• Title/Summary/Keyword: Methods of NOx Measuring

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A Study on the Method of NOx Reduction and NOx Measurement for the Diesel Engines (디젤기관의 NOx 저감방법 및 NOx 측정에 관한 연구)

  • 남정길;김준효;최주열
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2002.05a
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    • pp.193-199
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    • 2002
  • According to the NOx level requirement of annex Vl to IMO(International Maritime Organization) MARPOL 73/78, this regulation shall apply to each diesel engine with a power output of more than 130 ㎾ which is installed on a ship constructed and undergoes a major conversion on or after 1 January 2000. It is inevitable to adopt IMO standard for marine engines. Therefore, most of diesel engines which are being currently built should be tested and surveyed in accordance with the NOx technical code. In this study, various technics of NOx reduction methods were investigated for the diesel engines and the methods of NOx measuring were introduced by the new and simplified field detecting equipment. These results can be utilized for the basic design and developement of diesel engine for NOx reduction.

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A Study for NOx Discharge Characteristics of Diesel Engines (디젤엔진의 NOx 배출 특성에 관한 연구)

  • 남정길;최주열
    • Journal of Advanced Marine Engineering and Technology
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    • v.27 no.3
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    • pp.373-380
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    • 2003
  • According to the NOx regulations of annex Vi to IMO MARPOL 73/78, all diesel engines with a power output of more than 130 kW should be delivered so as to comply with the IMO speed dependent NOx limit. It is inevitable to adopt this regulations for marine engines Therefore, most of diesel engines which are being currently built should be designed and tested in accordance with the NOx technical code In this study, NOx concentrations of 4 type engines were measured with portable NOx measuring system recommended by ISO-8178. As the results NOx concentrations of each engine by variation of engine speed and engine load were visualized Also these results can be utilized for the basic design and development of diesel engine for NOx reduction.

Cleaning Interval Selection for SCR Considering Endurance Reliability and Emissions Reduction Efficiency in Heavy Duty Commercial Engine (대형 상용 엔진에서 SCR의 클리닝 주기 선정 및 저감효율에 따른 내구신뢰성 특성 연구)

  • Shin, Jaesik;Kang, Jungho;Kim, Hyongjun
    • Journal of Applied Reliability
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    • v.18 no.1
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    • pp.66-71
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    • 2018
  • Purpose: Performance recovered from SCR through cleaning was studied, measuring differential pressure, NOx reduction efficiency, fuel consumption and engine power before and after cleaning. Ideal cleaning intervals are proposed based on SCR mileage and differential pressure. SCR endurance and reliability improvements through cleaning were studied through physicochemical testing of SCR durability at 43,000km 50,000km, and 110,000km respectively. Methods: Engine power, fuel consumption and exhaust gas were measured using engine full load tests and ND-13 MODE by installing the SCR before cleaned at total engine mileages of 400,000 km, 300,000km and 200,000km. The same tests were performed after cleaning the SCR catalytic converter. Endurance and reliability of the SCR cleaning was studied through the same test by SCR catalyst after each 43,000km 50,000km, 110,000km, durability test on SCR cleaning. Conclusion: We confirmed the low-performance of the SCR due to clogging is restored by SCR cleaning technology. The NOx reduction efficiency was restored to 82%, 86% and 88% from 69%, 72% and 79%. As well as the NOx reduction efficiency, it was confirmed that the engine power, fuel consumption and back pressure was restored to fresh SCR levels. As a result of the durability and reliability achieved through SCR cleaning, we confined the appearance and reduction efficiency through visual inspection and ND-13 MODE are similar to new SCR catalysts. Finally, it was judged that there was no change in performance even when driving the SCR without cleaning throughout the 100,000 km mileage warranty.

