• Title/Summary/Keyword: Mg particles

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High-Strain Rate Deformation of Ultra-Fine Grained Al-Mg Alloys Fabricated by Equal-Channel Angular Pressing (ECAP으로 제조된 초미세림 Al-Mg 합금의 동적 변형거동)

  • Kim, Y.G.;Ko, Y.G.;Shin, D.H.;Lee, S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.306-309
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    • 2009
  • The influence of equal-channel angular pressing (ECAP) route on dynamic deformation behavior of ultra-fine grained Al-4.4%Mg alloys was investigated in this study. The 8-pass ECAPed specimens consisted of ultra-fine grains of $0.5{\mu}m$ in size, and contained the considerable amount of second phase particles, which were fragmented and distributed homogeneously in the matrix. The result of dynamic torsional tests indicated that the maximum shear stress and fracture shear strain were lowest in the specimen deformed by ECAP via route A among the 8-pass ECAPed specimens. The formation of adiabatic shear bands was addressed by concepts of critical shear strain, deformation energy required for void initiation, and microstructural homogeneity related to ECAP routes.

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The Improvement of Water Quality by Using Filter-aids in Rapid Sand Filters (급속모래여과 공정에서의 여과보조제에 의한 수질개선효과 연구)

  • 김형선;이규성;백영매;조춘구
    • Journal of Environmental Health Sciences
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    • v.27 no.4
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    • pp.15-24
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    • 2001
  • The objective of this study it to evaluate the microbial safety in rapid sand filters adapted in most drinking water treatment plants. The potential pathogens to cause water quality problems Are presumed to be Giardia and Gryptosporidium. They look like particles in view of their size. It has been reported that if the number of particles (larger than 2 ${\mu}{\textrm}{m}$ in water) is less than 100 per mL and its turbidity is below 0.1 NTU, it is considered as a safe water in terms of pathogens. In order to achieve such a good water quality. filter-aids (chemicals) were added to the inlet-channel of filter and their effectiveness was evaluated on the basis of water quality factors such as turbidity and particle counting. This study was conducted in she three steps of experiment: jar test. pilot plant test and real water treatment plant test (P plant in seoul). The experiment reult of the P water treatment showed that cationic polyamine was the most effective in the removal of particles and turbidity at the does of 0.25 mg/L. The turbidity without filer-aids showed in the range of 0.12 ~0.17 NTU during filtration and 0.14 NTU on the average. However. with addition of polyamine, the turbidity represented below(or less than) 0.1 NTU after 20 min in the start of filtration and kept 0.08 NTU on the average. On the other hand, as for number of particles, while no filter-aids led to the range of 111 ~270 per mL and 190 on the average, addition of polydmine led to 113 per mL on talc average, and kept below100 per mL after 20 min in the start of filtration.

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Study of Surface Alloying of TiC, TiB2 and VC with Carbon Steel Using High Energy Electron Beam Irradiation (고에너지 전자빔 투사를 이용한 TiC, TiB2 및 VC/ 탄소강 표면합금화 연구)

  • Yoo, Jung-Hoon;Shin, Kee-Sam;Yoon, Jae-Hong;Lee, Chan-Gyu;Hur, Sung-Gang;Lee, Je-Hyun;Oh, Jun-Chul;Lee, Sung-Hak;Euk, Kwang-Jun
    • Korean Journal of Materials Research
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    • v.12 no.12
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    • pp.904-910
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    • 2002
  • Surface alloying using TiC, $TiB_2$ and VC ceramic particles on carbon steel has been performed using high voltage electron beam. Each type of ceramic particles was mixed with flux of Al and $MgF_2$ in 1 to 4 ratio. The microstructures of the surface alloyed layers consisted of melted region, interface region. heat affected region and the unaffected matrix. The surface layer of the TiC surface alloyed had a cubed primary and a eutectic type of TiC. $TiB_2$ in surface layer of $TiB_2$ surface alloyed were incompletely melted with$ TiB_2$ particles as observed before the alloying. On the surface layer of the VC surface alloyed, very well defined cell structure was observed with VC on the cell boundary. In addition, ~50 nm in diameter VC particles in high density were ubiquitous in the matrix. Those fine VC particles prominently improved the hardness and wear resistance of the surface layer of the VC surface alloyed.

