• 제목/요약/키워드: Methods of NOx Measuring

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디젤기관의 NOx 저감방법 및 NOx 측정에 관한 연구 (A Study on the Method of NOx Reduction and NOx Measurement for the Diesel Engines)

  • 남정길;김준효;최주열
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2002년도 춘계학술대회논문집
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    • pp.193-199
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    • 2002
  • According to the NOx level requirement of annex Vl to IMO(International Maritime Organization) MARPOL 73/78, this regulation shall apply to each diesel engine with a power output of more than 130 ㎾ which is installed on a ship constructed and undergoes a major conversion on or after 1 January 2000. It is inevitable to adopt IMO standard for marine engines. Therefore, most of diesel engines which are being currently built should be tested and surveyed in accordance with the NOx technical code. In this study, various technics of NOx reduction methods were investigated for the diesel engines and the methods of NOx measuring were introduced by the new and simplified field detecting equipment. These results can be utilized for the basic design and developement of diesel engine for NOx reduction.

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디젤엔진의 NOx 배출 특성에 관한 연구 (A Study for NOx Discharge Characteristics of Diesel Engines)

  • 남정길;최주열
    • Journal of Advanced Marine Engineering and Technology
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    • 제27권3호
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    • pp.373-380
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    • 2003
  • According to the NOx regulations of annex Vi to IMO MARPOL 73/78, all diesel engines with a power output of more than 130 kW should be delivered so as to comply with the IMO speed dependent NOx limit. It is inevitable to adopt this regulations for marine engines Therefore, most of diesel engines which are being currently built should be designed and tested in accordance with the NOx technical code In this study, NOx concentrations of 4 type engines were measured with portable NOx measuring system recommended by ISO-8178. As the results NOx concentrations of each engine by variation of engine speed and engine load were visualized Also these results can be utilized for the basic design and development of diesel engine for NOx reduction.

대형 상용 엔진에서 SCR의 클리닝 주기 선정 및 저감효율에 따른 내구신뢰성 특성 연구 (Cleaning Interval Selection for SCR Considering Endurance Reliability and Emissions Reduction Efficiency in Heavy Duty Commercial Engine)

  • 신재식;강정호;김형준
    • 한국신뢰성학회지:신뢰성응용연구
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    • 제18권1호
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    • pp.66-71
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    • 2018
  • Purpose: Performance recovered from SCR through cleaning was studied, measuring differential pressure, NOx reduction efficiency, fuel consumption and engine power before and after cleaning. Ideal cleaning intervals are proposed based on SCR mileage and differential pressure. SCR endurance and reliability improvements through cleaning were studied through physicochemical testing of SCR durability at 43,000km 50,000km, and 110,000km respectively. Methods: Engine power, fuel consumption and exhaust gas were measured using engine full load tests and ND-13 MODE by installing the SCR before cleaned at total engine mileages of 400,000 km, 300,000km and 200,000km. The same tests were performed after cleaning the SCR catalytic converter. Endurance and reliability of the SCR cleaning was studied through the same test by SCR catalyst after each 43,000km 50,000km, 110,000km, durability test on SCR cleaning. Conclusion: We confirmed the low-performance of the SCR due to clogging is restored by SCR cleaning technology. The NOx reduction efficiency was restored to 82%, 86% and 88% from 69%, 72% and 79%. As well as the NOx reduction efficiency, it was confirmed that the engine power, fuel consumption and back pressure was restored to fresh SCR levels. As a result of the durability and reliability achieved through SCR cleaning, we confined the appearance and reduction efficiency through visual inspection and ND-13 MODE are similar to new SCR catalysts. Finally, it was judged that there was no change in performance even when driving the SCR without cleaning throughout the 100,000 km mileage warranty.

증착방법에 따른 $NO_x$가스 감지용 $WO_3$박막센서의 특성 변화 연구 (The Sensing Characteristics of $WO_3$ Thin Films for $NO_x$ Gas Detection with the Change of Deposition Methods)

  • 김태송;김용범;유광수;성기숙;정형진
    • 한국세라믹학회지
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    • 제34권4호
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    • pp.387-393
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    • 1997
  • In order to apply WO3 thin films to the semiconducting NOx gas sensors as a sensing material, which have been expected to show good electrical properties, such as large sensitivity, rapid responsibility, and high selectivity, the fabrication method and their sensing characteristics were studied. The variations of surface morphologies, crystallographic orientations and crystallinity with the WO3 thin film growing methods thermal evaporation and DC sputtering methods were investigated by using scanning electron microscopy (SEM) and X-ray diffraction(XRD) analysis. As a result of sensitivity (Rgas/Rair) measurements for the 5 ppm NO2 test gas, the sensitivity values were 113 for the sputtered films and 93 for the evaporated films. It was also observed that the recovery rate of a sensing signal after measuring sensitivity was faster in the sputtered films than in the evaporated films.