The Sensing Characteristics of $WO_3$ Thin Films for $NO_x$ Gas Detection with the Change of Deposition Methods (증착방법에 따른 $NO_x$가스 감지용 $WO_3$박막센서의 특성 변화 연구)

  • 김태송;김용범;유광수;성기숙;정형진
    • Journal of the Korean Ceramic Society
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    • v.34 no.4
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    • pp.387-393
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    • 1997
  • In order to apply WO3 thin films to the semiconducting NOx gas sensors as a sensing material, which have been expected to show good electrical properties, such as large sensitivity, rapid responsibility, and high selectivity, the fabrication method and their sensing characteristics were studied. The variations of surface morphologies, crystallographic orientations and crystallinity with the WO3 thin film growing methods thermal evaporation and DC sputtering methods were investigated by using scanning electron microscopy (SEM) and X-ray diffraction(XRD) analysis. As a result of sensitivity (Rgas/Rair) measurements for the 5 ppm NO2 test gas, the sensitivity values were 113 for the sputtered films and 93 for the evaporated films. It was also observed that the recovery rate of a sensing signal after measuring sensitivity was faster in the sputtered films than in the evaporated films.

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Application of an Emission Estimation Methodology to Reflect Microscale Road Driving Conditions (미시적 도로주행 조건을 반영한 배출량 산정 방법의 적용 사례 연구)

  • Hu, Hyejung;Yoon, Chunjoo;Yang, Choongheon;Kim, Jinkook
    • International Journal of Highway Engineering
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    • v.18 no.3
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    • pp.115-125
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    • 2016
  • PURPOSES : This study proposes a methodology to collect data necessary for microlevel emission estimation, such as second-by-second speeds and road grades, and to accordingly estimate emissions. METHODS : To ease data collection for microlevel emission estimation, a vehicle equipped with speed- and location-recording instruments as well as equipment for measuring road geometry was used. As a case study, this vehicle and the proposed methodology were used on a 10-km-long highway in Yongin City, Korea. Emissions from the vehicle during driving were estimated in various microscale driving conditions. RESULTS : Differences in the estimated emission under different microscale driving conditions cannot be ignored. Compared with the estimations obtained when second-by-second data were not considered, CO and NOx emissions were more than threefold higher when considering second-by-second speed; similarly, CO and NOx emission estimations were higher by approximately 10% and 3%, respectively, when considering second-by-second road grade. CONCLUSIONS : The proposed method can estimate vehicle emissions under real-world driving conditions in such applications as road design and traffic policy assessments.

Study of the Density of Smoke and Harmful Gases of Adhesive Indirect Moxibustion (접착식 간접구의 연기 밀도 및 유해가스 발생 확인 연구)

  • Kim, Eun-Jung;Kim, Yu-Jong;Hwang, Ji-Hoo;Cho, Hyun-Seok;Kim, Kyung-Ho;Lee, Seung-Deok;Kim, Kap-Sung
    • The Journal of Korean Medicine
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    • v.33 no.1
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    • pp.42-51
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    • 2012
  • Objectives: We measured the density of smoke and harmful gases emitted from burning adhesive indirect moxa. Through the test we aimed to find out if there was an excessive amount of smoke emitted and if it included harmful gases. Methods: 9 types of adhesive indirect moxa were chosen. The buffer layers which do not burn during treatment were removed and 10g of each moxa were made into powder and put into a holder. A smoke density chamber (Smoke Density Chamber FTT. U.K) and Fourier transform infrared spectroscopy (FT-IR I 4001. MIDAC U.S.A.) were used to measure the density of smoke and harmful gases emitted from burning moxa by ISO 5659-2 test. Results: The result of measuring maximum smoke density showed that the regular indirect adhesive moxa (A-F) emitted high density smoke of 172.1-291.4Ds. The smokeless moxas, Seoam moxas, emitted the least amount of 3.4-5.5Ds. Concentrations of 7 typical harmful gases (CO, HCl, HCN, HBr, HF, SO2, NOx) were measured and all of the moxas emitted CO due to incomplete combustion. 4 types of moxa emitted NOx and all smokless moxas emitted NOx. HBr, HCN, HCl, HF, SO2 were not found in any of the moxas. Conclusions: The amount of harmful gases emitted from burning moxa was much lower than short-term exposure standards of chemical and physical factors (Ministry of Labor 2010-44). Further experiments measuring gases from moxa combustion should be done in larger environments similar to normal medical clinics.

