated with some extra pressure drop, which has to be compensated.

연소중 미분탄의 단면관측 (Cross-section micrography of burning pulverized coal particles)

  • 한재현;최상민
    • 대한기계학회논문집
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    • 제13권4호
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    • pp.717-725
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    • 1989
  • 본 연구에서는 미분탄의 연소과정을 파악하기 위하여 메탄-공기 예혼합 화염에서 연소중인 석탄입자를 단계별로 여러 위치에서 순간 냉각에 의해 채취한 후 단면을 관측함으로써 미분탄 연소과정의 해석을 시도하였다. 산소 함유량이 미분탄 연소에 미치는 영향을 고려하기 위하여 반응로에서의 연소 조건을 바꾸어 보았다. 또한 미분탄 연소과정의 이해를 돕기 위해 비분탄을 도가니에 넣어 전기 로에서 가열하여 얻은 챠르와 공기중에서 가열하여 얻은 회(ash)에 대한 단면을 관측하였다. 시험용 미분탄은 국내 발전소 등지에서 대량 소비되는 수입 유연탄을 사용하였다.

Prediction of Axial Solid Holdups in a CFB Riser

  • Park, Sang-Soon;Chae, Ho-Jeong;Kim, Tae-Wan;Jeong, Kwang-Eun;Kim, Chul-Ung;Jeong, Soon-Yong;Lim, JongHun;Park, Young-Kwon;Lee, Dong Hyun
    • Korean Chemical Engineering Research
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    • 제56권6호
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    • pp.878-883
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    • 2018
  • A circulating fluidized bed (CFB) has been used in various chemical industries because of good heat and mass transfer. In addition, the methanol to olefins (MTO) process requiring the CFB reactor has attracted a great deal of interest due to steep increase of oil price. To design a CFB reactor for MTO pilot process, therefore, we has examined the hydrodynamic properties of spherical catalysts with different particle size and developed a correlation equation to predict catalyst holdup in a riser of CFB reactor. The hydrodynamics of micro-spherical catalysts with average particle size of 53, 90 and 140 mm was evaluated in a $0.025m-ID{\times}4m-high$ CFB riser. We also developed a model described by a decay coefficient to predict solid hold-up distribution in the riser. The decay coefficient developed in this study could be expressed as a function of Froude number and dimensionless velocity ratio. This model could predict well the experimental data obtained from this work.

Techno-economic assessment of a very small modular reactor (vSMR): A case study for the LINE city in Saudi Arabia

  • Salah Ud-Din Khan;Rawaiz Khan
    • Nuclear Engineering and Technology
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    • 제55권4호
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    • pp.1244-1249
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    • 2023
  • Recently, the Kingdom of Saudi Arabia (KSA) announced the development of first-of-a-kind(FOAK) and most advanced futuristic vertical city and named as 'The LINE'. The project will have zero carbon dioxide emissions and will be powered by clean energy sources. Therefore, a study was designed to understand which clean energy sources might be a better choice. Because of its nearly carbon-free footprint, nuclear energy may be a good choice. Nowadays, the development of very small modular reactors (vSMRs) is gaining attention due to many salient features such as cost efficiency and zero carbon emissions. These reactors are one step down to actual small modular reactors (SMRs) in terms of power and size. SMRs typically have a power range of 20 MWe to 300 MWe, while vSMRs have a power range of 1-20 MWe. Therefore, a study was conducted to discuss different vSMRs in terms of design, technology types, safety features, capabilities, potential, and economics. After conducting the comparative test and analysis, the fuel cycle modeling of optimal and suitable reactor was calculated. Furthermore, the levelized unit cost of electricity for each reactor was compared to determine the most suitable vSMR, which is then compared other generation SMRs to evaluate the cost variations per MWe in terms of size and operation. The main objective of the research was to identify the most cost effective and simple vSMR that can be easily installed and deployed.

조사시험용 핵연료봉 용접부 비파괴검사에 관한 연구 (A Study on the Non-destructive Inspection for End Closure Welding of Nuclear Fuel Elements for the Irradiation Test)

  • 김웅기;김수성;이철용;이도연;이정원
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2004년도 춘계 학술발표대회 개요집
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    • pp.302-304
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    • 2004
  • Nuclear fuel elements containing dry recycling nuclear fuel pellets for the irradiation test in a reactor were remotely fabricated from spent PWR fuel materials in a hot cell. End closure welding as well as seal tube welding for thermal sensor of the elements was performed by Nd:YAG laser. The soundness of the end closure welds and seal tube welds for the elements were evaluated by a precise X-ray inspection system composed of a micro-focus X-ray generator with an image intensifier and a real time camera system. Then, helium leak test was performed for the elements. The soundness of the welds of the fuel elements was confirmed by the X-ray inspection and helium leak test. The irradiation test for the fuel elements were successfully completed at the HANARO research reactor.

