• Title/Summary/Keyword: Mg particles

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Ballistic Properties of Zr-based Amorphous Alloy Surface Composites Fabricated by High-Energy Electron-Beam Irradiation (고에너지 전자빔 투사방법으로 제조된 Zr계 비정질 합금 표면복합재료의 탄도충격 성능)

  • Do, Jeonghyeon;Jeon, Changwoo;Nam, Duk-Hyun;Kim, Choongnyun Paul;Song, Young Buem;Lee, Sunghak
    • Korean Journal of Metals and Materials
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    • v.48 no.12
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    • pp.1047-1055
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    • 2010
  • The objective of this study is to investigate the ballistic properties of Zr-based amorphous alloy surface composites fabricated by high-energy electron-beam irradiation. The mixture of Zr-based amorphous powders and $LiF+MgF_2$ flux powders was deposited on a pure Ti substrate, and then an electron beam irradiated this powder mixture to fabricate a one-layer surface composite. A four-layer surface composite, in which the composite layer thickness was larger than 3 mm, was also fabricated by irradiating the deposited powder mixture by an electron beam three times on the one-layer surface composite. The microstructural analysis results indicated that a small amount of fine crystalline particles were homogeneously distributed in the amorphous matrix of the surface composite layer. According to the ballistic impact test results, the surface composite layers effectively blocked a fast traveling projectile, while many cracks were formed at the composite layers, and thus the surface composite plates were not perforated. The surface composite layer containing ductile ${\beta}$ dendritic phases showed a better ballistic performance than the one without dendrites because dendritic phases hindered the propagation of shear bands or cracks.

Analysis of Comfortable Environment in the Classroom with Humidification and Ventilation in Winter (겨울철 가습 및 환기에 따른 교실내 쾌적환경 분석)

  • Cheong, Seong-Ir;Sheng, Nai-Li;Kim, Doo-Hyun;Lee, Jae-Keun;Hwang, Yu-Jin;Park, Jong-Hoon;Seo, Seok-Jang
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.21 no.7
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    • pp.402-408
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    • 2009
  • In this paper, the effects of ventilation and humidification on thermal comfort and indoor air quality(IAQ) were evaluated in a classroom when a heat pump system was operated in winter. Thermal comfort parameters, such as temperature, relative humidity, globe temperature and air velocity, were measured at 9 points in the classroom. The concentration of $CO_2$ and total suspended particles(TSP) in the classroom were measured in order to analyze IAQ. Temperature distribution in the classroom was decreased by $2{\sim}5^{\circ}C$ when the ventilation system and the humidifier were operated. When the relative humidity was adjusted to 60% by operating the humidifier and the ventilation system, the predicted mean vote(PMV) in the classroom was within the comfortable range of $-0.5{\sim}0.5$. When the ventilation system was operated, the average concentration of $CO_2$ and TSP were decreased by 645 ppm and 0.17 $mg/m^3$, respectively. This paper suggests the humidification and ventilation conditions to maintain the comfortable environment in the school classroom in winter experimentally.

Field Study on Application of Reactive Zone Technology Using Zero-Valent Iron Nanoparticles for Remediation of TCE-Contaminated Groundwater (TCE 오염 지하수의 정화를 위한 나노영가철 기반 반응존 공법의 현장 적용성 연구)

  • Ahn, Jun-Young;Kim, Cheolyong;Hwang, Kyung-Yup;Jun, Seong-Chun;Hwang, Inseong
    • Journal of Soil and Groundwater Environment
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    • v.19 no.6
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    • pp.80-90
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    • 2014
  • The laboratory and field studies were conducted to identify an optimal injection concentration of nanoscale zero-valent iron particles (NZVI) and to evaluate the applicability of NZVI-based reactive zone technology to the site contaminated with trichloroethylene (TCE) DNAPL (Dense Non-Aqueous Phase Liquid). The laboratory test found an optimal injection concentration of NZVI of 5 g/L that could remove more than 95% of 0.15 mM TCE within 20 days. Eleven test wells were installed at the aquifer that was mainly composed of alluvial and weathered soils at a strong oxic condition with dissolved oxygen concentration of 3.50 mg/L and oxidation-reduction potential of 301 mV. NZVI of total 30 kg were successfully injected using a centrifugal pump. After 60 days from the NZVI injection, 86.2% of the TCE initially present in the groundwater was removed and the mass of TCE removed was 405 g. Nonchlorinated products such as ethane and ethene were detected in the groundwater samples. Based on the increased chloride ion concentration at the site, the mass of TCE removed was estimated to be 1.52 kg. This implied the presence of DNAPL TCE which contributed to a higher estimate of TCE removal than that based on the TCE concentration change.

