• Title/Summary/Keyword: Mg-Graphite

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Fabrication of Mg2Ni-Graphite hydrogen absorbing composites materials by M.A. using planetary mill (기계적 합금화법에 의한 Mg2Ni-Graphite 수소저장합금 제조)

  • Hong, Tae Whan;Ha, Won;Kim, Shae Kwang;Kim, Young Jig
    • Transactions of the Korean hydrogen and new energy society
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    • v.10 no.2
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    • pp.91-99
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    • 1999
  • Under Hydrogen atmosphere, composites of Mg-Ni-Graphite were prepared by mechanical alloying(M.A.) using planetary mill. Mechanically alloyed powders were analyzed by XRD, SEM and automatic PCT. From the results of XRD, Mg-Ni-Graphite Composites were obtained successfully after 168hrs M.A. By the PCT test, synthesized powders were absorbed 4.9 wt% hydrogen at 623K.

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Effect of Magnesium Nanoparticles on Graphite Oxide for Hydrogen Storage Behaviors (마그네슘입자가 담지된 그라파이트 옥사이드의 수소저장거동)

  • Lee, Seul-Yi;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.157.2-157.2
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    • 2011
  • In this work, we prepared Mg nanoparticles loaded graphite oxide (Mg-G) as a function of Mg content in order to investigate hydrogen storage behaviors. The structure and morphology of the Mg-G samples were characterized by X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM). The textural properties of the samples were evaluated using $N_2$/77 K adsorption isotherms. The hydrogen adsorption capacities were investigated at 298 K/10 MPa. As a result, the hydrogen adsorption capacities of the Mg-G were enhanced with increasing the Mg content. Therefore, it was found that the presence of Mg on graphite surfaces created hydrogen-favorable sites, resulting in enhancing the hydrogen adsorption capacity.

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The Hydrogen Production from the Hydrolysis of Mg-Graphite Pellet for Military Fuel Cells (군용 연료전지 적용을 위한 Mg-Graphite 펠렛의 가수분해 반응을 이용한 수소생산)

  • Park, Minsun;Yu, Minkyu;Kim, Jongsoo;Kwon, Hyuksang
    • Journal of the Korea Institute of Military Science and Technology
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    • v.18 no.2
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    • pp.160-166
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    • 2015
  • On board hydrogen generation from the hydrolysis of an active metal is very attractive due to its economical, convenient, and safe reasons. A Mg-graphite pellet has been designed as a hydrogen source for portable fuel cell. Mg (1 g) + 0.10 g graphite pellet showed an excellent hydrogen generation rate that is equivalent to 15.8 ml/g.min from its hydrolysis. The hydrogen generation rate of the pellet is significantly increased due to the galvanic corrosion by galvanic cells between Mg anode and graphite cathode in a 10.wt. % NaCl solution at a room temperature.

Electric Conduction Properties of NaCl Electrolyte as a Function of Electrode Materials (전극재료에 따른 NaCl 전해질의 전기전도특성)

  • Kim, Yong-Hyuk
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.11
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    • pp.2026-2031
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    • 2010
  • The electrical characteristics of galvanic cell which is composed of the cathode electrode(graphite, carbon and copper) and the anode electrode(Zn and Mg) were investigated. For this research as electrolyte 2~12 wt% NaCl aqueous solution were used. At graphite cathode electrodes which use Zn and Mg with the anode electrode, the open circuit voltage was 1.3V most highly. The maximum output power increased as the electrolyte concentration increased, due to a increase in ion density. When Zn and Mg with the anode electrode, the maximum output power respectively was evaluated as 2.2mW and 5.5mW about the graphite cathode electrode in the NaCl 4wt%. The research results indicated that the output power of cell which is composed with graphite with the cathode and Mg with the anode was most excellent and the efficiency of the cell could be enhanced by increasing the electrolyte concentration.

High temperature and damping properties of squeeze cast Mg hybrid Metal Matrix Composites. (하이브리드 Mg 복합재료의 진동 감쇠능 및 고온 특성평가)

  • 장재호;김봉룡;최일동;조경목;박익민
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.10a
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    • pp.143-146
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    • 2002
  • Mg alloy is the lightest material of structural materials and is noticed for lightweight automotive parts because of excellent castability, superior ductility and damping capacity than Al alloy. But Mg Alloy is poor corrosion resistance and high temperature creep properties. In this study, Mg Matrix Composites were fabricated by squeeze casting method to improve high temperature creep properties and damping capacity. Hybrid Mg composites reinforced with Alborex, graphite particle, and SiCp was improved creep properties and damping capacity compared with Mg alloy. Compared to the length ($9\mu\textrm{m}, 27\mu\textrm{m}, 45\mu\textrm{m} etc.$), Hybrid Mg composites reinforced with SiCp, one of the most superior of the length and Alborex were more superior than those reinforced with graphite particle and Alborex in mechanical properties, creep characteristics, and damping capacity, etc.

