• Title/Summary/Keyword: Mg particles

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Low-Temperatrue Synthesis of Mullite Powders by the Emulsion Technique (MgO-Al2O3-SiO2계 요업원료의 제조 및 소결특성 -에멀젼법에 의한 Mullite분체의 저온합성-)

  • 현상훈;이희수;송승룡
    • Journal of the Korean Ceramic Society
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    • v.26 no.3
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    • pp.361-370
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    • 1989
  • Mullite powders were synthesized from the common solution of aluminum sulfate and sodium silicate solutions by the emulsion-hot kerosene technique. The reaction temperature and mechanism for mullitization and the characteristics of synthesized mullite powders were investigated. The effect of Na components introduced from sodium silicate solution on the physical property and microstructure of sintered mullite was also examined. It was proved that mullites were formed at 75$0^{\circ}C$ through the reaction mechanism of Na2O.2.2SiO2+3.3Al2(SO4)3longrightarrow1.1(3Al2O3.2SiO2)+Na2SO4+8.9SO3. Synthetic mullite powders consisted of the compositiion of 3Al2O3.2SiO2 and showed highly agglomeration of hollow spherical particles of 1${\mu}{\textrm}{m}$ diameter. The density and fracture toughness of sintered mullites were somewhat reduced because of the effect of a very small amount of residual Na components.

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Characteristics of Image Sticking Observed During Background Display in AC-PDP (AC PDP의 배경광 잔상특성)

  • 류재화;임성현;김동현;김중균;이호준;박정후
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.2
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    • pp.91-96
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    • 2004
  • In darkroom condition, it was observed that a white picture pattern lasted several minutes leaves a recognizable trace in subsequent black background picture. Although this is not a serious problem for the most current public display or home TV applications, the image sticking should be minimized for future high quality multimedia display applications. In order to characterize this picture memory effect having relatively long time scale, spatially resolved luminance measurement and light waveform measurement have been performed. Pixels located at the outer boundary of white pattern previously displayed shows highest luminance. These cells also shows fastest ignition at the ramp up reset sequence. The luminance and ignition voltage differences between boundary cells and the other cells are increased with display duration and number of sustain-pulse. It is speculated that image sticking observed at the boundary cell is originated from the transport of charged particles and re-deposition of reactive species such as Mg, O provided from strong sustain discharge region.

Effects of the addition of chelate compound in phosphating surface conditioning solution (인산염 표면 조정액 중의 킬레이트제 첨가 영향)

  • 남궁성;허보영
    • Journal of the Korean institute of surface engineering
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    • v.34 no.4
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    • pp.281-288
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    • 2001
  • Phosphating treatments have been performed to improve paint adhesion and corrosion resistance of zinc and zinc alloy coated steels for a long time. In this work, the effects of the addition of chelate compound were studied to improve the stability of surface conditioning solution and properties of zinc phosphate films. The coalescence of colloidal Ti-compound and extraneous charged particles (alkaliearth metal cation such as $Mg^{2+}$ , $Ca^{2+}$ ) were suppressed by using a surface conditioning solution with chelate compound. Therefore, after surface conditioning solution containing chelate compound was left standing for one week at room temperature, the formation of a white sediment was decreased comparing to surface conditioning solution without chelate compound. The crystal size of phosphate film was fine and the whiteness value of phosphated zinc coated steel sheets was also high without the decrease of corrosion resistance and anti-patina. It was very effective to use chelate compound improving the stability of surface conditioning solution.