Application of fluorescent particles as a tracer to detect the membrane surface damage in a pilot scale membrane bioreactor (형광입자를 이용한 분리막 표면 검측 방법의 파일럿 규모 플랜트 적용)

  • Kim, Choah;Kim, Hee Jun;Cho, Jinwoo
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.1
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    • pp.33-40
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    • 2016
  • In this study, a fluorescent silica nano particle is used as the surrogate for challenging test of membrane surface integrity. The particles are functionalized by a fluorescent dying agent so that as an ultraviolet light is imposed a bright fluorescent image from the particles can be taken. If a membrane surface is damaged and has a compromised part larger than the size of surrogate the fluorescent particles would pass through and contained in the permeate. An operator can directly notice whether the membrane surface is damaged or not by detecting a fluorescent image taken from the permeate. Additionally, the size of compromised part is estimated through analysing the fluorescent image in which we surmise the mass of particles included in the permeate by calculating an average RGB value of the image. The pilot scale experiments showed that this method could be applied successfully to determine if a membrane surface had a damaged parts regardless of the test condition. In the testing on the actual damaged area of $4.712mm^2$, the lowest error of estimating the damaged area was -1.32% with the surrogate concentration of 80 mg/L, flux of $40L/m^2/hr$ for 25 minutes of detection. A further study is still going on to increase the lowest detection limit and thus decrease the error of estimation.

Chemical Compositions and Spatial Distribution Analysis of Fall-Out Particles in Suwon Area (수원지역 강하분진의 화학조성및 공간분포 분석)

  • 김현섭;이태정;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.1
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    • pp.23-32
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    • 1999
  • Deposition is one of the important removal mechanisms for the ambient aerosol, and it also leads to adverse environmental and economic impacts. The purpose of this study was to investigate chemical compositions and spatial distributions of fall-out aerosols. A total number of 340 samples were collected at 35 sampling sites in Suwon area from January to November, 1996. Twelve inorganic elements (Al, Ba, Cd, Cr, K, Pb, Sb, Zn, Cu, Fe, Ni, and V) and eight ionic components ($F^-$, Cl, $NO_3^-$, $SO_4^{2-}$, $Na^+$, $NH_4^+$, $Mg^{2+}$, and $Ca^{2+}$) were analyzed by AAS and IC, respectively. The monthly variation showed that the flux of fall-out particles was increased in the spring season(March, April, and May) and decreased from August to October. Arithmetic mean flux of fall-out particles was 176.8 kg/$ extrm{km}^2$/day during the study period. The fluxes of each chemical species were $SO_4^{2-}$ 12.414, $Ca^{2+}$ 7.369, $NO_3^-$ 5.812, $Cl^-$ 3.566, $NH_4^+$ 3.176, Fe 3.107 kg/$\textrm{km}^2$/day, and so on. By using a kriging analysis, spatial distribution pattern of those fluxes was intensively studied. Total fluxes estimated in Suwon city were 8424.72t/y of fall-out particles, 519.27t/y of $SO_4^{2-}$, 336.79t/y of $Ca^{2+}$,267.34 t/y of $NO_3^+$, 155.36t/y of $Cl^-$, 147.79t/y of Fe.