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A Study on the Solidification Characteristics of CV Graphite Cast Iron (CV흑연주철(黑鉛鑄鐵)의 응고특성(凝固特性)에 관한 연구(硏究))

  • Chun, C.C.;Kim, S.Y.;Lee, G.W.
    • Journal of Korea Foundry Society
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    • v.5 no.3
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    • pp.5-12
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    • 1985
  • Many researchers have studied the eutectic solidification of CV Graphite Cast Iron qualitatively. However quantative studies have not been done. The type of eutectic solidification of CV Graphite Cast Iron treated with CG Alloy (Fe-Si-Mg-5Ti-Ca-Ce) was studied quantitatively through M.D.E. value (Mushy Degree of Eutectic Solidification) = $t_2/t_1)$, where $t_1$ is the difference of the eutectic solidification starting time between surface and center part of the casting sample, and $t_2$ is the time of eutectic solidification of the center part. Following results were obtained. (1) The M.D.E. value of CV graphite cast iron lies between that of spheroidal graphite and that of flake graphite cast iron but is closer to that of Flake graphite cast iron. (2) The M.D.E. value of CV graphite cast iron depends upon CV ratio. (3) The time required for eutectic solidification increases as graphite form is changed from Flake, CV. to spheroidal graphite. (4) The M.D.E. value increases as cooling rate increases.

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Tribological Properties of Alumina/Graphite Composites (Alumina/graphite 복합체의 마찰마모 특성)

  • 백용혁;정종인;박용갑;김주영
    • Journal of the Korean Ceramic Society
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    • v.34 no.4
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    • pp.380-386
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    • 1997
  • The tribological properties of ceramics are very important in the application to engineering ceramic parts such as seal rings, pump parts, thread guides, and so on. In this study, the effects of graphite addition on the mechanical and tribological properties of alumina/graphite composites were investigated. The composites were prepared by the adding of graphite powder to the mixture of Al2O3, talc and calcium carbonate. Bending strength, water absorption, friction coefficient, the amount of worn out material at a certain time, and maximum surface roughness(Rmax) of the prepared composites were measured. Crystalline phases and microstructure were examined with XRD and SEM. The melt of Al2O3-CaO-MgO-SiO2 system was shown over 10 vol% graphite composition. As the amount of the graphite is increased, needle like crystals of mullite were formed and grown. We obtained the good properties of friction coefficients and wear resistance at the powder composition containing 15 vol% of graphite.

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Densification of matrix graphite for spherical fuel elements used in molten salt reactor via addition of green pitch coke

  • He, Zhao;Zhao, Hongchao;Song, Jinliang;Guo, Xiaohui;Liu, Zhanjun;Zhong, Yajuan;Marrow, T. James
    • Nuclear Engineering and Technology
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    • v.54 no.4
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    • pp.1161-1166
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    • 2022
  • Green pitch coke with an average particle size of 2 mm was adopted as densifier and added to the raw materials of conventional A3-3 matrix graphite (MG) to prepare modified A3-3 matrix graphite (MMG) by the quasi-isostatic molding method. The structure, mechanical and thermal properties were assessed. Compared with MG, MMG had a more compact structure, and exhibited improved properties of higher mechanical strength, higher thermal conductivity and better molten salt barrier performance. Notably, under the same infiltration pressure of 5 atm, the fluoride salt occupation of MMG was only 0.26 wt%, whereas it was 15.82 wt% for MG. The densification effect of green pitch coke endowed MMG with improved properties for potential use in the spherical fuel elements of molten salt reactor.

Hydrogenation Study of Mg-based Alloys by mechanical Grinding Reaction for Hydrogen Storage of Fuel Cell (연료전지의 수소저장용 마그네슘계 합금의 기계적 분쇄 반응에 의한 수소화 특성 평가)

  • Kim, Ho-Sung;Suh, Hee-Seok;Cha, Jae-Sang
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.6
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    • pp.69-74
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    • 2006
  • The effects of mechanical grinding(MG) treatment on the hydrogen storage of $Mg_2Ni$ alloy and $Mg_2Ni$ composite alloy($Mg_2Ni+graphite$) were investigated by pressure-composition-temperature(PCT) measurement, the micro-electrode technique of electrochemistry and etc, in which PCT was measured at high temperature(around $300[^{\circ}C]$) of gas phase and a carbon-filament micro-electrode for electrochemical evaluation was manipulated to make electrical contact with the particle in 1M KOH aqueous solution. It was found that the hydrogenation properties of $Mg_2Ni$ and graphite composite particle were greatly improved by the mechanical grinding treatment by which the $Mg_2Ni$ and graphite composite alloys could be changed into microstructure and nano-level particles. namely; the hydrogen dissociation pressure of PCT measurement was decreased from 0.55[MPa] to 0.42[MPa] and hydrogenation peaks by micro-electrode were also observed more clearly on the same sample.

Decolorization of a Rhodamine B Using Ru-graphite Electrode (Ru-흑연 전극을 이용한 Rhodamine B의 색 제거)

  • Park, Young-Seek
    • Journal of Environmental Science International
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    • v.17 no.5
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    • pp.547-553
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    • 2008
  • For the RhB removal from the wastewater, electrochemical method was adapted to this study. Three dimensionally stable anode (Pt, Ir and Ru) and graphite and Ru cathode were used. In order to identify decolorization, the effects of electrode, current density, electrolyte and air flow rate were investigated. The effects of electrode material, current, electrolyte concentration and air flow rate were investigated on the decolorization of RhB. Electro-Fenton's reaction was evaluated by added $Fe^{2+}$ and $H_2O_2$ generated by the graphite cathode. Performance for RhB decolorization of the four electrode systems lay in: Ru-graphite > Ru-Ru > Ir-graphite > Pt-graphite. A complete color removal was obtained for RhB (30 mg/L) at the end of 30 min of electrolysis under optimum operations of 2 g/L NaCl concentration and 2 A current. $Fe^{2+}$ addition increased initial reaction and decreased final RhB concentration. However the effect was not high.