Relationship and Characteristics of PM10 and Endotoxin Concentrations in Windowless Poultry Houses in South Korea (일부 밀폐형 무창계사에서 발생하는 PM10 및 엔도톡신의 특성 및 연관성 분석)

  • Kim, Hyocher;Sin, Sojung;Kim, Kyungsu;Jung, Wongeon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.31 no.4
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    • pp.331-341
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    • 2021
  • Objectives: The aim of this study was to evaluate the concentrations and relationships of coarse particles with a diameter of 10 ㎛ (PM10) with endotoxins according to the time of measurement in windowless poultry houses. Methods: In this study, measurement was performed on ten windowless poultry houses with a vertically integrated system from July to November. PM10 was measured using personal environmental monitors and polytetrafluoroethylene (PTFE) filters with a 4 L/min-calibrated pump in selected sampling locations (two near the door and two near an exhaust fan). The endotoxin on PTFE filter was analyzed by the LAL turbidimetric method. Results: The range of geometric mean concentrations of PM10 and endotoxins for each of the 38 samples were 0.12-3.30 mg/m3 and 11.9-3553.66 EU/m3, respectively. PM10 and endotoxin concentrations varied by farm, increasing with the decrease in ventilation. The range of the coefficient of determination between PM10 and endotoxin was 0.0009-0.9249. As the atmospheric temperature decreased, it was confirmed that the concentrations of PM10 and endotoxin increased because the volume of ventilation was decreased. Conclusions: Endotoxins were more affected by time of measurement and ventilation than PM10, which means that endotoxins could be an important indicator for intervention programs for improvement of indoor environments.

The Optimal Solution Treatment Condition in a Al-Si-Cu AC2B Alloy (Al-Si-Cu계 AC2B 합금의 최적 용체화 처리 조건)

  • Jung, Jae-Gil;Park, June-Soo;Ha, Yang-Soo;Lee, Young-Kook;Jun, Joong-Hwan;Kang, Hee-Sam;Lim, Jong-Dae
    • Korean Journal of Metals and Materials
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    • v.47 no.4
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    • pp.223-227
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    • 2009
  • The precipitates, hardness, and tensile properties of Al-6.2Si-2.9Cu AC2B alloy were investigated with respect to solution treatment time at $500^{\circ}C$. $Al(Cu)-Al_2Cu$ eutectic, Si, ${\theta}-(Al_2Cu)$, and $Q-(Al_5Cu_2Mg_8Si_6)$ phases were observed in the as-cast specimen. With increasing the solution treatment time at $500^{\circ}C$, the $Al(Cu)-Al_2Cu$ eutectic and ${\theta}-(Al_2Cu)$ phases were gradually reduced and finally almost disappeared in 5 h. The mechanical properties, such as hardness, tensile strength, and elongation, were improved with solution treatment time until about 5 h due to the dissolution of the $Al_2Cu$ particles. With further holding time, the mechanical properties did not change much. The solution treated specimens for over 5 h at $500^{\circ}C$ exhibit almost the same tensile properties even after aging at $250^{\circ}C$ for 3.5 h. Accordingly, the optimal solution treatment condition of the Al-Si-Cu AC2B alloy is considered to be 5 h at $500^{\circ}C$.

