• Title/Summary/Keyword: Mg-alloy

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Resistance Spot Welding Characteristics of Mg Alloy Using Process Tape (Process Tape를 사용한 마그네슘 합금의 저항 점 용접 특성)

  • Choi, Dong-Soon;Kim, Dong-Cheol;Kang, Moon-Jin
    • Journal of Welding and Joining
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    • v.31 no.3
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    • pp.49-53
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    • 2013
  • Recently, studies about application of magnesium alloy sheet to automotive bodies are on the increase. For application to automotive bodies, researches about characteristics of resistance spot welding of magnesium alloy sheet are essential. Electrode life of resistance spot welding of magnesium alloy is very short due to sticking of magnesium alloy to copper alloy electrode. To increase electrode life, most effective method is inserting cover plate between electrode and magnesium sheet. But application of cover plate to actual process is difficult and decreases welding productivity. Process tape supplied automatically as cover plate can minimize lose of productivity and increase welding quality. In this study, resistance spot welding of magnesium alloy is carried out with applying process tape. Acceptable welding current region according to electrode force and welding time is determined.

Synthesis of Mg2Ni by mechanical alloying and its electrochemical characteristics for Ni-MH secondary battery (Ni-MH 2차 전지용 Mg2Ni의 기계적 합금화법에 의한 제조 및 전기화학적 특성)

  • Moon, Hong-Gi;Choi, Seung-Jun;Kim, Dae-Hwan;Park, Choong-Nyeon
    • Journal of Hydrogen and New Energy
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    • v.10 no.4
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    • pp.225-232
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    • 1999
  • The $Mg_2Ni$ hydrogen storage alloys which have much higher theoretical discharge capacity than $AB_5$ and $AB_2$ type alloys were synthesized by mechanical alloying with some additives and subjected to the electrochemical measurements. Two different processes were employed to the synthesis of $Mg_2Ni$ alloys with using the high energy ball mill SPEX 8000. One was only ball milling, 12 hrs, the Mg and Ni powders for 12 hrs with additives such as $AB_5$, Ni, Co and Cu powders. In the other process the Mg and Ni powders were ball milled for 1 hr first and then heat treated at $300{\sim}400^{\circ}C$ for 1 hr to get $Mg_2Ni$ alloy, and finally the $Mg_2Ni$ alloy powders were ball milled with the additives for 12 hrs. The alloy powders prepared were compacted at room temperature under $7.64tons/cm^2$ into disk type electrodes for the electrochemical measurements. The experimntal results showed that the electrodes prepared with the heat treated alloy powders had a higher discharge capacities than those without heat treatment. The addition of Ni caused an increase of the discharge capacity and the addition of Co improved the cycling characteristics. The electrode prepared by ball milling of $Mg_2Ni$ and 10wt% Ni powders has showed the highest discharge capacity, 546mAh/g.alloy, which was 55% of the theoretical capacity.

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Formation of Anodic Films on Pure Mg and Mg alloys for Corrosion Protection

  • Moon, Sungmo;Nam, Yunkyung
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.11a
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    • pp.16-16
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    • 2012
  • Mg and its alloys have been of great interest because of their low density of 1.7, 30% lighter than Al, but their wide applications have been limited because of their poor resistances against corrosion and/or abrasion. Corrosion resistance of Mg alloys can be improved by formation of anodic films using anodic oxidation method in aqueous electrolytes. Plasma electrolytic oxidation (PEO) is one of anodic oxidation methods by which hard anodic films can be formed as a result of micro-arc generation under high electric field. PEO method utilize not only substrate elements but also chemical components in electrolytes to form anodic films on Mg alloys. PEO films formed on AM50 magnesium alloy in an acidic fluozirconate electrolyte were observed to consist of mainly $ZrO_2$ and $MgF_2$. Liu et al reported that PEO coating on AM30 Mg alloy consists of $MgF_2$-rich outer porous layer and an MgO-rich dense inner layer. PEO films prepared on ACM522 Mg die-casting alloy in an aqueous phosphate solution were also reported to be composed of monoclinic $Mg_3(PO_4)_2$. $CeO_2$-incorporated PEO coatings were also reported to be formed on AZ31 Mg alloys in $CeO_2$ particle-containing $Na_2SiO_3$-based electrolytes. Magnesium tin hydroxide ($MgSn(OH)_6$) was also produced on AZ91D alloy by PEO process in stannate-containing electrolyte. Effects of $OH^-$, $F^-$, $PO{_4}^{3-}$ and $SiO{_3}^{2-}$ ions and alloying elements of Al and Sn on the formation of PEO films on pure Mg and Mg alloys and their protective properties against corrosion have been investigated in this work. $PO{_4}^{3-}$, $F^-$ and $SiO{_3}^{2-}$ ions were observed to contribute to the formation of PEO films but $OH^-$ ions were found to break down the surface films under high electric field. The effect of pulse current on the formation of PEO films will be also reported.

