• Title/Summary/Keyword: Mg particles

Search Result 738, Processing Time 0.03 seconds

High Temperature Oxidation Behavior of Mg-6%Al-1%Zn-1%CaO Alloys

  • Lee, Dong Bok;Kim, Min Jung
    • Journal of the Korean institute of surface engineering
    • /
    • v.50 no.1
    • /
    • pp.42-45
    • /
    • 2017
  • The magnesium-base AZ61 alloy was cast while adding 1% CaO powder into the melt. It was hot extruded, and oxidized at $550-650^{\circ}C$ in air in order to study its microstructure and oxidation behavior. Initially added CaO powder reacted with Al in the melt to $Al_2Ca$ particles that aligned along the extrusion direction. The formed $Al_2Ca$ particles increased the oxidation resistance through forming the superficial CaO scale at the upper part of the thin MgO oxide scale.

Changes in Hardness and Damping Capacity of Aged Mg-5%Sn Alloy (시효한 Mg-5%Sn 합금의 경도와 진동감쇠능 변화)

  • Jun, Joong-Hwan
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.35 no.5
    • /
    • pp.255-261
    • /
    • 2022
  • In this work, the strain-amplitude independent and strain-amplitude dependent damping capacities of Mg-5%Sn alloy have been investigated as a function of its age-hardening response. The hardness increased with an increase in aging time, reached a peak value after 48 h, and then it gradually decreased. The damping capacities of the Mg-5%Sn alloy exhibited a decreasing tendency in the order of solution-treated, under-aged, peakaged, and over-aged states in the strain-amplitude dependent region, whereas they increased continuously with aging time in the strain-amplitude independent region. The microstructural examination during aging revealed that the lower concentration of Sn solutes in the α-(Mg) matrix and the lower density of the Mg2Sn precipitate particles may well be the crucial factors for better damping values in the strain-amplitude independent and strain-amplitude dependent regions, respectively.

Concentration and Pollution Characteristics of Secondary Aerosol Components Over the Yellow Sea by Ship-Borne Observation in Spring, 2015 (2015년 봄철에 선박으로 관측한 서해상 이차에어로졸 성분의 농도 및 오염 특성)

  • Ko, Hee-Jung;Kang, Chang-Hee;Cha, Joo Wan;Ryoo, Sang-Boom
    • Atmosphere
    • /
    • v.27 no.1
    • /
    • pp.29-40
    • /
    • 2017
  • The $PM_{10}$ and $PM_{2.5}$ particles over the Yellow Sea of Korea were collected by ship-borne observation during two cruises in spring, 2015. Their water-soluble ionic components such as $NH_4^+$, $Na^+$, $K^+$, $Mg^{2+}$, $Ca^{2+}$, $SO_4^{2-}$, $NO_3^-$, $Cl^-$, $F^-$, $CH_3COO^-$, $HCOO^-$, and $CH_3SO_3^-$ were analyzed, in order to examine the pollution characteristics of the secondary aerosol components. The comparative study of particle size distribution has resulted that $NH_4^+$, $nss-SO_4^{2-}$, $nss-Mg2+$, $nss-K^+$, $HCOO^-$, and $CH_3SO_3^-$ species mostly existed in fine particle mode. Meanwhile, nss-F-and sea-salt species were distributed in both fine and coarse particle mode, $NO_3^-$, $nss-Ca^{2+}$, $CH_3COO^-$ species were rich in coarse particle mode. The concentrations of secondary pollutants($nss-SO_4^{2-}$, $NO_3^-$, $NH_4^+$) increased in fine particles, and those of natural components ($nss-Ca^{2+}$, Sea-salt) increased in coarse particles. $NH_4^+$ exists as the form of $(NH_4)_2SO_4$ and $NH_4NO_3$, and mostly as $(NH_4)_2SO_4$ in fine particles. $NH_4NO_3$ has lower content compared to $(NH_4)_2SO_4$, and it mostly existed in fine particles at Yellow Sea I and in coarse particles at Yellow Sea II. The concentration ratios of $NO_3^-/nss-SO_4^{2-}$ for Yellow Sea I and Yellow Sea II were 0.52 and 0.16 in coarse particles, and they were 0.64 and 0.38 in fine particles, respectively, showing that the stationary source emissions were more important than mobile source emissions in Yellow Sea II (except Passage II-4).