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미시적 도로주행 조건을 반영한 배출량 산정 방법의 적용 사례 연구 (Application of an Emission Estimation Methodology to Reflect Microscale Road Driving Conditions)

  • 허혜정;윤천주;양충헌;김진국
    • 한국도로학회논문집
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    • 제18권3호
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    • pp.115-125
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    • 2016
  • PURPOSES : This study proposes a methodology to collect data necessary for microlevel emission estimation, such as second-by-second speeds and road grades, and to accordingly estimate emissions. METHODS : To ease data collection for microlevel emission estimation, a vehicle equipped with speed- and location-recording instruments as well as equipment for measuring road geometry was used. As a case study, this vehicle and the proposed methodology were used on a 10-km-long highway in Yongin City, Korea. Emissions from the vehicle during driving were estimated in various microscale driving conditions. RESULTS : Differences in the estimated emission under different microscale driving conditions cannot be ignored. Compared with the estimations obtained when second-by-second data were not considered, CO and NOx emissions were more than threefold higher when considering second-by-second speed; similarly, CO and NOx emission estimations were higher by approximately 10% and 3%, respectively, when considering second-by-second road grade. CONCLUSIONS : The proposed method can estimate vehicle emissions under real-world driving conditions in such applications as road design and traffic policy assessments.

접착식 간접구의 연기 밀도 및 유해가스 발생 확인 연구 (Study of the Density of Smoke and Harmful Gases of Adhesive Indirect Moxibustion)

  • 김은정;김유종;황지후;조현석;김경호;이승덕;김갑성
    • 대한한의학회지
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    • 제33권1호
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    • pp.42-51
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    • 2012
  • Objectives: We measured the density of smoke and harmful gases emitted from burning adhesive indirect moxa. Through the test we aimed to find out if there was an excessive amount of smoke emitted and if it included harmful gases. Methods: 9 types of adhesive indirect moxa were chosen. The buffer layers which do not burn during treatment were removed and 10g of each moxa were made into powder and put into a holder. A smoke density chamber (Smoke Density Chamber FTT. U.K) and Fourier transform infrared spectroscopy (FT-IR I 4001. MIDAC U.S.A.) were used to measure the density of smoke and harmful gases emitted from burning moxa by ISO 5659-2 test. Results: The result of measuring maximum smoke density showed that the regular indirect adhesive moxa (A-F) emitted high density smoke of 172.1-291.4Ds. The smokeless moxas, Seoam moxas, emitted the least amount of 3.4-5.5Ds. Concentrations of 7 typical harmful gases (CO, HCl, HCN, HBr, HF, SO2, NOx) were measured and all of the moxas emitted CO due to incomplete combustion. 4 types of moxa emitted NOx and all smokless moxas emitted NOx. HBr, HCN, HCl, HF, SO2 were not found in any of the moxas. Conclusions: The amount of harmful gases emitted from burning moxa was much lower than short-term exposure standards of chemical and physical factors (Ministry of Labor 2010-44). Further experiments measuring gases from moxa combustion should be done in larger environments similar to normal medical clinics.

직접분사식 바이오에탄올-가솔린 혼합연료의 분무 및 희박연소 특성에 관한 실험적 연구 (An Experimental Study on the Spray and Lean Combustion Characteristics of Bio-enthanol-Gasoline Blended Fuel of GDI)

  • 박기영;강석호;김인구;임철수;김재만;조용석;이성욱
    • 한국분무공학회지
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    • 제19권3호
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    • pp.115-122
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    • 2014
  • As a demand for an automobile increases, air pollution and a problem of the energy resources come to the fore in the world. Consequently, governments of every country established ordinances for green-house gas reduction and improvement of air pollution problem. Especially, as international oil price increases, engine using clean energy are being developed competitively with alternative transportation energy sources development policy as the center. Bio ethanol, one of the renewable energy produced from biomass, gained spotlight for transportation energy sources. Studies are in progress to improve fuel supply methods and combustion methods which are key features, one of the engine technologies. DI(Direct Injection), which can reduce fuel consumption rate by injecting fuel directly into the cylinder, is being studied for Green-house gas reduction and fuel economy enhancement at SI(Spark Ignition). GDI(Galoine Direct Injection) has an advantage to meet the regulations for fuel efficiency and $CO_2$ emissions. However it produces increased number of ultrafine particles, that yet received attention in the existing port-injection system, and NOX. As fuel is injected into the cylinder with high-pressure, a proper injection strategy is required by characteristics of a fuel. Especially, when alcohol type fuel is considered. In this study, we tried to get a base data bio-ethanol mixture in GDI, and combustion for optimization. We set fuel mixture rate and fuel injection pressure as parameters and took a picture with a high speed camera after gasoline-ethanol mixture fuel was injected into a constant volume combustion chamber. We figured out spraying characteristic according to parameters. Also, we determine combustion characteristics by measuring emissions and analyzing combustion.