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Analysis of $Si_3N_4$ Ultra Fine Powder Using High-pressure Acid Digestion and Slurry Injection in Inductively Coupled Plasma Atomic Emission Spectrometry

  • Kim, K.H.;Kim, H.Y.;Im, H.B.
    • Bulletin of the Korean Chemical Society
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    • v.22 no.2
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    • pp.159-163
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    • 2001
  • Si3N4 powder has been analyzed by inductively coupled plasma atomic emission spectrometry (ICP-AES). The sample was dissolved by high-pressure acid digestion with HF, H2SO4 (1+1), and HNO3 mix ture. This technique is well suited for the impurity analysis of Si3N4 because the matrix interference is eliminated. A round-robin samples trace elements, such as Ca, W, Co, Al, Fe, Mg, and Na, were determined. For the direct analysis, slurry nebulization of 0.96 mm Si3N4 powder also has been studied by ICP-AES. Emission intensities of Fe were measured as ICP operational conditions were changed. Significant signal difference between slurry particles and aqueous solution was observed in the present experiment. Analytical results of slurry injection and high-pressure acid digestion were compared. For the use of aqueous standard solution for calibration, k-factor was determined to be 1.71 for further application.

Immunoregulatory Action of Soeumin Seungyangikkitang (소음인(少陰人) 승양익기탕(升陽益氣湯)의 면역조절작용(免疫調節作用))

  • Ryu, Chang-ryeol;Song, Jeong-mo
    • Journal of Sasang Constitutional Medicine
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    • v.13 no.3
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    • pp.102-113
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    • 2001
  • The purpose of this research was to investigate the effects of Seungyangikkitang (SIT) on the immune cells in BALB/c mice. SIT (500mg/kg) was administerd p.o. once a day for 7 days. SIT enhanced the proliferation of thymocytes, but decreased the proliferation of splenocytes. SIT enhanced the subpopulation of cytotoxic T cells in thymocytes and helper T cells in splenocytes, but did not affect the subpopulation of B220/Thy1 cells. SIT enhanced the production of γ-interferon and interleukin-2 in thymocytes, splenocytes and serum, but did not affect the production of interleukin-4. SIT suppressed the production of nitric oxide, but enhanced the lucigenin chemiluminescence and the engulfment of FITC-conjugated E. coli particles in peritoneal macrophages. These results suggest that SIT has a potent activity on the specific immunity via the cytokine secretion of Th1 cells and the non-specific immunity via the phagocytic activity of macrophages in vivo.

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Physico.chemical Properties of Inorganic Materials Currently Used as Root Medium Components for Crop Production in Korean Plant Factories (국내에서 식물공장용 배지 재료로 유통되는 무기물의 토양 물리화학적 특성)

  • Shin, Bo Kyoung;Son, Jung Eek;Choi, Jong Myung
    • Journal of Bio-Environment Control
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    • v.21 no.4
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    • pp.336-342
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    • 2012
  • Inorganic materials were commonly used as container media in domestic plant factories. Objective of this research was to secure the information in soil physical and chemical properties of inorganic materials such as vermiculites and perlites. To achieve this, 12 gold and silver vermiculites from China, Zimbabwe, and South Africa and 5 perlites from China were collected based on the marketing grades (MG) in particle sizes and analyzed for determination of their characteristics. The percentage of particles larger than $710{\mu}m$, in China perlite MG 3~5 mm, China silver vermiculites MG > 8 mm and MG 3~8 mm were 99.9%, 99.8%, and 99.7%, respectively, which were much higher than 28.4% in China gold vermiculite MG 0.3~1.0 mm, 14.0% in perlite MG < 1.0 mm, and 12.6% of Zimbabwe silver vermiculite MG < 1.0 mm. The container capacities of perlite MG < 1.0 mm and South Africa silver vermiculite MG 0.25~1.0 mm were 72.0% and 71.1%, respectively. The air space in China silver vermiculite MG 3~8 mm was 49.3% which was higher than other materials tested. However, the China gold and silver vermiculites MG 0.3~1 mm had 3.5% and 2.4% in air space indicating that possible problems could occur in soil aeration when they are used for container media. The percentage of easily available and buffering water of China gold vermiculite MG 0.3~1 mm and perlite MG < 1.0 mm were the highest among test materials. The ranges of pH and electrical conductivity were 6.36 to 10.7 and 0.032 to $0.393dS{\cdot}m^{-1}$ in vermiculites and 7.78 to 8.62 and 0.030 to $0.041dS{\cdot}m^{-1}$ in perlite, respectively. The cation exchange capacity of China silver vermiculite MG 0.3~1 mm were $14.7cmol{\cdot}kg^{-1}$ that was 10 times as high as $0.34cmol{\cdot}kg^{-1}$ in perlite MG 1~2.5 mm. The vermiculites had the higher contents of exchangeable cations such as Ca, K, and Na, than those of perlites.