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Agrobacterium Mediated Transformation from Callus Pretreated with Particle Bombardment in Lilium lancifolium Thunb. (Particle Bombardment에 의해 전처리 된 참나리(Lilium lancifolium Thunb.) 캘러스의 Agrobacterium tumefaciens을 통한 형질전환)

  • Nam, Sang-Wook;Kim, Hei-Young
    • Journal of Plant Biotechnology
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    • v.31 no.1
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    • pp.13-17
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    • 2004
  • To improve transformation efficiency, the callus of Lilium lancifolium Thunb. were bombarded by particles coated with pIG 121 Hm which include NPT II and GUS genes, and then cocultivated with Agrobacterium tumefaciens EHA101 which contain pIG121Hm binary vector, carrying neomycin phosphotransferase (NPT II) and $\beta$-Glucuronidase (GUS) genes. Three days after cocultivation with Agrobacterium tumefaciens and particle bombardment, the callus clusters were transferred to MS medium containing 1mg/L 2,4-D, 0.1mg/L BAP, 100mg/L kanamycin and 200mg/L carbenicillin. Four weeks after transfer to the selection medium, GUS expression was detected and PCR analysis revealed the presence of NPT II fragment of the expected size (700 bp) in the transformed callus. The GUS expression from Agrobacterium-mediated transformants after particle bombardment increased to over 3-folds compared with that of callus cocultivated with Agrobacterium tumefaciens without particle bombardment. The callus clusters containing kanamycin resistant gene were transferred to MS medium containing 1mg/L NAA and 1mg/L BAP. Somatic embryos were developed in four weeks and microbulbs expressing GUS were formed.

Properties of Explosion and Flame Velocity with Content Ratio in Mg-Al Alloy Particles (마그네슘합금의 조성비율에 따른 폭발 및 화염전파 특성)

  • Han, Ou-Sup;Lee, Keun-Won
    • Journal of the Korean Institute of Gas
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    • v.16 no.4
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    • pp.32-37
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    • 2012
  • The aim of this study is to evaluate the characteristics of explosion and flame velocity that can be utilized to factories where Mg-Al alloy metal powders are handled in the form of raw materials, products or by-product for similar dust explosion prevention and mitigation. Because the strength of the blast pressure is the result due to flame propagation, flame velocity in dust explosion can be utilized as a valuable information for damage prediction. An experimental investigation was carried out on the influences of content ratio of Mg-Al alloy (mean particle size distribution of 151 to 161 ${\mu}m$). And a model of flame propagation velocity based on the time to peak pressure and flame arrival time in dust explosion pressure, assuming the constant burning velocity, leads to a representation of flame velocity during dust explosion. As the results, the maximum flame velocity of Mg-Al(60:40 wt%), Mg-Al(50:50 wt%) and Mg-Al(40:60 wt%) was estimated 15.5, 18 and 15.2 m/s respectively, and also tend to change with content ratio of Mg-Al.

Microstructure, Tensile Strength, and High Cycle Fatigue Properties of Mg+Al2Ca added ADC12 (Al-Si-Cu) Alloy (Mg+Al2Ca 첨가 ADC12 (Al-Si-Cu) 합금의 미세조직, 인장 및 고주기 피로 특성)

  • Kim, Y.K.;Kim, M.J.;Kim, Shae K.;Yoon, Y.O.;Lee, K.A.
    • Transactions of Materials Processing
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    • v.26 no.5
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    • pp.306-313
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    • 2017
  • This study investigated the microstructure, tensile strength, and high cycle fatigue properties of ADC12 aluminum alloys with different $Mg+Al_2Ca$ contents manufactured using die casting process. Microstructural observation identified the presence of ${\alpha}-Al$, eutectic Si, $Al_2Cu$, and Fe-intermetallic phases. The increase of $Mg+Al_2Ca$ content resulted in finer pore size and decreased pore distribution. Room temperature tensile strength tests were conducted at strain rate of $1{\times}10^{-3}/sec$. For 0.6%Mg ADC12, measured UTS, YS, and El were 305.2MPa, 157.0MPa, and 2.7%, respectively. For 0.8%Mg ADC12, measured UTS, YS, and El were 311.2 MPa, 159.4 MPa, and 2.4%, respectively. Therefore, 0.8% ADC12 alloy had higher strength and slightly decreased elongation compared to 0.6% Mg ADC12. High cycle fatigue tests revealed that 0.6% Mg ADC12 alloy had a fatigue limit of 150 MPa while 0.8% Mg ADC12 had a fatigue limit of 160MPa. It was confirmed that $Mg+Al_2Ca$ added ADC12 alloy achieved finer, spherical eutectic Si particles, and $Al_2Cu$ phases with greater mechanical and fatigue properties since size and distribution of pores and shrinkage cavities decreased as $Mg+Al_2Ca$ content increased.