Field Emission Property of Double-walled Carbon Nanotubes Related to Purification and Transmittance (이중벽 탄소나노튜브의 정제와 투과도에 따른 전계방출 특성 평가)

  • Ahn, KiTae;Jang, HyunChul;Lyu, SeungChul;Lee, Hansung;Lee, Naesung;Han, Moonsup;Park, Yunsun;Hong, Wanshick;Park, Kyoungwan;Sok, Junghyun
    • Korean Journal of Metals and Materials
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    • v.49 no.1
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    • pp.79-84
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    • 2011
  • Double-walled carbon nanotubes (DWCNTs) with high purity were produced by the catalytic decomposition of tetrahydrofuran (THF) using a Fe-Mo/MgO catalyst at $800^{\circ}C$. The as-synthesized DWCNTs typically have catalytic impurities and amorphous carbon, which were removed by a two-step purification process consisting of acid treatment and oxidation. In the acid treatment, metallic catalysts were removed in HCl at room temperature for 5 hr with magnetic stirring. Subsequently, the oxidation, using air at $380^{\circ}C$ for 5 hr in the a vertical-type furnace, was used to remove the amorphous carbon particles. The DWCNT suspension was prepared by dispersing the purified DWCNTs in the aqueous sodium dodecyl sulfate solution with horn-type sonication. This was then air-sprayed on ITO glass to fabricate DWCNT field emitters. The field emission properties of DWCNT films related to transmittance were studied. This study provides the possibility of the application of large-area transparent CNT field emission cathodes.

Purification of Single-walled Carbon Nanotubes by HCl Treatment and Analysis of the Field Emission Property (염산에 의한 단중벽 탄소나노튜브 정제와 전자방출 특성 평가)

  • Lyu, SeungChul;Jung, Dami;Ahn, KiTae;Lee, Hansung;Lee, Naesung;Park, Yunsun;Sok, Junghyun
    • Korean Journal of Metals and Materials
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    • v.48 no.4
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    • pp.335-341
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    • 2010
  • High-quality single-walled carbon nanotubes (SWCNTs) were synthesized by catalytic decomposition of $C_2H_2$ using Fe-Mo/MgO catalyst at $800^{\circ}C$. The as-synthesized SWCNTs typically occurred in the form of a bundle with a diameter of 10~20 nm together with amorphous carbon and catalytic impurities, which were removed by a two-step purification process consisting of oxidation and an acid treatment. The oxidation step, using an $O_2$-Ar mixture at $380^{\circ}C$ for 5 hr in a vertical-type furnace and a $HNO_3$ treatment at $100^{\circ}C$ for one hour, was utilized to remove the amorphous carbon particles. Subsequently, metallic catalysts were removed in HCl at room temperature for 5 hr under magnetic stirring. The SWCNT suspension was prepared by dispersing the purified SWCNTs in an aqueous sodium dodecyl benzene sulfonate solution with horn-type sonication. This was then air-sprayed on glass to fabricate CNT field emitters. The samples had a turn-on field value of 4 V/${\mu}m$ and a current density of 0.67 mA/$cm^2$ at 9 V/${\mu}m$. Increasing the HCl treatment time improved the field emission properties.

Evaluation of Removal Efficiency in Emission Pollutants by Air Pollution Prevention Facilities from Meat Grilled Restaurants - Focus on the Electrostatic Precipitator - (직화구이 음식점 방지시설의 오염물질 저감 효과 평가 - 전기집진방식을 중심으로 -)

  • Seo, Jang-Won;Kim, Young-Il;Lee, Hee-Sun;Kim, Ji-Hun;Kim, Young-Doo;Shin, Jin-Ho
    • Particle and aerosol research
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    • v.17 no.4
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    • pp.115-123
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    • 2021
  • The emission gas from meat grilled restaurants has unpleasant odor and sticky particulate matters (PM) in form of oil mist. This affects the residents living nearby. In oder to decrease the odor and PM, electrostatic precipitators (ESP) were installed at several restaurants by support of Seoul metropolitan government and emission characteristics of PM and odor were investigated. The removal efficiency of odor and PM at before- and after-ESP was that total hydrocarbon (THC), NH3, H2S, acetaldehyde, butyraldehyde were not much decreased. Total suspended particles (TSP) emitted from the vent was below the value of 7 mg/m3 regardless of the concentration of before-ESP and removal efficiency was in the range of 64 ~ 86%. The ratio of PM1.0 to PM10 of emission gas was over 0.9. So it was revealed that most PM of emission gas was PM1.0. The PM concentration in the air of the street near the vent was higher than another street due to the emission gas and the PM of indoor air of restaurant grilling meats was measured very high compared to outdoor air. So it needs more powerful ventilation of indoor air.