Effects of Soil Bulk Density on Saturated Hydraulic Conductivity and Solute Elution Patterns (토양의 용적밀도에 따른 포화수리전도도 및 음이온의 용출양상)

  • Kim, Pil-Joo;Lee, Do-Kyoung;Chung, Doug-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.30 no.3
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    • pp.234-241
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    • 1997
  • The effects of bulk densities(${\rho}_b$) on saturated hydraulic conductivity (Ksat) and solute elution patterns were investigated from five different bulk densities ranging from $1.1Mg/m^3$ to $1.5Mg/m^3$ with each increment of $0.1Mg/m^3$. The hydraulic conductivities observed were divided into two stages: (1) a linearly decrease with increase in bulk density up to $1.4Mg/m^3$, (2) a steady state where the bulk density is greater than $1.4Mg/m^3$. Using the saturated hydraulic conductivity at the steady state, we figured out the equation describing the correlation between bulk densities(${\rho}_b$) and saturated hydraulic conductivity(Ksat) as follows: $Ksat=-19.2({\rho}_b{^2})+6{\rho}_b+15.5$, (r=0.985). Electrical conductivity(EC) measured from the leachate of the soil column showed that EC at the same pore volume were decreased with an increase in the bulk density from $1.2g/cm^3$, $1.5g/cm^3$, as shown in the time taken to collect the same pore volume at each respective bulk density. The maximum relative concentrations (C/Co=1) from the breakthrough curves for the anions of $Cl^-$, $NO_3{^-}$ and $SO_4{^{2-}}$, which are weakly adsorbed on the soil particles, moved to the right of the graph, while a distinctive retardation occurs at the bulk density between $1.3Mg/m^3$ and $1.4Mg/m^3$. The time taken to recover about 90% of indigenous sulphate was approximately twice as those of chloride and nitrate, resulting in slightly stronger adsorption characteristics for sorption sites on the soil surface. Thus, we can conclude that the salt accumulation in green house soil might be significantly influenced by it's bulk density at the soil depth, as well as the adsorption capacity of ions for the sorption sites in soils.

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Effect of Alloying Elements on Particulate Dispersion Behavior and Mechanical Properties in TiC Particulate Reinforced Magnesium Matrix Composites (TiC 입자강화 Mg 복합재료에 있어서 입자 분산거동 및 기계적 성질에 미치는 합금원소의 영향)

  • Lim, Suk-Won;Choh, Takao;Park, Yong-Jin
    • Journal of Korea Foundry Society
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    • v.14 no.3
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    • pp.240-247
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    • 1994
  • TiC particulate reinforced magnesium matrix composites were fabricated by melt stirring method. The effect of alloying elements on TiC particulate dispersion into molten magnesium and mechanical properties were investigated. The incorporation time is defined as the time required for dispersion of solid particles into molten metal. The incorporation time of TiC particles into molten pure magnesium was remarkably shorter and the particulated dispersion was more uniform than that of pure aluminum which was reported previously. The incorporation time was, prolonged by the addition of Al, Bi, Ca, Ce, Pb, Sn or Zn. The tensile strength increased and elongation decreased by the addition of Cu or Sn into the matrices and composites. Although, the tensile strength of the matrices and composites increased by alloying with Ca or Ce, the maximum elongation was observed at a content of about 1% for the matrices. By alloying with Zn, the tensile strength increased for the matrices and composites, but the elongation of the matrices increased. The pure magnesium and its alloy matrix composites reinforced with 20vol% TiC have the tensile strength of about 400MPa. This value is compared with the tensile strength of SiC whisker reinforced magnesium matrix composites fabricated by liquid infiltration method at the same volume fraction. There fore, the melt strirring method which has the advantages of simple process is considered to be efficient in fabricating magnesium matrix composites.