An Experimental Study on the Spray and Lean Combustion Characteristics of Bio-enthanol-Gasoline Blended Fuel of GDI (직접분사식 바이오에탄올-가솔린 혼합연료의 분무 및 희박연소 특성에 관한 실험적 연구)

  • Park, Gi-Young;Kang, Seok-Ho;Kim, In-Gu;Lim, Cheol-Soo;Kim, Jae-Man;Cho, Yong-Seok;Lee, Seong-Wock
    • Journal of ILASS-Korea
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    • v.19 no.3
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    • pp.115-122
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    • 2014
  • As a demand for an automobile increases, air pollution and a problem of the energy resources come to the fore in the world. Consequently, governments of every country established ordinances for green-house gas reduction and improvement of air pollution problem. Especially, as international oil price increases, engine using clean energy are being developed competitively with alternative transportation energy sources development policy as the center. Bio ethanol, one of the renewable energy produced from biomass, gained spotlight for transportation energy sources. Studies are in progress to improve fuel supply methods and combustion methods which are key features, one of the engine technologies. DI(Direct Injection), which can reduce fuel consumption rate by injecting fuel directly into the cylinder, is being studied for Green-house gas reduction and fuel economy enhancement at SI(Spark Ignition). GDI(Galoine Direct Injection) has an advantage to meet the regulations for fuel efficiency and $CO_2$ emissions. However it produces increased number of ultrafine particles, that yet received attention in the existing port-injection system, and NOX. As fuel is injected into the cylinder with high-pressure, a proper injection strategy is required by characteristics of a fuel. Especially, when alcohol type fuel is considered. In this study, we tried to get a base data bio-ethanol mixture in GDI, and combustion for optimization. We set fuel mixture rate and fuel injection pressure as parameters and took a picture with a high speed camera after gasoline-ethanol mixture fuel was injected into a constant volume combustion chamber. We figured out spraying characteristic according to parameters. Also, we determine combustion characteristics by measuring emissions and analyzing combustion.

Protective effect of Artemisiae Capillaris Herba water extract on liver injury induced by thioacetamide (인진호 열수 추출물이 thioacetamide에 의해 유발된 간손상에 미치는 간보호 효과)

  • Kim, Min Ju;Lee, Jin A;Shin, Mi-Rae;Park, Hae-Jin;Roh, Seong-Soo
    • Journal of Nutrition and Health
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    • v.54 no.4
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    • pp.412-421
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    • 2021
  • Purpose: Thioacetamide (TAA) produces reactive oxygen species (ROS) in the liver, and the generated ROS induces liver injury through inflammatory reactions. The current study was undertaken to investigate the hepatoprotective effect of Artemisiae Capillaris Herba water extract (AC), imparted via its antioxidant activity, in an animal model of TAA-induced liver injury. Methods: Animal experiments were conducted in 5 groups: normal, control (TAA 200 mg/kg), SM (TAA 200 mg/kg + silymarin 100 mg/kg), ACL (TAA 200 mg/kg + AC 100 mg/kg), ACH (TAA 200 mg/kg + AC 200mg/kg). TAA (intraperitoneal) and treatment compounds (per oral) were administered for 3 days. Serum levels of ammonia concentration and myeloperoxidase (MPO) activity were subsequently measured. Liver tissues were subjected to western blot analysis for measuring the oxidative stress (NADPH oxidase), anti-oxidative activity (Nrf2, heme oxygenase-1 [HO-1], superoxide dismutase [SOD], catalase, and GPx-1/2), tissue inhibitors of metalloproteinase (TIMP)-1, and matrix metalloproteinases (MMPs) protein expressions. Results: Serum ammonia levels and MPO activity were significantly increased in the TAA-induced control group, whereas groups administered AC treatment showed markedly reduced levels. Western blot analysis revealed significantly increased NOX2 and p22phox expressions, (oxidative stress-related factors) in the TAA-induced control group. These levels were determined to be significantly decreased after AC exposure. Moreover, antioxidant-related factors including Nrf2, HO-1, SOD, catalase, and GPx-1/2 were significantly decreased in the control group and increased in the AC treated groups. In addition, MMP expressions were significantly suppressed in the AC treatment group due to increased levels of TIMP-1. Conclusion: Taken together, these data indicate that exposure to AC reduces the oxidative stress by inhibiting the expression of NADPH oxidase (NOX2 and p22phox) through the Nrf2 signaling pathway. We therefore propose the potential of AC for the prevention and treatment of TAA-induced liver injury.

