• Transactions of Materials Processing
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• v.22 no.2
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• pp.108-113
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• 2013

This paper demonstrates the lubricant performance in T-shape hot forging of Mg alloys. This processes induces complex plastic material flow of the initial billet such as simultaneous compression and extrusion deformations. Five lubricants with different amounts of graphite are applied to the T-shape forging at temperatures of 300 and $350^{\circ}C$. As the amount of graphite in the lubricant increases, the extruded depth gradually increases, which improves hot forgeability for Mg alloys. However, the lubricant performance decreases as forging temperature increases from 300 to $350^{\circ}C$. As the punch stroke increases, forgeability is considerably influenced by the lubricant. Thus, the selection of lubricants in hot forging of Mg alloys is critical when plastic deformation is severe.

• Journal of Korea Foundry Society
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• v.9 no.6
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• pp.474-482
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• 1989

The aim of this research is to investigate the effects of gas bubbles on the formation of spheroidal graphite in cast iron, Fe-Si-8%Mg alloy, mischmetal hydride($MmH_2$) and $CaCO_3$, which discharge various amounts of Mg, $H_2$ and $Co_2$, gases, were added to Fe-3.9% C-2.0%Si melt and the melt was innoculated with 0.3wt% of 75%Fe-Si. The spheroidal graphites and/or compacted vermicular graphites were produced with more than 0.625cc/g of Mg gas or more than 0.3125cc/g of $H_2$ gas while $CO_2$ gas did not contribute to graphite spheroidization. Nodule counts increased with the amount of Fe-Si-Mg added ; but they decreased with the amount of $MmH_2$ added because the number of effective gas bubbles decrease with the increase in Mm residual. The bull's eye structure was revealed with 0.625cc/g, 1.25cc/g of Mg and 0.3125cc/g of $H_2$ ; the ledeburite structure was revealed with more than 0.625cc/g of $H_2$.

• Journal of Korea Foundry Society
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• v.3 no.4
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• pp.239-247
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• 1983

CV graphite cast iron has been studied and generally known to have properties close to the average values of those between flake and spheroidal graphite cast iron. However, the thermal diffusivity of CV graphite cast iron is much larger than that of the average value of those between flake and spheroidal graphite cast iron. In this study, an easy production method of CV graphite cast iron with small additions of a Al-Cu which is known as the element of the graphitization was investigated. The effects of hold time and of Al-Cu additions after the treatments with spheroidizer (Fe-Si-Mg alloy) were also investigated. Increasing the additions of a Al-Cu alloy, the holding time to form a CV graphite cast iron was decreasing. Tensile strength and thermal diffusivity (flash method) were measured in order to find the changes of the mechanical properties and the physical properties. Spheroidal, CV, and flake graphite cast iron have tensile strengths 46.44, 38.29, and $27.29\;kg/mm^2$ and thermal diffusivities $3.95{\times}10^{-6,}$ $8.41{\times}10^{-6}$, $8.81{\times}10^{-6}m^2/sec$, respectively at room temperature.

• Journal of Korea Foundry Society
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• v.5 no.3
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• pp.19-26
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• 1985

This study has been carried out to examine into wettability of Cu-5%Sn alloy in $Al_2O_3$, MgO, $SiO_2$ and graphite, respectively and investigated into the change in macrostructure of Cu-5%Sn alloy according to kind and mixing rate of mold-coating. The results obtained from the experiment are summerized as follows; 1. Cu Cu-5%Sn alloy, wettabilities of $Al_2O_3$ and MgO were good, on the other hand, wettabilities of $SiO_2$ and graphite were bad. 2. The fine equiaxed zone was created because of the role of $Al_2O_3$ and MgO as preferential nucleation sites. 3. Notwithstanding change of mixing rate of $SiO_2$ in mold coating the equixed zone was not created. 4. The area of equiaxed zone was varied according to mixing rate in the case of using $Al_2O_3$ and MgO in mold-coating.

• Journal of Environmental Science International
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• v.29 no.4
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• pp.383-393
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• 2020

To increase electrolysis performance, the applicability of seawater to the iron-fed electro-Fenton process was considered. Three kinds of graphite electrodes (activated carbon fiber-ACF, carbon felt, graphite) and dimensionally stable anode (DSA) electrode were used to select a cathode having excellent hydrogen peroxide generation and organic decomposition ability. The concentration of hydrogen peroxide produced by ACF was 11.2 mg/L and those of DSA, graphite, and carbon felt cathodes were 12.9 ~ 13.9 mg/L. In consideration of durability, the DSA electrode was selected as the cathode. The optimum current density was found to be 0.11 A/㎠, the optimal Fe²⁺ dose was 10 mg/L, and the optimal ratio of Fe²⁺ dose and hydrogen peroxide was determined to be 1:1. The optimum air supply for hydrogen peroxide production and Rhodamine B (RhB) degradation was determined to be 1 L/min. The electro-Fenton process of adding iron salt to the electrolysis reaction may be shown to be more advantageous for RhB degradation than when using iron electrode to produce hydrogen peroxide and iron ion, or electro-Fenton reaction with DSA electrode after generating iron ions using an iron electrode.