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Analysis of Precipitation Chemistry at Rural Site in the Eastern Coast, Korea

  • Kang, Gong-Unn;Shin, Dae-Ywen;Kim, Hui-Kang
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.E1
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    • pp.29-39
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    • 2003
  • The 10-day interval basis measurements of precipitation samples at Yangyang, the rural and coastal area on the eastern coast of the Korea peninsula were accomplished for understanding the precipitation chemistry and the temporal variations of major ions September 1991 to February 1997. The precipitation was slightly acidic, and 37% of the samples in winter were pH less than 4.5. The concentrations of cations were found on the order $Na^+\;>\;{NH_4}^+\;>\;Ca^{2+}\;>\;Mg^{2+}\;>\;K^+$ and those of anions followed the pattern $Cl^-\;>\;{SO_4}^{2-}\;>\;{NO_3}^-$. Neglecting sea salt components, the major ions controlling precipitation chemistry were nss-${SO_4}^{2-}$ and ${NO_3}^-$ in anion and ${NH_4}^+$ and nss-$Ca^{2+}$ in cation. Concentrations of these ions were lower than those measured at urban sites in Korea, but were higher than those measured in Japan. Most of nss-${SO_4}^{2-}$ and ${NO_3}^-$ were neutralized by ammonia and calcium species, especially alkaline soil particles in spring and ammonia gas in other seasons. Considering also the annual value of [nss -${SO_4}^{2-}$]/[${NO_3}^-$] ratio of 2.62 and the neutralizing factors, ammonium sulphate compounds were dominant. Annual mean concentrations of these ions showed relatively small fluctuations, while larger seasonal variations were observed with higher levels in spring and winter. Precipitation amount, influence extent of acidic gases and alkaline particles long-range transported from China continent, and energy consumption pattern in each season might be able to explain this seasonal trend.sonal trend.

Study of the Dependency of the Specific Power Absorption Rate on Several Characteristics of the Excitation Magnetic Signal when Irradiating a SPION-containing Ferrofluid

  • Rosales, Alejandra Mina;Aznar, Elena;Coll, Carmen;Mendoza, Ruben A. Garcia;Bojorge, A. Lorena Urbano;Gonzalez, Nazario Felix;Martinez-Manez, Ramon;del Pozo Guerrero, Francisco;Olmedo, Jose Javier Serrano
    • Journal of Magnetics
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    • v.21 no.3
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    • pp.460-467
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    • 2016
  • Magnetic hyperthermia mediated by superparamagnetic particles is mainly based in sinusoidal waveforms as excitation signals. Temperature changes are conventionally explained by rotation of the particles in the surrounding medium. This is a hypothesis quite questionable since habitual experimental setups only produce changes in the magnetic module, not in the field lines trajectories. Theoretical results were tested by changing the waveform of the exciting signal in order to compare non-sinusoidal signals against sinusoidal signals. Experiments were done at different frequencies: 200 KHz, 400 KHz, 600 KHz, 800 KHz and 1 MHz. Superparamagnetic Iron Oxide samples (SPION), made of magnetite ($Fe_3O_4$) and suspended in water (100 mg/ml), were used. Magnetic field strength varies from $0.1{\pm}0.015KA/m$ to $0.6{\pm}0.015KA/m$. In this study was observed that the power loss depends on the applied frequency: for 1 to 2.5 RMS current the responses for each signal are part of the higher section of the exponential function, and for 3.5 to 8 RMS current the response is clearly the decrement exponential function's tale (under $1{\times}10^3LER/gr$).