인진호 열수 추출물이 thioacetamide에 의해 유발된 간손상에 미치는 간보호 효과 (Protective effect of Artemisiae Capillaris Herba water extract on liver injury induced by thioacetamide)

  • 김민주;이진아;신미래;박해진;노성수
    • Journal of Nutrition and Health
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    • 제54권4호
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    • pp.412-421
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    • 2021
  • 본 연구는 TAA 복강투여로 유발된 간 손상 동물모델에서 인진호 열수 추출물의 간보호 효능을 평가하였으며 다음과 같은 결론을 얻었다. TAA로 인해 줄어드는 체중은 인진호 열수 추출물을 투여한 군에서 유의하게 증가하였으며, 간손상에 의해 증가한 혈중 암모니아 함량과 MPO 활성은 인진호 열수 추출물 투여군에서 유의하게 감소하였다. 간 조직의 western blotting 결과, 인진호 열수 추출물 투여가 산화적 스트레스 관련 인자들의 발현을 유의적으로 감소시키고, 항산화 관련 인자들의 발현을 유의하게 증가시켰으며, MMPs의 발현은 감소시키고 TIMP-1의 발현은 증가시킴을 확인할 수 있었다. 따라서 인진호 열수 추출물은 TAA로 유발된 간손상 동물모델에서 항산화 작용을 통해 산화적 스트레스를 억제하여 간보호 효과를 보이는 것으로 판단된다.

농업지역(밭) 암모니아 등 대기오염물질 계절별 모니터링 연구 (Study on the Emission Characteristics of Air Pollutants from Agricultural Area)

  • 김민욱;김진호;김경식;홍성창
    • 한국환경농학회지
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    • 제40권3호
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    • pp.211-218
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    • 2021
  • BACKGROUND: Fine particulate matter (PM2.5) is produced by chemical reactions between various precursors. PM2.5 has been found to create greater human risk than particulate matter (PM10), with diameters that are generally 10 micrometers and smaller. Ammonia (NH3) and nitrogen oxides (NOx) are the sources of secondary generation of PM2.5. These substances generate PM2.5 through some chemical reactions in the atmosphere. Through chemical reactions in the atmosphere, NH3 generates PM2.5. It is the causative agent of PM2.5. In 2017 the annual ammonia emission recorded from the agricultural sector was 244,335 tons, which accounted for about 79.3% of the total ammonia emission in Korea in that year. To address this issue, the agricultural sector announced the inclusion of reducing fine particulate matter and ammonia emissions by 30% in its targets for the year 2022. This may be achieved through analyses of its emission characteristics by monitoring the PM2.5 and NH3. METHODS AND RESULTS: In this study, the PM2.5 concentration was measured real-time (every 1 hour) by using beta radiation from the particle dust measuring device (Spirant BAM). NH3 concentration was analyzed real-time by Cavity Ring-Down Spectroscopy (CRDS). The concentrations of ozone (O3) and nitrogen dioxide (NO2) were continuously measured and analyzed for the masses collected on filter papers by ultraviolet photometry and chemiluminescence. CONCLUSION: This study established air pollutant monitoring system in agricultural areas to analyze the NH3 emission characteristics. The amount of PM2.5 and NH3 emission in agriculture was measured. Scientific evidence in agricultural areas was obtained by identifying the emission concentration and characteristics per season (monthly) and per hour.

질소산화물 제거를 위한 TiO2-mayenite 제조 방법에 관한 연구 (Investigation on the Preparation Method of TiO2-mayenite for NOx Removal)

  • 박지혜;박정준;박희주;이광복
    • 청정기술
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    • 제26권4호
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    • pp.304-310
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    • 2020
  • 다양한 건축재료에 광촉매(TiO2)를 적용하기 위하여 TiO2-mayenite를 제조하였다. TiO2는 졸-겔법을 사용하여 titanium isopropoxide (TTIP)와 urea를 1:1의 비율로 고정하여 합성하였다. 그 후 온도범위 400 - 700 ℃로 소성하여 온도에 따른 특성을 분석하였다. TiO2의 물리 및 화학적 특성은 BET, TGA 그리고 XRD를 통해 분석되었다. 질소산화물 제거 실험은 KS L ISO 22197-1에 의거하여 1 시간 동안의 NO의 농도변화를 측정하여 확인하였다. 제조된 입자들은 600 ℃ 이하에서 아나타제 결정구조를 나타내었고, TiO2 (urea)-400에서 2.35 µmol h-1의 가장 높은 질소산화물 제거율을 나타내었다. TiO2-mayenite는 TiO2 분산 용액을 스프레이하는 방법(s/s)과 졸-겔 상태의 용액을 스프레이 하는 방법(g/s)으로 제조하였다. BET와 XRD 분석을 통하여, 제조된 TiO2-mayenite는 졸-겔 상태의 용액을 스프레이 하여 제조한 5-TiO2 (g/s) 입자가 열처리에도 결정구조를 유지하는 것을 확인하였다. 또한 질소산화물 제거 실험에서도 5-TiO2 (g/s)-500 입자에서 0.55 µmol h-1의 가장 높은 제거율을 나타내었다. 결론적으로 TiO2-mayenite를 제조하기 위하여 TiO2는 졸-겔 상태에서 mayenite에 결합시켜야 결정구조를 유지하며, 높은 질소산화물 제거 능력을 나타내는 것을 확인하였다.