• Environmental Engineering Research
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• v.21 no.3
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• pp.247-255
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• 2016

Ten trace elements (Mg, Ca, V, Cr, Mn, Fe, Cu, Zn, Mo, and Cd) were determined in seven traditionally used wild medicinal plants of the Nagas in the North-East India viz Cynoglossum furcatum Wallich, Elsholtzia blanda Bentham, Lycopodium cernuum Linnaeus, Potentilla fulgens Wallich ex Hooker, Swertia macrosperma C.B. Clarke, Thalictrum foliolosum DC and Valeriana jatamansi Jones. Plant samples were dried, weighed, digested and analyzed for their mineral distribution level ranging from trace to major elements by graphite furnace-atomic absorption spectroscopy. All the medicinal herbs studied were found to contain the ten elements analyzed. The elemental concentration is given in mg/kg. Mg and Ca are present in high concentrations in both the roots and leaves of the plant samples. Among trace transition metals Fe had the highest concentration, followed by Mn, Cr, Cu, V, Zn, and Mo. Analysis showed that the toxic Cd element was at a lower concentration and is within the permissible limit of FAO/WHO, California standards and United States Pharmacopeia Limit for Nutritional Supplements.

• Korean Journal of Chemical Engineering
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• v.35 no.12
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• pp.2442-2451
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• 2018

Novel highly active visible-light photocatalysts in the form of zinc bismuth oxide ($ZnBi_2O_4$) and graphite hybrid composites were prepared by coupling via a co-precipitation method followed by calcination at $450^{\circ}C$. The asprepared $ZnBi_2O_4$-graphite hybrid composites were tested for the degradation of rhodamine B (RhB) solutions under visible-light irradiation. The existence of strong electronic coupling between the two components within the $ZnBi_2O_4$-graphite heterostructure suppressed the photogenerated recombination of electrons and holes to a remarkable extent. The prepared composite exhibited excellent photocatalytic activity, leading to more than 93% of RhB degradation at an initial concentration of $50mg{\cdot}L^{-1}$ with 1.0 g catalyst per liter in 150 min. The excellent visible-light photocatalytic mineralization of $ZnBi_2O_4-1.0graphite$ in comparison with pristine $ZnBi_2O_4$ could be attributed to synergetic effects, charge transfer between $ZnBi_2O_4$ and graphite, and the separation efficiency of the photogenerated electrons and holes. The photo-induced $h^+$ and the superoxide anion were the major active species responsible for the photodegradation process. The results demonstrate the feasibility of $ZnBi_2O_4-1.0graphite$ as a potential heterogeneous photocatalyst for environmental remediation.

• Journal of Microbiology and Biotechnology
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• v.14 no.2
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• pp.324-329
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• 2004

Oxygen diffuses through the cation-specific membrane, reducing the coulomb yield of the fuel cell. In the present study, attempts were made to enhance current generation from the fuel cell by lowering the oxygen diffusion, including the uses of ferricyanide as a cathode mediator and of a platinum-coated graphite electrode. Ferricyanide did not act as a mediator as expected, but as an oxidant in the cathode compartment of the microbial fuel cell. The microbial fuel cell with platinum-coated graphite cathode generated a maximum current 3-4 times higher than the control fuel cell with graphite cathode, and the critical oxygen concentration of the former was 2.0 mg $1^{-1}$, whilst that of the latter was 6.6 mg $1^{-1}$. Based on these results, it was concluded that inexpensive electrodes are adequate for the construction of an economically feasible microbial fuel cell with better performance as a novel wastewater treatment process.

• Journal of the Korean Recycled Construction Resources Institute
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• v.12 no.1
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• pp.40-46
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• 2024

A novel approach is presented to address issues associated with the use of strong acidic solutions for the leaching of magnesium oxide (MgO) from spent magnesia-carbon refractories. An ultrasonic flotation and separation process is employed, with a mildly acidic solvent, acetic acid, used to selectively chelate MgO from the spent refractories. When using 2 M acetic acid as a solvent, the recovery of the graphite exhibited 99.7 % with high purity of 72.7 %, showing a significant improvement compared to using water as the solvent. Furthermore, the technology presented in this study offers a method for producing magnesium acetate through the reaction of MgO in spent refractory with acetic acid, providing a means for the purification and separation of graphite.

• Korean Journal of Materials Research
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• v.11 no.8
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• pp.679-684
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• 2001

The surface of natural graphite has not only good electrical conductivities and lubrication properties but also has strong hydrophobicity. There are no functional groups and chemical properties on it. It is difficult to join with any other ions and to disperse in aqueous system. In order to increase dispersion ability throughout modification of surface property, it is necessary to let graphite have some function on its surface by the adsorption of surfactant molecules. In this study, using zeta potential adsorbed surfactant molecules(ABDM) on graphite surface and its surface Properties turn hydrophobic into hydrophilic. The dispersing mechanism of graphite particles in aqueous system has been explained using the DLVO theory, It is concluded that the high dispersable graphite suspension of which dispersing stability$(T_{1/2})$ is 44.5 hours at pH 10 and 22.5mV zeta potential can be produced.