• Title/Summary/Keyword: Micro Pore

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Characterization of metal-containing activated carbon derived from phenolic resin (페놀 수지로부터 유도된 금속이 함유된 활성탄의 특성화)

  • Oh, Won-Chun;Jang, Won-Cheoul;Kim, Bum-Soo
    • Analytical Science and Technology
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    • v.14 no.4
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    • pp.349-355
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    • 2001
  • A series of micro- and mesoporous activated carbons were prepared from phenolic resin using a metal treated chemical activation methodology. $N_2$-adsorption data were used to characterize the surface properties of the produced activated carbons. Results of the surface properties and pore distribution analysis showed that phenolic resin can be successfully converted to micro- and mesoporous activated carbons with specific surface areas higher than $962.3m^2/g$. Activated carbons with porous structure were produced by controlling the amount of metal chlorides($CdCl_2$, $CuCl_2$). Pore evolvement was shown to be most effected by the incremental addition of metal chloride. From the thermodynamic DSC data, enthalpy formations(${\Delta}H$) of first endothermic reaction were increase with the incremental addition of metal chloride.

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Tensile Behavior of Ultra-High Performance Concrete According to Combination of Fibers (섬유 조합에 따른 초고성능 콘크리트의 인장거동)

  • Choi, Jung-Il;Koh, Kyung-Taek;Lee, Bang-Yeon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.4
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    • pp.49-56
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    • 2015
  • Ultra-High Strength Concrete(UHPC) has ultra-high material performance including high strength and high flowability. On the other hand it is less ductile than high ductile fiber reinforced cementitious composite. This study investigated the effect of combination of steel fiber and micro fiber on the tensile behavior of UHPC. Four types of UHPC containing combination of steel fiber, polyethylene(PE), polyvinyl alcohol(PVA), and basalt fiber were designed. And then uniaxial tension tests were performed to evaluate the tensile behavior of UHPC according to combination of fibers. And density was measured to evaluate whether micro fiber induces unintentional high pore or not. From the test results, it was exhibited that PE fiber with high strength is effective to improve the tensile behavior of UHPC and basalt fiber is effective to increase the cracking and tensile strength of UHPC. Furthermore, it was also verified that micro fiber does not make high pore.

Performance Enhancement of Gas-Liquid Mixed Plasma Discharge System using High Speed Agitation (고속 교반을 이용한 기-액 혼합 플라즈마방전 시스템의 성능 향상)

  • Park, Young-Seek
    • Journal of Environmental Science International
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    • v.26 no.6
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    • pp.711-717
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    • 2017
  • Dielectric Barrier Discharge (DBD) plasma is a new technique for use in environmental pollutant degradation, which is characterized by the production of hydroxyl radicals as the primary degradation species. Due to the short lifetime of the chemically active species generated during the plasma reaction, the dissolution of the plasma gas has a significant effect on the reaction performance. The plasma reaction performance can be enhanced by combining the basic plasma reactor with a homogenizer system in which the bubbles are destroyed and turned into micro-bubbles. For this purpose, the improvement of the dissolution of plasma gas was evaluated by measuring the RNO (N-dimethyl-4-nitrosoaniline, an indicator of the generation of OH radicals). Experiments were conducted to evaluate the effects of the diameter, rotation speed, and height of the homogenizer, pore size, and number of the diffuser and the applied voltage on the plasma reaction. The results showed that the RNO removal efficiency of the plasma reactor combined with a homogenizer is two times higher than that of the conventional one. The optimum rotor size and rotation speed of the homogenizer were 15.1 mm, and 19,700 rpm, respectively. Except for the lowest pore size distribution of $10-16{\mu}m$, the pore size of the diffuser showed little effect on RNO removal.