Vertical Variation of the Particle Flux in the Eastern Tropical Pacific from 2009 to 2010 (동태평양 열대해역에서 2009-2010년 침강입자 플럭스의 수직 변화)

  • Kim, Hyung Jeek;Cho, Sosul;Kim, Dongseon;Kim, Kyeong Hong;Yoo, Chan Min
    • Ocean and Polar Research
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    • v.44 no.3
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    • pp.221-233
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    • 2022
  • A sediment trap had been deployed at 1250 m depth in the Eastern Tropical Pacific (ETP) from September 2009 to July 2010, with the aim of understanding the temporal and vertical variability of particle flux. During the monitoring period, total particle flux varied from 12.4 to 101.0 mg m-2day-1, with the higher fluxes in January-March 2010. Biogenic particle flux varied in phase with the total particle flux. The increase in total particle flux during January-March 2010 was attributed to the enhanced biological production in the surface layer caused by wind-driven mixing in response to the seasonal shifts in the location of the Intertropical convergence zone. The export ratio (e-ratio) was estimated using the particulate organic carbon flux and satellite-derived net primary production data. The estimated e-ratios changed between 0.8% and 2.8% (1.4±0.6% on average). The ratio recorded in the negative phase of Pacific decadal oscillation (PDO) was similar to the previous results obtained from the ETP during the 1992/93 periods in the positive phase of PDO. This suggests that the regime shift of the PDO is not related to the carbon export ratio.

Antibacterial activity of florfenicol composite nanogels against Staphylococcus aureus small colony variants

  • Liu, Jinhuan;Ju, Mujie;Wu, Yifei;Leng, Nannan;Algharib, Samah Attia;Luo, Wanhe
    • Journal of Veterinary Science
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    • v.23 no.5
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    • pp.78.1-78.13
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    • 2022
  • Background: Florfenicol might be ineffective for treating Staphylococcus aureus small colony variants (SCVs) mastitis. Objectives: In this study, florfenicol-loaded chitosan (CS)-sodium tripolyphosphate (TPP) composite nanogels were prepared to allow targeted delivery to SCV infected sites. Methods: The formulation screening, the characteristics, in vitro release, antibacterial activity, therapeutic efficacy, and biosafety of the florfenicol composite nanogels were studied. Results: The optimized formulation was obtained when the CS and TPP were 10 and 5 mg/mL, respectively. The encapsulation efficiency, loading capacity, size, polydispersity index, and zeta potential of the optimized florfenicol composite nanogels were 87.3% ± 2.7%, 5.8% ± 1.4%, 280.3 ± 1.5 nm, 0.15 ± 0.03, and 36.3 ± 1.4 mv, respectively. Optical and scanning electron microscopy showed that spherical particles with a relatively uniform distribution and drugs might be incorporated in cross-linked polymeric networks. The in vitro release study showed that the florfenicol composite nanogels exhibited a biphasic pattern with the sustained release of 72.2% ± 1.8% at 48 h in pH 5.5 phosphate-buffered saline. The minimal inhibitory concentrations of commercial florfenicol solution and florfenicol composite nanogels against SCVs were 1 and 0.25 ㎍/mL, respectively. The time-killing curves and live-dead bacterial staining showed that the florfenicol composite nanogels were concentration-dependent. Furthermore, the florfenicol composite nanogels displayed good therapeutic efficacy against SCVs mastitis. Biological safety studies showed that the florfenicol composite nanogels might be a biocompatible preparation because of their non-toxic effects on the renal tissue and liver. Conclusions: Florfenicol composite nanogels might improve the treatment of SCV infections.