Effect of Mg content on the density and critical properties of in-situ reacted MgB2 bulk superconductor

  • Jun, Byung-Hyuk;Kim, Dan-Bi;Park, Soon-Dong;Kim, Chan-Joong
    • Progress in Superconductivity and Cryogenics
    • /
    • v.16 no.1
    • /
    • pp.19-22
    • /
    • 2014
  • The effects of Mg content on the pore formation, density and critical properties were investigated in in-situ reacted $MgB_2$ superconductors. The $Mg_{1+x}B_2$, (x=-0.2, 0.0, 0.05, 0.3, 1.0) bulk samples with different Mg contents were heat-treated at $900^{\circ}C$ for 1 h in an Ar atmosphere. The dimensional changes of a pellet's mass and volume after heat-treatment were measured. After heat-treatment process, the sample mass was decreased by Mg evaporation, but the sample volume was expanded by pore formation at the Mg site; therefore, the apparent density was decreased. Spherical pores the same as Mg particles were developed after heat-treatment in all samples, and the pore density was increased with increasing Mg content. As the x of Mg content was increased to 1.0, the apparent density of $Mg_{1+x}B_2$ samples was decreased due to a relatively larger reduction in a mass change. The critical current density of Mg excessive sample of x=0.05 showed the highest values over the applied magnetic fields because the excessive Mg may compensate Mg loss and enhance grain connectivity.

Change in Corrosion Resistance of Solution-Treated AZ91-X%Sn Magnesium Alloys (용체화처리한 AZ91-X%Sn 마그네슘 합금의 부식 저항성 변화)

  • Moon, Jung-Hyun;Jun, Joong-Hwan
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.28 no.5
    • /
    • pp.229-238
    • /
    • 2015
  • The effects of Sn addition and solution treatment on corrosion behavior were studied in AZ91 magnesium casting alloy. The addition of 5%Sn contributed to the introduction of $Mg_2Sn$ phase, to the reduction in dendritic cell size and to the increase in the amount of secondary phases. After the solution treatment, trace amount of $Al_8Mn_5$ particles were observed in the ${\alpha}$-(Mg) matrix for the AZ91 alloy, while $Mg_2Sn$ phase with high thermal stability was additionally found in the AZ91-5%Sn alloy. Before the solution treatment, the AZ91-5%Sn alloy had better corrosion resistance than the Sn-free alloy, which is caused by the enhanced barrier effect of the (${\beta}+Mg_2Sn$) phases formed more continuously along the dendritic cell boundaries. It is interesting to note that after the solution treatment, the corrosion rate of both alloys became increased, but the Sn-added alloy showed higher corrosion rate than the Sn-free alloy. The microstructural examination on the corroded surfaces revealed that the remaining $Mg_2Sn$ particles in the solution-treated AZ91-5%Sn alloy play a role in accelerating corrosion by galvanic coupling with the ${\alpha}$-(Mg) matrix.

Chemical Properties of Indoor Individual Particles Collected at the Daily Behavior Spaces of a Factory Worker

  • Ma, Chang-Jin;Kang, Gong-Unn;Sakai, Takuro
    • Asian Journal of Atmospheric Environment
    • /
    • v.11 no.2
    • /
    • pp.122-130
    • /
    • 2017
  • The main purpose of the study was to clarify the properties of individual particles collected at each behavior space of a factory worker. The samplings of size-segregated ($PM_{2.1-1.1}$ and $PM_{4.7-3.3}$) indoor particles were conducted at three different behavior spaces of a factory worker who is engaged in an auto parts manufacturing plant (i.e., his home, his work place in factory, and his favorite restaurant). Elemental specification (i.e., relative elemental content and distribution in and/or on individual particles) was performed by a micro-PIXE system. Every element detected from the coarse particulate matters of home was classified into three groups, i.e., a group of high net-counts (Na, Al, and Si), a group of intermediate net-counts (Mg, S, Cl, K, and Ca), and a group of minor trace elements (P, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, and Pb). The results of EF for $PM_{4.7-3.3}$ in home indicated that several heavy metals were generated from the sources within the house itself. An exceptional feature shown in the individual particles in workplace is that Cr, Mn, and Co were clearly detected in both fine and coarse particles. Cluster analysis suggested that the individual coarse particles ($PM_{4.7-3.3}$) collected at the indoor of factory were chemically heterogeneous and they modified with sea-salt, mineral, and artificially derived elements. The principal components in individual coarse particles collected at restaurant were sea-salt and mineral without mixing with harmful trace elements like chromium and manganese. Compared to the indoor fine particles of home and restaurant, many elements, especially, Cl, Na, Cr, Mn, Pb, and Zn showed overwhelmingly high net-counts in those of factory.