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Mechanical Properties of Rapidly Solidified Mg-Zn Base Alloys (급냉응고된 Mg-Zn계 합금의 기계적 성질)

  • Kim, Yeon-Wook
    • Journal of Korea Foundry Society
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    • v.18 no.5
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    • pp.462-466
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    • 1998
  • Interest in rapid solidification of magnesium alloys stems from the fact that conventional ingot metallurgy alloys exhibit poor strength, ductility, and corrosion resistance. Such properties can be improved by microstructural refinement via rapid solidification processing. Mg-5wt%Zn alloys have been produced as continuous strips by melt overflow technique and the strips were consolidated by hot extrusion. The yield stress, tensile strengh and ductility obtained in asextruded Mg-5wt%Zn alloy were ${\sigma}_{0.2}=152\;MPa$, ${\sigma}_{T.S{\cdot}}=263\;MPa$ and ${\varepsilon}=21.8%$. In order to evaluate the influence of additional elements on mechanical properties, Th and Zr were added in rapidly solidified Mg-5wt%Zn alloy. An 130% increase in yield stress of as-extruded Mg-5wt%Zn-3wt%Th-1wt%Zr alloy was attributed to grain refinement by rapid solidification and elemental addition.

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Damping Capacity of Heat-Treated Mg-Nd Alloy (열처리한 Mg-Nd 합금의 진동감쇠능)

  • Jun, Joong-Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.26 no.4
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    • pp.185-190
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    • 2013
  • Influence of solution treatment (T4) and peak-aging (T6) on damping capacity was investigated in permanent-mold cast Mg-3%Nd alloy. In as-cast state, the microstructure was characterized by eutectic $Mg_{12}Nd$ intermetallic phase network in the intergranular region. T4 treatment resulted in a dissolution of the eutectic particles, but small amount of the particles still remained in the microstructure. After T6 treatment, nano-sized ${\beta}^{\prime}(Mg_{12}Nd)$ particles were precipitated within the matrix. T4 microstructure showed higher damping capacity than as-cast and T6 ones. In view of the microstructural features, this may well be associated with the dissolution of second-phase particles which play a role in pinning the dislocations acting as a damping source.

Microstructure and Mechanical Properties of Mg-Zn-Y-Yb Alloys Produced by Consolidation of Rapidly Solidified Ribbons

  • Sakamoto, Yoshihito;Yamasaki, Michiaki;Kawamura, Yoshihito
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1045-1047
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    • 2006
  • Fabrication of $Mg_{95.75}Zn_1Y_3Yb_{0.25}$ bulk alloy has been performed through the consolidation of rapidly solidified ribbons. The $Mg_{95.75}Zn_1Y_3Yb_{0.25}$ bulk alloy exhibited excellent mechanical properties, high tensile yield strength of 530 MPa, and large elongation of 3 %. Microstructure of the alloy was characterized by equiaxed fine grains that consist of -Mg, long period ordered (LPO) structure phase, and $Mg_5RE$-type cubic compound. The strengthening of the alloys may be due to fine grains with LPO structure phase and $Mg_5RE$-type compound.

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