Abstract
Deposition is one of the important removal mechanisms for the ambient aerosol, and it also leads to adverse environmental and economic impacts. The purpose of this study was to investigate chemical compositions and spatial distributions of fall-out aerosols. A total number of 340 samples were collected at 35 sampling sites in Suwon area from January to November, 1996. Twelve inorganic elements (Al, Ba, Cd, Cr, K, Pb, Sb, Zn, Cu, Fe, Ni, and V) and eight ionic components ($F^-$, Cl, $NO_3^-$, $SO_4^{2-}$, $Na^+$, $NH_4^+$, $Mg^{2+}$, and $Ca^{2+}$) were analyzed by AAS and IC, respectively. The monthly variation showed that the flux of fall-out particles was increased in the spring season(March, April, and May) and decreased from August to October. Arithmetic mean flux of fall-out particles was 176.8 kg/$ extrm{km}^2$/day during the study period. The fluxes of each chemical species were $SO_4^{2-}$ 12.414, $Ca^{2+}$ 7.369, $NO_3^-$ 5.812, $Cl^-$ 3.566, $NH_4^+$ 3.176, Fe 3.107 kg/$\textrm{km}^2$/day, and so on. By using a kriging analysis, spatial distribution pattern of those fluxes was intensively studied. Total fluxes estimated in Suwon city were 8424.72t/y of fall-out particles, 519.27t/y of $SO_4^{2-}$, 336.79t/y of $Ca^{2+}$,267.34 t/y of $NO_3^+$, 155.36t/y of $Cl^-$, 147.79t/y of Fe.