Electrodeposition of Some Selective Metals Belonging to Light, Refractory and Noble Metals from Ionic Liquid Electrolytes

  • Dilasari, Bonita;Kwon, Kyung-Jung;Lee, Churl-Kyoung;Kim, Han-Su
    • Journal of the Korean Electrochemical Society
    • /
    • v.15 no.3
    • /
    • pp.135-148
    • /
    • 2012
  • Ionic liquids are steadily attracting interests throughout a recent decade and their application is expanding into various fields including electrochemistry due to their unique properties such as non-volatility, inflammability, low toxicity, good ionic conductivity, wide electrochemical potential window and so on. These features make ionic liquids become an alternative solution for electrodeposition of metals that cannot be electroplated in aqueous electrolytes. In this review, we classify investigated metals into three categories, which are light (Li, Mg), refractory (Ti, Ta) and noble (Pd, Pt, Au) metals, rather than covering the exhaustive list of metals and try to update the recent development in this area. In electrodeposition of light metals, granular fine Li particles were successfully obtained while the passivation of electrodeposited Mg layers is an obstacle to reversible deposition-dissolution process of Mg. In the case of refractory metals, the quality of Ta and Ti deposit particles was effectively improved with addition of LiF and pyrrole, respectively. In noble metal category, EMIM TFSA ionic liquid as an electrolyte for Au electrodeposition was proven to be effective and BMP TFSA ionic liquid developed a smooth Pd deposit. Pt nanoparticle production from ionic liquid droplet in aqueous solution can be cost-effective and display an excellent electrocatalytic activity.

An Experimental Study on the Convection Heat Transfer of Al-Mg/water Micro Fluid in a Circular Tube with Swirl

  • Chang, Tae-Hyun;Kim, Chiwon;Kil, Sang-Cheol;Lee, Chang-Hoan
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.36 no.7
    • /
    • pp.869-875
    • /
    • 2012
  • In the past decades, extensive studies on convection heat transfer on internal flow have been conducted by using high specific surface area, by increasing heat transfer coefficient and swirl flow, and by improving the transport properties. In this study, we applied a tangential slot swirl generator to improve heat transfer in a horizontal circular copper tube. The Al-Mg particles (approximately $100{\mu}m$ to $130{\mu}m$) were employed for this experimental work. The copper tube was heated uniformly by winding a heating coil with a resistance of 9 ohm per meter for heat transfer. Using Al-Mg particles, experiments were performed in the Reynolds number range of 5,000 to 13,130, with and without swirl. Experimental data transfers or comparisons between Nusselt numbers with and without swirl along the test tube and Reynolds numbers are presented. The Nusselt number is improved by increasing Reynolds numbers or swirl intensities along the test tube.

Properties of Polyalphaolefin-Based Ferrofluids

  • Kim, Jong-Hee;Park, Keun-Bae
    • Journal of Magnetics
    • /
    • v.20 no.4
    • /
    • pp.371-376
    • /
    • 2015
  • Magnetite nanoparticles were synthesized by adding excess ammonium hydroxide to a solution of iron (II) and (III) chlorides. The surfactants of oleic acid and Span 80 were applied in sequence to the magnetic particles as a combined stabilizer, and poly-${\alpha}$-olefin (PAO) 30 or 60 was used as the liquid base with a low or high viscosity, respectively. The ferrofluids were prepared with the concentrations of 200, 300, 400, and 500 mg/mL, and characterized by density, dispersion, magnetization, and viscosity. The density of the fluids increased proportionally to the concentration from 0.98 to 1.27 g/mL and 1.01 to 1.30 g/mL with PAO 30 base and PAO 60 base, and the dispersion stability was 77-95 and 81-74% for the PAO-30 and PAO-60-based fluids, respectively. The observed saturation magnetization values of the PAO-30 and PAO-60-based ferrofluids were 16 to 42 mT and 17 to 41 mT with the concentration increase in the range 200-500 mg/mL, respectively, depending upon the content of magnetic particles in the fluid. The viscosity variation of the PAO-30 and PAO-60-based ferrofluids in the temperature range $20-80^{\circ}C$ was the least with the concentrations of 400 and 300 mg/mL, respectively.