Effect of Ca Addtion on Microstructure and Mechanical Properties of Mg-11Li-3Zn-1Sn-0.4Mn Based Alloys (Mg-11Li-3Zn-1Sn-0.4Mn 마그네슘 합금의 Ca 첨가에 따른 미세조직 및 기계적 특성평가)

  • Kim, Jung-Han;Kim, Yong-Ho;Yoo, Hyo-Sang;Son, Hyeon-Taek;Lee, Seong-Hee
    • Korean Journal of Materials Research
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    • v.25 no.6
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    • pp.269-273
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    • 2015
  • The effect of adding Ca on the microstructural and mechanical properties of as-cast Mg-11Li-3Zn-1Sn(wt%) alloys were investigated. Mg-11Li-3Zn-1Sn-0.4Mn with different Ca additions (0.4, 0.8, 1.2 wt%) were cast under an $SF_6$ and $Co_2$ atmosphere at $720^{\circ}C$. The cast billets were homogenized at $400^{\circ}C$ for 12h and extruded at $200^{\circ}C$. The microstructural and mechanical properties were analyzed by OM, XRD, SEM, and tensile tests. The addition of Ca to the Mg-11Li-3Zn-1Sn-0.4Mn alloy resulted in the formation of $Ca_2Mg_6Zn_3$, MgSnCa intermetallic compound. By increasing Ca addition, the volume fraction and size of $Ca_2Mg_6Zn_3$ with needle shape were increased. This $Ca_2Mg_6Zn_3$ intermetallic compound was elongated to the extrusion direction and refined to fine particles due to severe deformation during hot extrusion. The elongation of the 0.8 wt% Ca containing alloy improved remarkably without reduction strength due to the formation of fine grain and $Ca_2Mg_6Zn_3$ intermetallic compounds by Ca addition. It is probable that fine and homogeneous $Ca_2Mg_6Zn_3$ intermetallic compounds played a significant role in the increase of mechanical properties.

Effects of Nickel and Iron Oxide Addition by Milling under Hydrogen on the Hydrogen-Storage Characteristics of Mg-Based Alloys

  • Song, Myoung Youp;Baek, Sung Hwan;Park, Hye Ryoung;Mumm, Daniel R.
    • Korean Journal of Metals and Materials
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    • v.50 no.1
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    • pp.64-70
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    • 2012
  • Samples of pure Mg, 76.5 wt%Mg-23.5 wt%Ni, and 71.5 wt%Mg-23.5 wt%Ni-5 wt%$Fe_2O_3$ were prepared by reactive mechanical grinding and their hydriding and dehydriding properties were then investigated. The reactive mechanical grinding of Mg with Ni is considered to facilitate nucleation and to shorten diffusion distances of hydrogen atoms. After hydriding-dehydriding cycling, the 76.5 wt%Mg-23.5 wt%Ni and 71.5 wt%Mg-23.5 wt%Ni-5 wt%$Fe_2O_3$ samples contained $Mg_2Ni$ phase. In addition to the effects of the creation of defects and the decrease in particle size, the addition of Ni increases the hydriding and dehydriding rates by the formation of $Mg_2Ni$. Expansion and contraction of the hydride-forming materials (Mg and $Mg_2Ni$) with the hydriding and dehydriding reactions are also considered to increase the hydriding and dehydriding rates of the mixture by forming defects and cracks leading to the fragmentation of particles. The reactive mechanical grinding of Mg-Ni alloy with $Fe_2O_3$ is considered to decrease the particle size.