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Inverter Air-conditioner Power System with Low Power Dissipation Type using Micro-controller

  • Mun, Sang-Pil;Shu, Ki-Young;Kim, Ju-Yong;Kim, Kwang-Tae
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2004년도 춘계학술대회 논문집
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    • pp.492-496
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    • 2004
  • When using a conventional power factor correction circuit, a comparatively huge capacitor is used to boost-up output voltage. It has a large amount of harmonic distortion in the input current waveform. To improve the input current waveform of diode rectifiers, we propose a new operating principle for the power factor correction circuit. Due to the fact that the proposed circuit uses smaller ones and a smaller reactor, the output voltage increases and obtains higher input current waveforms. These are suitable for the harmonics guidelines. The proposed circuit is able to obtain higher power factor and efficiency. Also, it has reduced switching loss and held over-shooting by using an inverter of eliminated dead-time HPWM that has non-linear impedance circuits to make up diodes, capacitance and a reactor. We compared the conventional PWM inverter and proposed HPWM inverters and found that a high input power factor of 97[%] and an efficiency of 98[%] were also obtained.

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Multi-step Reactions on Microchip Platform Using Nitrocellulose Membrane Reactor

  • Park, Sung-Soo;Joo, Hwang-Soo;Cho, Seung-Il;Kim, Min-Su;Kim, Yong-Kweon;Kim, Byung-Gee
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제8권4호
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    • pp.257-262
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    • 2003
  • A straightforward and effective method is presented for immobilizing enzymes on a microchip platform without chemically modifying a micro-channel or technically microfabricating a column reactor and fluid channel network. The proposed method consists of three steps: the reconstitution of a nitrocellulose (NC) membrane on a plane substrate without a channel network, enzyme immobilization on the NC membrane, and the assembly of another substrate with a fabricated channel network. As a result, enzymes can be stably and efficiently immobilized on a microchip. To evaluate the proposed method, two kinds of enzymatic reaction are applied: a sequential two-step reaction by one enzyme, alkaline phosphatase, and a coupled reaction by two enzymes, glucose oxidase and peroxidase, for a glucose assay.

호흡률 및 송풍기 제어 기반 포기조 최적 DO 농도 설정과 전력 비용 절감 연구 (Optimal DO Setpoint Decision and Electric Cost Saving in Aerobic Reactor Using Respirometer and Air Blower Control)

  • 이광수;김민한;김종락;유창규
    • Korean Chemical Engineering Research
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    • 제52권5호
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    • pp.581-586
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    • 2014
  • 하수처리장을 운영함에 있어 안정적인 방류수질 확보와 이에 따른 처리 비용을 최소화하는 것이 주요 목적이다. 하지만 유입수 유량 및 성분 농도의 변화와 미생물의 비선형적인 동특성, 기타 환경 요인에 의해서 최적의 운전 제어를 하기가 쉽지 않기 때문에, 기존의 하수처리장에서는 필요한 양 이상의 폭기 및 화학물질을 과량 주입하는 방법 등을 사용하였다. 본 연구에서는 포기조에서 미생물에 필요한 용존산소농도는 유지하면서 과폭기로 인한 전력 비용을 감소하는 최적 제어 방법을 제안하였다. 하수조성와 포기조 미생물의 호흡률은 실시간 미생물 호흡률 측정기(Oxygen uptake rate, OUR)를 이용하여 측정하였고, 실시간 호흡률 측정값을 바탕으로 현재 미생물에 필요한 최적 DO 농도를 제안하였다. 유입수 부하변동에 따라 변화하는 미생물 호흡에 필요한 산소량 만큼만 폭기하도록 구성함으로써, 방류수 수질기준을 만족함과 동시에 전력 비용을 최소화할 수 있는 방안을 제시하였다.

미세액적 유동반응기 공정에서 연속제조된 나노구조 SiO2:Zn 원환형 입자의 특성 (Characteristics of Nano-structured SiO2:Zn Hollow Powders Prepared in the Micro Drop Fluidized Reactor (MDFR) Process)

  • 양시우;강용;강호
    • Korean Chemical Engineering Research
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    • 제56권4호
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    • pp.585-591
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    • 2018
  • 미세액적 유동반응기 공정에서 제조된 나노구조 $SiO_2:Zn$ 원환형 입자의 특성을 밴드갭 에너지와 표면 반응성의 관점에서 고찰하였다. $SiO_2:Zn$ 원환형 입자를 단일 공정에서 연속적이며 합리적인 생산 효율로 첨가제인 THAM (tris(hydroxymethyl)-aminomethane)과 도핑되는 $Zn^{2+}$ 이온의 농도 변화에 따라 성공적으로 제조할 수 있었다. 그리고 $Zn^{2+}$ 이온의 도핑은 $Si^{4+}$ 이온의 conduction band 보다 에너지 레벨이 낮은 $Zn^{2+}$ 이온의 acceptor level을 형성함으로써 $SiO_2:Zn$ 원환형 입자의 밴드갭 에너지를 줄일 수 있었다. 또한, 입자의 원환형 구조는 $SiO_2:Zn$ 입자의 밴드갭 에너지를 감소시키는데 기여하였다. 따라서 $Zn^{2+}$ 이온이 도핑된 $SiO_2:Zn$ 원환형 입자는 표면에 SiO-H의 형성과 산소 결함의 생성으로 표면 반응성을 증대시킬 것으로 사료되었다.