Influence of Heating Rate and Temperature on Carbon Structure and Porosity of Activated Carbon Spheres from Resole-type Phenolic Beads

  • Singh, Arjun;Lal, Darshan
    • Carbon letters
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    • v.10 no.3
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    • pp.181-189
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    • 2009
  • Activated carbon spheres (ACS) were prepared at different heating rates by carbonization of the resole-type phenolic beads (PB) at $950^{\circ}C$ in $N_2$ atmosphere followed by activation of the resultant char at different temperatures for 5 h in $CO_2$ atmosphere. Influence of heating rate on porosity and temperature on carbon structure and porosity of ACS were investigated. Effect of heating rate and temperature on porosity of ACS was also studied from adsorption isotherms of nitrogen at 77 K using BET method. The results revealed that ACS have exhibited a BET surface area and pore volume greater than $2260\;m^2/g$ and $1.63\;cm^3/g$ respectively. The structural characteristics variation of ACS with different temperature was studied using Raman spectroscopy. The results exhibited that amount of disorganized carbon affects both the pore structure and adsorption properties of ACS. ACS were also evaluated for structural information using Fourier Transform Infrared (FTIR) Spectroscopy. ACS were evaluated for chemical composition using CHNS analysis. The ACS prepared different temperatures became more carbonaceous material compared to carbonized material. ACS have possessed well-developed pores structure which were verified by Scanning Electron Microscopy (SEM). SEM micrographs also exhibited that ACS have possessed well-developed micro- and meso-pores structure and the pore size of ACS increased with increasing activation temperature.

Description of Feeding Apparatus and Mechanism in Nemopilema nomurai Kishinouye (Scyphozoa: Rhizostomeae)

  • Lee, Hye-Eun;Yoon, Won-Duk;Lim, Dong-Hyun
    • Ocean Science Journal
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    • v.43 no.1
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    • pp.61-65
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    • 2008
  • Feeding apparatus, mechanism and passage of ingested prey were described for Nemopilema nomurai (Scyphozoa: Rhizostomeae). N. nomurai medusae without central mouths have developed complicated canal systems connecting the tip of the tentacle and oral arm to the gut cavity. The number of junctions in the canal system increases with the bell diameter. The prey is gathered by paralyzing nematocyst at the tentacles and by adhering cirri at the oral arms and scapulets. They are engulfed into the terminal pore located at the oral arms and scapulets, and entered into the gut cavity via the canal system. The estimated digestion time is 1 hour and 20 min. The diameter of terminal pore is always about 1 mm, implying that they could not eat prey larger than that pore size. On the other hand, ephyrae have central mouths and could swallow prey as large as adults could. Exploitation of the same size of food by adult and ephyra implies that N. nomurai can affect seriously the whole food web, massively ingesting micro- and mesozooplankton and cutting the energy transfer toward the higher level of carnivores.

Plasma Electrolytic Oxidation of Ti-25Ta-xHf for Dental Implants (치과임플란트용 Ti-25Ta-xHf 합금의 플라즈마 전해 산화)

  • Kim, Jeong-Jae;Choe, Han-Cheol
    • Journal of Surface Science and Engineering
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    • v.51 no.6
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    • pp.344-353
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    • 2018
  • Plasma electrolytic oxidation of Ti-25Ta-xHf alloy in electrolyte containing Ca and P for dental implants was investigated using various experimental techniques. Ti-25Ta-xHf (x=0 and 15 wt.%) alloys were manufactured in an arc-melting vacuum furnace. Micropores were formed in PEO films on Ti-25Ta-xHf alloys in 0.15 M calcium acetate monohydrate + 0.02 M calcium glycerophosphate at 240 V, 270 V and 300 V for 3 min, respectively. The microstructure of Ti-25Ta-xHf alloys changed from (${\alpha}^{\prime}+{\alpha}^{{\prime}{\prime}}$) phase to (${\alpha}^{{\prime}{\prime}}+{\beta}$) phase by addition of Hf. As the applied potential increased, the number of pore and the area ratio of occupied by micro-pore decreased, whereas the pore size increased. The anatase phase increase as the applied potential increased. Also, the crystallite size of anatase-$TiO_2$ can be controlled by applied voltage.