Study on the Emission Characteristics of Air Pollutants from Agricultural Area (농업지역(밭) 암모니아 등 대기오염물질 계절별 모니터링 연구)

  • Kim, Min-Wook;Kim, Jin-Ho;Kim, Kyeong-Sik;Hong, Sung-Chang
    • Korean Journal of Environmental Agriculture
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    • v.40 no.3
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    • pp.211-218
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    • 2021
  • BACKGROUND: Fine particulate matter (PM2.5) is produced by chemical reactions between various precursors. PM2.5 has been found to create greater human risk than particulate matter (PM10), with diameters that are generally 10 micrometers and smaller. Ammonia (NH3) and nitrogen oxides (NOx) are the sources of secondary generation of PM2.5. These substances generate PM2.5 through some chemical reactions in the atmosphere. Through chemical reactions in the atmosphere, NH3 generates PM2.5. It is the causative agent of PM2.5. In 2017 the annual ammonia emission recorded from the agricultural sector was 244,335 tons, which accounted for about 79.3% of the total ammonia emission in Korea in that year. To address this issue, the agricultural sector announced the inclusion of reducing fine particulate matter and ammonia emissions by 30% in its targets for the year 2022. This may be achieved through analyses of its emission characteristics by monitoring the PM2.5 and NH3. METHODS AND RESULTS: In this study, the PM2.5 concentration was measured real-time (every 1 hour) by using beta radiation from the particle dust measuring device (Spirant BAM). NH3 concentration was analyzed real-time by Cavity Ring-Down Spectroscopy (CRDS). The concentrations of ozone (O3) and nitrogen dioxide (NO2) were continuously measured and analyzed for the masses collected on filter papers by ultraviolet photometry and chemiluminescence. CONCLUSION: This study established air pollutant monitoring system in agricultural areas to analyze the NH3 emission characteristics. The amount of PM2.5 and NH3 emission in agriculture was measured. Scientific evidence in agricultural areas was obtained by identifying the emission concentration and characteristics per season (monthly) and per hour.

Investigation on the Preparation Method of TiO2-mayenite for NOx Removal (질소산화물 제거를 위한 TiO2-mayenite 제조 방법에 관한 연구)

  • Park, Ji Hye;Park, Jung Jun;Park, Hee Ju;Yi, Kwang Bok
    • Clean Technology
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    • v.26 no.4
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    • pp.304-310
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    • 2020
  • In order to apply a photocatalyst (TiO2) to various building materials, TiO2-mayenite was prepared in this study. The TiO2 was synthesized using the sol-gel method by fixing titanium isopropoxide (TTIP) and urea at a ratio of 1 : 1. Later, they were calcined in a temperature range of 400-700 ℃ to analyze the properties according to temperature. BET, TGA, and XRD were used to analyze the physical and chemical properties of TiO2. The nitrogen oxide removal test was confirmed by measuring the change in the concentration of NO for 1 h according to KS L ISO 22197-1. The prepared TiO2 samples exhibited an anatase crystal structure below 600 ℃, and TiO2 (urea)-400 showed the highest nitrogen oxide removal rate at 2.35 µmol h-1. TiO2-mayenite was prepared using two methods: spraying TiO2 dispersion solution (s/s) and sol-gel solution (g/s). Through BET and XRD analysis, it was found that 5-TiO2 (g/s) prepared by spraying a sol-gel solution has maintained its crystallinity even after heat treatment. Also, 5-TiO2 (g/s)-500 showed the highest removal rate of 0.55 µmol h-1 in the nitrogen oxide removal test. To prepare TiO2-mayenite, it was confirmed that mayenite should be blended with TiO2 in a sol-gel state to maintain the crystal structure and exhibit a high nitrogen oxide removal rate.