Fabrication of Micro-Heatsink using Nanotemplate (나노 템플레이트를 이용한 마이크로 히트 싱크)

  • 함은주;손원일;홍재민
    • Journal of the Microelectronics and Packaging Society
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    • v.10 no.1
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    • pp.7-11
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    • 2003
  • The semiconductor chips or electronic components generate heat, which causes malfunction of the parts when it was not cooled properly. Bulky heat sink and cooling fan are used to get rid of the heat. However, with this bulky system, it is hard to integrate the electronics system in a small scale. The cooling efficiency of the system depends on the surface area of the heat sink, thermal conductivity of the material and the method of integration. In order to develop a novel cooling system, a micro-heatsink with a large surface area while retaining small volume was fabricated by electroless deposition of gold/copper inside a Track-etched membrane. The structure of the micro-heatsink was investigated using SEM or optical microscope. It was also found that the micro-heatsink is more efficient than a flat copper plate.

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Adsorption Properties of Demineralized Activated Carbon (세정 활성탄의 흡착특성)

  • 김정열;신창호;서문원;김영호;이근희;지상운
    • Journal of the Korean Society of Tobacco Science
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    • v.18 no.1
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    • pp.85-91
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    • 1996
  • Commercially available activated carbon was treated with 0.2N NaOH/0.1N HCl to decrease the ash contents and to analyze the effect of demineralization. We have studied their properties and adsorptivity to solvents such as benzene, acetone, toluene and carbon tetrachloride, ammonia and also aldehydes of cigarette smoke. By demineralization with NaOH/HCl, surface area and pore volume were increased up to 10 - 20% according to developement of micro-pore and pH of activated carbon was also changed from 10.2 to 6.3. Surface acidity of the activated carbon treated with chemicals increased slightly. The chemical treatment led to small increase in adsorptioil properties of solvents, ammonia and aldehydes of cigarette smoke, but content of chlorine and sulfur in activated carbon were reduced. As the results of smoking test, charcoal taste caused by the activated carbon was reduced significantly by the treatment with NaOH/HCl.

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Microstructure and Mechanical Properties of Co-Cr-Mo alloy for CAD/CAM Applications fabricated by Powder Metallurgy Process (분말야금공법으로 제조된 CAD/CAM용 Co-Cr-Mo 합금의 미세조직 및 기계적 특성)

  • Cha, Sung-Soo
    • Journal of Technologic Dentistry
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    • v.37 no.4
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    • pp.235-242
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    • 2015
  • Purpose: The aims of this study are compare with microstructure and mechanical properties of Co-Cr-Mo alloys fabricated by powder metallurgy(P/M) process and casting process respectively. Methods: Microstructure and micro-hardness were tested by SEM and Vickers Hardness Tester. The sintered specimen was produced by furnace-coolling after sintering, however the casting specimen were produced thru air-cooling and water-cooling after the casting. For observation of phase transformation during sintering, DSC analyzing was carried out. Results: Mean pore size of sintered Co-Cr-Mo alloy was $4.32{\mu}m$ and that of casting alloy was $1.63{\mu}m$. Hardness of sintered alloy was lower than water-quenched casting alloy. Conclusion: Proper sintering temperature of Co-Cr-Mo alloy was above $1,200^{\circ}C$ and pore size of casting specimen were finer than sintered specimen, but hardness were similar.

Effect of Curing Condition in Early Age on Variation of Pore Structure and Carbonation of Fatigued Mortar (초기양생조건이 피로를 받은 모르터의 세공구조와 중성화의 변화에 미치는 영향)

  • ;Tanaka Kyoji
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.659-664
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    • 2001
  • This paper was studied to effects of fatigue by low flexural load on micro structures and carbonation of mortar. Mortar specimens cured at various conditions were first subjected to bending repeated loads, and it was made clear that insufficient cure reduced fatigue resistance of them. Next, fatigue tests that the stress levels are lower than the ones of fatigue rupture were carried out, The effect of curing conditions in early age on carbonation was furthermore studied using the scale, and it was made clear that insufficient cure is also susceptible to carbonation of them. Finally, the reason for rapid carbonation of fatigued mortars insufficiently outed was discussed from the view point of changes in pore structure of them.

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